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Aspen Physical Property System - Physical Property Models

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Chung-Lee-Starling Thermal Conductivity<br />

The main equation for the Chung-Lee-Starling thermal conductivity model is:<br />

Where:<br />

f1<br />

f2<br />

�<br />

270 3 Transport <strong>Property</strong> <strong>Models</strong><br />

=<br />

=<br />

=<br />

�(p = 0) can be calculated by the low pressure Chung-Lee-Starling model.<br />

The molar density can be calculated using an equation-of-state model (for<br />

example, the Benedict-Webb-Rubin equation-of-state). The parameter pr is<br />

the reduced dipolemoment:<br />

The polar parameter � is tabulated for certain alcohols and carboxylic acids.<br />

For low pressures, f1 is reduced to 1.0 and f2 is reduced to zero. This gives<br />

the Chung-Lee-Starling expression for thermal conductivity of low pressure<br />

gases.<br />

The same expressions are used for mixtures. The mixture expression for � (p<br />

= 0) must be used. (See Chung-Lee-Starling Low-Pressure Vapor Viscosity.)<br />

Where:

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