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Clevertex - Grado Zero Espace Srl

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as Nitinol. This specific alloy has very good electric and mechanical properties and a high resistance<br />

against corrosion. Moreover, Nitinol has the quality of inducing the transformation by means of electric<br />

energy. When sufficient electric power is transmitted through the wire, the generated warmth will<br />

produce the transformation. Usually, a shape memory alloy is chosen whose transformation<br />

temperature lies far above room temperature. By changing the rate of Ni and Ti, one can increase or<br />

decrease the transformation temperature. The available transition temperatures vary between –100<br />

and + 100°C.<br />

NiTi-alloys usually occur in the form of wires, making them suitable to be processed in a textile<br />

material.<br />

Because of their biocompatibility, NiTi-alloys are also applied in the medical world. They are put to use<br />

in surgical tools as well as in permanent implants.<br />

BioMetal is the trade name of nickel-titanium fibres produced by Toki, a Japanese company. The<br />

fibres are capable to remember a certain length, which means when a force is applied on the fibre<br />

during heating it contracts. When it cools down again, it elongates. The fibres can be used for instance<br />

as electrothermal driven actuators.<br />

Further, the American company Dynalloy Inc. commercialises a shape memory alloy actuator wire<br />

made of nickel-titanium under the trade name Flexinol®. Its ability to flex and shorten is electrically<br />

driven. The alloy wire can be applied variously; in the field of textiles applications include light fibre<br />

switches and light fibre gates (automotive industry) [188].<br />

Cuprous-zinc alloys are capable of a two-way activation and therefore can produce the reversible<br />

variation needed for protection from changeable weather conditions. They will also react to<br />

temperature changes brought about by variations in physical activity levels.<br />

Polymers<br />

Shape memory polymers are defined as polymeric materials with the ability to sense and respond to<br />

external stimuli in a predetermined shape.<br />

Shape memory polymers were first developed in France (CdF Chimie Company) and commercialised<br />

by Nippon Zeon Co. in Japan in 1984.<br />

Polymers such as polynorbornylene, transpolyisoprene, styrene-butadiene copolymer, polyethylene,<br />

polyester copolymerised with others and block polyurethanes have been discovered to have shape<br />

memory properties. A variety of about twenty polymers were developed with shape memory effects.<br />

Shape recovery due to the shape memory of polymers may be triggered by heat, light, electricity and<br />

other stimuli.<br />

111

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