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Toray Industries and Marmot Mountain Works ® also introduced a polyurethane polymer film<br />

MemBrain ® laminated between adjacent layers of clothing, thus resulting in a waterproof and<br />

breathable fabric. When the temperature of the outer layer of clothing has fallen sufficiently, the<br />

polyurethane film responds so that the air gap between the layers of clothing becomes broader. This<br />

broadening is achieved if, on cooling, the film develops an out-of-plane deformation, which must be<br />

strong enough to resist the weight of the clothing and the forces induced by the movements of the<br />

wearer. The deformation must be capable of reversal if the outer layer of clothing subsequently<br />

becomes warmer.<br />

Another application of shape memory polymers is the production of form regulating clothes. Australian<br />

scientists at University of Wollongong have invented a smart bra that will change its properties in<br />

response to breast movement, giving better support to active women. The bra tightens and loosens its<br />

own straps, or stiffens and relaxes its cups, to restrict breast movement, preventing pain and sag. The<br />

bra is made of a fabric with a special coating that makes it contract when the strain on it passes a preset<br />

level. Scientists at Wollongong University say the brazier automatically provides women extra<br />

support during strenuous activity such as exercise.<br />

Other smart fabrics being developed by the team include a knee sleeve that tells athletes whether they<br />

have landed properly and a cloth for the US military with built-in solar energy cells and batteries. The<br />

team is also working with doctors at Sydney's Royal North Shore Hospital on a glove for people with<br />

hand injuries that uses electric signals to help patients clench their hands and pick things up.<br />

In protective clothing, shape memory polyurethanes have been proposed to shield against heat,<br />

although these ideas have, to our knowledge, never reached the market.<br />

Finishings<br />

MiracleCare, developed by the Japanese company Toyobo, is a long-standing vapour phase shapememory<br />

finishing process for cotton and other cellulosic materials.<br />

Nano-Tex licenses a nanotechnology treatment applied by pad in fabric form or by dipping the finished<br />

garment. This is a permanent method of minimising wrinkles, while also offering softness and<br />

breathability. The crease removal is achieved by a mixture of heat and moisture [191]. Eddie Bauer<br />

used this technology in a khaki trousers collection.<br />

118

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