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Clevertex - Grado Zero Espace Srl

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B. Thermal vibrations<br />

Shape memory polymers can also be used to make a moisture permeable membrane. In this case,<br />

the polymer membrane reacts by inducing thermal vibrations. Micro-Brownian movements of the<br />

amorphous polymeric soft segments occur when the temperature rises above a predetermined<br />

activation temperature. Due to these movements, micropores appear in the polymer membrane. Water<br />

vapour molecules (with an average diameter of 3.5 Å) and body heat can escape through these pores.<br />

Molecular structure below the activation<br />

temperature [189]<br />

Fig. 103 Molecular structure<br />

Fig. 104 Activation scheme [189]<br />

Molecular structure above the activation<br />

temperature [189]<br />

Gels<br />

Encapsulated Bi-Gels absorb liquid at differing rates according to temperature which causes them to<br />

bend. This offers possibilities for their use as actuators in a variable insulation system. Exploratory<br />

work using polyacrylamide and poly-N-isopropylacrylamide did not produce the envisaged robust<br />

actuator behaviour.<br />

Workers at the company S.Mizushima of Mizushima Silk Industry Ltd. succeeded in developing a<br />

shape-memory silk yarn. The silk yarn is chemically treated by dipping in a solution of hydrolyzed<br />

113

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