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B. Thermal vibrations<br />
Shape memory polymers can also be used to make a moisture permeable membrane. In this case,<br />
the polymer membrane reacts by inducing thermal vibrations. Micro-Brownian movements of the<br />
amorphous polymeric soft segments occur when the temperature rises above a predetermined<br />
activation temperature. Due to these movements, micropores appear in the polymer membrane. Water<br />
vapour molecules (with an average diameter of 3.5 Å) and body heat can escape through these pores.<br />
Molecular structure below the activation<br />
temperature [189]<br />
Fig. 103 Molecular structure<br />
Fig. 104 Activation scheme [189]<br />
Molecular structure above the activation<br />
temperature [189]<br />
Gels<br />
Encapsulated Bi-Gels absorb liquid at differing rates according to temperature which causes them to<br />
bend. This offers possibilities for their use as actuators in a variable insulation system. Exploratory<br />
work using polyacrylamide and poly-N-isopropylacrylamide did not produce the envisaged robust<br />
actuator behaviour.<br />
Workers at the company S.Mizushima of Mizushima Silk Industry Ltd. succeeded in developing a<br />
shape-memory silk yarn. The silk yarn is chemically treated by dipping in a solution of hydrolyzed<br />
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