Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
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L<strong>on</strong>ger campaigns with improved m<strong>on</strong>olithics<br />
for lining <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> melt-hold furnaces<br />
Andy Wynn, John Coppack and Tom Steele, Thermal Ceramics UK Ltd.<br />
To remain competitive, <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> producers<br />
c<strong>on</strong>tinue to increase productivity<br />
through <str<strong>on</strong>g>the</str<strong>on</strong>g>ir melt-hold furnaces. Increasing<br />
heat input to <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace using more<br />
powerful burners is comm<strong>on</strong> practice.<br />
But faster melting leads to increased<br />
metal losses from surface oxidati<strong>on</strong> and<br />
to segregati<strong>on</strong> from large heat gradients.<br />
These effects are countered by increased<br />
use <str<strong>on</strong>g>of</str<strong>on</strong>g> fluxes and increased stirring. Given<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> increasingly challenging envir<strong>on</strong>ment<br />
within which <str<strong>on</strong>g>the</str<strong>on</strong>g> refractory lining has to<br />
work, traditi<strong>on</strong>al lining soluti<strong>on</strong>s can no<br />
l<strong>on</strong>ger be relied up<strong>on</strong> to provide <str<strong>on</strong>g>the</str<strong>on</strong>g> service<br />
lives that were previously achieved.<br />
Therefore, a new generati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> furnace<br />
lining materials is required to cope with<br />
today’s <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> furnace. This work<br />
reports <strong>on</strong> a new m<strong>on</strong>olithic material<br />
with improved performance, compared to<br />
existing materials, designed for use in <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
ramp/hearth area <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> furnaces.<br />
Improved behaviour against <str<strong>on</strong>g>the</str<strong>on</strong>g> critical<br />
performance criteria in this furnace regi<strong>on</strong><br />
are dem<strong>on</strong>strated in <str<strong>on</strong>g>the</str<strong>on</strong>g> laboratory<br />
using industry standard test methods.<br />
The refractory lining <str<strong>on</strong>g>of</str<strong>on</strong>g> a typical furnace<br />
used for holding and melting <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> has<br />
to withstand a wide variety <str<strong>on</strong>g>of</str<strong>on</strong>g> physical and<br />
chemical envir<strong>on</strong>ments. Each <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> different<br />
areas within <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace (Fig. 1) presents a different<br />
set <str<strong>on</strong>g>of</str<strong>on</strong>g> operating c<strong>on</strong>diti<strong>on</strong>s, in terms <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
peak temperature, metal c<strong>on</strong>tact, salt c<strong>on</strong>tact,<br />
etc. Therefore, in order for a m<strong>on</strong>olithic material<br />
to perform in a particular area <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
furnace, it needs to cope with <str<strong>on</strong>g>the</str<strong>on</strong>g> specific<br />
envir<strong>on</strong>mental c<strong>on</strong>diti<strong>on</strong>s in that regi<strong>on</strong>. This<br />
is why furnace linings are complex arrangements,<br />
with different materials installed in different<br />
locati<strong>on</strong>s [1].<br />
Background: In <str<strong>on</strong>g>the</str<strong>on</strong>g> last 30 years, a group <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
m<strong>on</strong>olithic technologies has emerged, specifically<br />
designed to perform within <str<strong>on</strong>g>the</str<strong>on</strong>g> unique<br />
envir<strong>on</strong>ment <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> melt-hold fur-<br />
naces. These Al-resistant grades <str<strong>on</strong>g>of</str<strong>on</strong>g>ten c<strong>on</strong>tain<br />
‘n<strong>on</strong>-wetting’ additives, particularly in <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
metal c<strong>on</strong>tact areas, to minimize interacti<strong>on</strong><br />
between <str<strong>on</strong>g>the</str<strong>on</strong>g> refractory and <str<strong>on</strong>g>the</str<strong>on</strong>g> melt to suppress<br />
damage from ‘corundum growth’ [2].<br />
As <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> producers strive to increase<br />
productivity, <str<strong>on</strong>g>the</str<strong>on</strong>g> envir<strong>on</strong>ment within <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace<br />
is becoming more arduous. Chamber<br />
temperatures are increasing and more aggressive<br />
fluxes are being used, necessitating more<br />
frequent and severe cleaning operati<strong>on</strong>s <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> furnace walls. To maintain high productivity,<br />
it is necessary to minimize <str<strong>on</strong>g>the</str<strong>on</strong>g> frequency<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> furnace downtime. The more aggressive<br />
c<strong>on</strong>diti<strong>on</strong>s today mean that lining materials<br />
developed in <str<strong>on</strong>g>the</str<strong>on</strong>g> past are now being used be-<br />
y<strong>on</strong>d <str<strong>on</strong>g>the</str<strong>on</strong>g>ir original intended design boundaries<br />
and <str<strong>on</strong>g>the</str<strong>on</strong>g>ir service performance is under threat,<br />
leading to more frequent lining repairs.<br />
Aluminium producers take a furnace <str<strong>on</strong>g>of</str<strong>on</strong>g>fline<br />
for repair <strong>on</strong>ce a critical lining area has degraded<br />
to <str<strong>on</strong>g>the</str<strong>on</strong>g> point <str<strong>on</strong>g>of</str<strong>on</strong>g> affecting <str<strong>on</strong>g>the</str<strong>on</strong>g> efficiency<br />
and/or safety <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> operati<strong>on</strong>. At this stage,<br />
not all <str<strong>on</strong>g>the</str<strong>on</strong>g> lining will have degraded to <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
point that it is in need <str<strong>on</strong>g>of</str<strong>on</strong>g> replacement or repair.<br />
Therefore, <str<strong>on</strong>g>the</str<strong>on</strong>g> frequency <str<strong>on</strong>g>of</str<strong>on</strong>g> furnace down-<br />
time is determined by <str<strong>on</strong>g>the</str<strong>on</strong>g> area <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace<br />
most quickly and frequently degraded during<br />
operati<strong>on</strong>. In order to increase campaign<br />
times and decrease frequency <str<strong>on</strong>g>of</str<strong>on</strong>g> stoppages,<br />
we need to improve <str<strong>on</strong>g>the</str<strong>on</strong>g> service life <str<strong>on</strong>g>of</str<strong>on</strong>g> this<br />
weak link in <str<strong>on</strong>g>the</str<strong>on</strong>g> lining. To identify <str<strong>on</strong>g>the</str<strong>on</strong>g> regi<strong>on</strong><br />
most frequently and quickly degraded, we<br />
worked with several <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> producers.<br />
Their feedback suggested that <str<strong>on</strong>g>the</str<strong>on</strong>g> most comm<strong>on</strong><br />
area that was <str<strong>on</strong>g>the</str<strong>on</strong>g> cause <str<strong>on</strong>g>of</str<strong>on</strong>g> repair downtime<br />
was <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp / hearth area.<br />
The failure mechanisms within <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace<br />
envir<strong>on</strong>ment, that limit refractory service life,<br />
are listed in [1]. Since our target is to improve<br />
refractory performance in <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp / hearth<br />
regi<strong>on</strong>, we need to understand which <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g>se<br />
failure modes are most critical to lining performance<br />
in this regi<strong>on</strong>.<br />
Performance targets: A study <str<strong>on</strong>g>of</str<strong>on</strong>g> working<br />
practices and furnace operating c<strong>on</strong>diti<strong>on</strong>s at<br />
MEASURING & CONTROL<br />
a number <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> producers revealed<br />
that <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp / hearth regi<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> an <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
melt-hold furnace is subjected to severe mechanical<br />
and <str<strong>on</strong>g>the</str<strong>on</strong>g>rmal stress during <str<strong>on</strong>g>the</str<strong>on</strong>g> loading<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> large ingot down <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp. Frequent loading<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> heavy ingot to feed <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace, <str<strong>on</strong>g>of</str<strong>on</strong>g>ten<br />
by fork lift truck, subjects <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp to severe<br />
abrasive forces. As <str<strong>on</strong>g>the</str<strong>on</strong>g> ingot is usually at room<br />
temperature, <str<strong>on</strong>g>the</str<strong>on</strong>g>re is also c<strong>on</strong>siderable <str<strong>on</strong>g>the</str<strong>on</strong>g>r-<br />
mal shock <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp / hearth refractory,<br />
which is at furnace operating temperature.<br />
As <str<strong>on</strong>g>the</str<strong>on</strong>g> bottom <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp and <str<strong>on</strong>g>the</str<strong>on</strong>g> complete<br />
hearth are in c<strong>on</strong>tact with molten metal, <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
refractory is also subject to chemical attack<br />
from <str<strong>on</strong>g>the</str<strong>on</strong>g> alloy, alloying elements and flux additi<strong>on</strong>s.<br />
A study <str<strong>on</strong>g>of</str<strong>on</strong>g> ramp / hearth degradati<strong>on</strong><br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> Al-resistant materials c<strong>on</strong>taining ‘n<strong>on</strong>-wetting’<br />
additives suggested that damage leading<br />
to furnace downtime is mostly due to <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
mechanical acti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> erosi<strong>on</strong> and <str<strong>on</strong>g>the</str<strong>on</strong>g>rmal<br />
shock from ingot loading. We <str<strong>on</strong>g>the</str<strong>on</strong>g>refore focused<br />
our work <strong>on</strong> developing a new Al-resistant<br />
material with improved abrasi<strong>on</strong> and<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g>rmal shock resistance. To achieve significant<br />
improvements in performance we set out<br />
to increase abrasi<strong>on</strong> and <str<strong>on</strong>g>the</str<strong>on</strong>g>rmal shock resistance<br />
by 20% compared to existing materials.<br />
As metal and alkali resistance are sec<strong>on</strong>dary<br />
performance parameters in this furnace regi<strong>on</strong>,<br />
we also had to ensure that any changes<br />
we made to <str<strong>on</strong>g>the</str<strong>on</strong>g> materials did not degrade<br />
chemical resistance.<br />
EXPERIMENTAL<br />
Fig. 1: Furnace<br />
lining z<strong>on</strong>es in a<br />
typical <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
melt-hold furnace<br />
Two existing, industry leading Al-resistant<br />
m<strong>on</strong>olithic materials used by many <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
producers in <str<strong>on</strong>g>the</str<strong>on</strong>g> ramp / hearth area <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
<strong>ALU</strong>MINIUM · EAC CONGRESS 2011 19<br />
Images: Thermal Ceramics