Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
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MELTING, RECYCLING & HEAT TREATMENT<br />
The new generati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
heat treatment plants – a vanguard c<strong>on</strong>cept<br />
Markus Belte and Dan Dragulin, Belte AG<br />
The vigorous discussi<strong>on</strong> in <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
heat treatment community about <str<strong>on</strong>g>the</str<strong>on</strong>g> development<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> appropriate technique<br />
becomes within <str<strong>on</strong>g>the</str<strong>on</strong>g> framework <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
present work a genuine c<strong>on</strong>crete answer.<br />
This paper is completely dedicated to <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
presentati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> a new generati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> heat<br />
treatment plants; it first introduces <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
fundamentals <str<strong>on</strong>g>of</str<strong>on</strong>g> high speed heat transfer<br />
processes and presents practical results<br />
and <str<strong>on</strong>g>the</str<strong>on</strong>g>irs <str<strong>on</strong>g>the</str<strong>on</strong>g>rmodynamical analysis and<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g>n <str<strong>on</strong>g>of</str<strong>on</strong>g>fers a detailed perspective <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
vanguard c<strong>on</strong>cept <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> new generati<strong>on</strong><br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> heat treatment plants. The<br />
present work is based <strong>on</strong> original experiments<br />
and investigati<strong>on</strong>s obtained by <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
authors and will present techniques never<br />
used before in <str<strong>on</strong>g>the</str<strong>on</strong>g> industrial heat treatment<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g>.<br />
Infrared radiati<strong>on</strong> – <str<strong>on</strong>g>the</str<strong>on</strong>g>oretical aspects<br />
The radiati<strong>on</strong> heat transfer process is described<br />
by <str<strong>on</strong>g>the</str<strong>on</strong>g> law <str<strong>on</strong>g>of</str<strong>on</strong>g> Stefan-Boltzmann:<br />
• ∂Q<br />
Q = ⎯⎯ = εσST 4<br />
∂t (1)<br />
• 4 4<br />
Q = εσS [T O - T U ] (2)<br />
•<br />
Where: Q = heat flow rate; ε = emissivity 1 ;<br />
σ = 5.67 x 10 -8 W/m 2 K 4 Stefan-Boltzmannc<strong>on</strong>stant;<br />
S = surface <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> emitting body;<br />
T = temperature <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> emitting body (Kelvin);<br />
T O = surface temperature; T U = envir<strong>on</strong>ment<br />
temperature 2 .<br />
The heating rate can be calculated using <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
following formula:<br />
mc 100 TWB Ta<br />
τ = ⎯ ⎯⎯ [ ξ´(⎯⎯)- ξ´´ (⎯⎯)]<br />
α T 3<br />
U<br />
TU TU (⎯⎯)<br />
100<br />
(3) 3<br />
Where: m = mass/surface unity <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> product<br />
to be heated; c =specific heat; TWB = heat<br />
treatment temperature; TU = envir<strong>on</strong>ment temperature;<br />
ξ = f(TWB/TU) A special case <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> heat transfer process<br />
is <str<strong>on</strong>g>the</str<strong>on</strong>g> infrared heat transfer process.<br />
“Infrared radiati<strong>on</strong>, that porti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
electromagnetic spectrum that extends from<br />
1 ε Є (0,1] ; for <str<strong>on</strong>g>the</str<strong>on</strong>g> ideal black body: ε = 1<br />
2 The envir<strong>on</strong>ment could be <str<strong>on</strong>g>the</str<strong>on</strong>g> interior <str<strong>on</strong>g>of</str<strong>on</strong>g> a furnace.<br />
3 According to [3]<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> l<strong>on</strong>g wavelength, or red, end <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> visiblelight<br />
range to <str<strong>on</strong>g>the</str<strong>on</strong>g> microwave range. Invisible<br />
to <str<strong>on</strong>g>the</str<strong>on</strong>g> eye, it can be detected as a sensati<strong>on</strong><br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> warmth <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> skin. The infrared range<br />
is usually divided into three regi<strong>on</strong>s: near<br />
infrared (nearest <str<strong>on</strong>g>the</str<strong>on</strong>g> visible spectrum), with<br />
wavelengths 0.78 to about 2.5 micrometres (a<br />
micrometre, or micr<strong>on</strong>, is 10 -6 metre); middle<br />
infrared, with wavelengths 2.5 to about 50 micrometres;<br />
and far infrared, with wavelengths<br />
50 to 1,000 micrometres. Most <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> radiati<strong>on</strong><br />
emitted by a moderately heated surface is infrared;<br />
it forms a c<strong>on</strong>tinuous spectrum. Molecular<br />
excitati<strong>on</strong> also produces copious infrared<br />
radiati<strong>on</strong> but in a discrete spectrum <str<strong>on</strong>g>of</str<strong>on</strong>g> lines or<br />
bands.” [Encyclopaedia Britannica [1]]<br />
“Radiant heating has been used in <str<strong>on</strong>g>the</str<strong>on</strong>g> industry<br />
since <str<strong>on</strong>g>the</str<strong>on</strong>g> 1930s, where it was introduced to<br />
bake finishes <strong>on</strong> cars. It took time for <str<strong>on</strong>g>the</str<strong>on</strong>g> new<br />
technology to gain acceptance but today <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
technology is used in most industrialised countries<br />
especially for drying and curing <str<strong>on</strong>g>of</str<strong>on</strong>g> paints<br />
and drying <str<strong>on</strong>g>of</str<strong>on</strong>g> textile, pulp and paper. Infrared<br />
energy is unique because it can heat materials<br />
or objects without heating <str<strong>on</strong>g>the</str<strong>on</strong>g> air around <str<strong>on</strong>g>the</str<strong>on</strong>g>m.<br />
That allows infrared heat to be c<strong>on</strong>centrated<br />
exactly where it is wanted without much loss<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> energy.” [2]<br />
In <str<strong>on</strong>g>the</str<strong>on</strong>g> case <str<strong>on</strong>g>of</str<strong>on</strong>g> an infrared heating <str<strong>on</strong>g>the</str<strong>on</strong>g> maxi-<br />
mum temperature which can be reached depends<br />
<strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> envir<strong>on</strong>ment temperature:<br />
T - T U = (T max - T U)(1-e -B . τ ) (4) [3]<br />
Where: T = body temperature; τ = durati<strong>on</strong>;<br />
T U = envir<strong>on</strong>ment temperature; T max = maximum<br />
temperature; B = coefficient which takes<br />
into account <str<strong>on</strong>g>the</str<strong>on</strong>g> process c<strong>on</strong>diti<strong>on</strong>s<br />
In <str<strong>on</strong>g>the</str<strong>on</strong>g> case <str<strong>on</strong>g>of</str<strong>on</strong>g> a classic heat transfer process<br />
performed exclusively through air c<strong>on</strong>vecti<strong>on</strong>,<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> body temperature can not exceed <str<strong>on</strong>g>the</str<strong>on</strong>g> air<br />
temperature.<br />
Gas radiati<strong>on</strong><br />
In <str<strong>on</strong>g>the</str<strong>on</strong>g> case <str<strong>on</strong>g>of</str<strong>on</strong>g> flame radiati<strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g>re are two<br />
types radiati<strong>on</strong>: visible and invisible/infrared<br />
radiati<strong>on</strong>. The last <strong>on</strong>e is <str<strong>on</strong>g>the</str<strong>on</strong>g> invisible infrared<br />
radiati<strong>on</strong> emitted by carb<strong>on</strong> di<str<strong>on</strong>g>oxide</str<strong>on</strong>g> and<br />
steam 4 .<br />
The quantity <str<strong>on</strong>g>of</str<strong>on</strong>g> heat transferred through<br />
radiati<strong>on</strong> from a <str<strong>on</strong>g>layer</str<strong>on</strong>g> <str<strong>on</strong>g>of</str<strong>on</strong>g> CO 2 respectively H 2O<br />
to a grey surface are:<br />
3.2 3.2<br />
Tg Tw<br />
qCO2 = ε . 10.35(p .<br />
CO2 s) 0.4 [(⎯⎯) - (⎯⎯)<br />
100 100<br />
Tg<br />
0.65<br />
. (⎯) ] Tw 4 After J. H. Brunklaus<br />
Fig. 1: Bilateral (green) and unilateral (red) exposure to radiati<strong>on</strong> (not coated, h = 10 cm)<br />
(5)[[7]→[6]]<br />
60 <strong>ALU</strong>MINIUM · EAC CONGRESS 2011<br />
Abbildungen: Belte