Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
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APPLICATION-ORIENTED TECHNOLOGIES<br />
Soldering and brazing <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> and its alloys<br />
Christian Eisenbeis, SLV Duisburg<br />
The joining <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> always requires<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> use <str<strong>on</strong>g>of</str<strong>on</strong>g> special technologies. In particular,<br />
soldering and brazing techniques<br />
need special experience in order to obtain<br />
joints <str<strong>on</strong>g>of</str<strong>on</strong>g> good quality and sufficient<br />
strength. In additi<strong>on</strong>, <str<strong>on</strong>g>the</str<strong>on</strong>g>re is <str<strong>on</strong>g>of</str<strong>on</strong>g>ten a<br />
good chance to use <str<strong>on</strong>g>the</str<strong>on</strong>g> brazing technologies<br />
for an efficient and highly mechanized<br />
fabricati<strong>on</strong> process. Compared with<br />
welding, soldering and brazing allow<br />
appropriate higher or lower process-temperatures,<br />
depending <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> type <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
<str<strong>on</strong>g>aluminium</str<strong>on</strong>g> base metal. The market <str<strong>on</strong>g>of</str<strong>on</strong>g>fers<br />
new and improved filler metals and fluxes,<br />
and – at <str<strong>on</strong>g>the</str<strong>on</strong>g> same time – <str<strong>on</strong>g>the</str<strong>on</strong>g> demands<br />
<strong>on</strong> quality and strength <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> brazed <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
joints have increased. Traditi<strong>on</strong>al<br />
and highly developed procedures like<br />
flame brazing, resistant brazing, or c<strong>on</strong>trolled-arc-brazing<br />
are available ei<str<strong>on</strong>g>the</str<strong>on</strong>g>r<br />
for simple or sophisticated brazed comp<strong>on</strong>ents<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g>. In this presentati<strong>on</strong><br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> basics and <str<strong>on</strong>g>the</str<strong>on</strong>g> technical soluti<strong>on</strong>s will<br />
be explained and illustrated by figures<br />
and practical examples.<br />
1. The brazing process<br />
For soldering and brazing unlike welding an<br />
additi<strong>on</strong>al brazing filler metal is used whose<br />
melting temperature (or melting range) is<br />
below <str<strong>on</strong>g>the</str<strong>on</strong>g> melting temperature <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> parent<br />
metal. The joining surfaces <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> parent metals<br />
are wetted by <str<strong>on</strong>g>the</str<strong>on</strong>g> liquid braze without being<br />
molten <str<strong>on</strong>g>the</str<strong>on</strong>g>mselves.<br />
As a result, <str<strong>on</strong>g>the</str<strong>on</strong>g> following aspects are <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
importance:<br />
• It is possible to join dissimilar metals and<br />
metal alloys, respectively<br />
• Due to <str<strong>on</strong>g>the</str<strong>on</strong>g> relatively low process tempera-<br />
ture <str<strong>on</strong>g>the</str<strong>on</strong>g> comp<strong>on</strong>ent is less <str<strong>on</strong>g>the</str<strong>on</strong>g>rmally<br />
influenced<br />
• The amount <str<strong>on</strong>g>of</str<strong>on</strong>g> filler metal is relatively<br />
small<br />
• The rapid sequence <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> brazing process<br />
• Low distorti<strong>on</strong> compared with welding<br />
• Brazing/soldering <str<strong>on</strong>g>of</str<strong>on</strong>g> a variety <str<strong>on</strong>g>of</str<strong>on</strong>g> areas to<br />
be joined at <str<strong>on</strong>g>the</str<strong>on</strong>g> same time.<br />
The joint is built up by <str<strong>on</strong>g>the</str<strong>on</strong>g> exchange <str<strong>on</strong>g>of</str<strong>on</strong>g> diffusi<strong>on</strong><br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> metals within a small z<strong>on</strong>e (Fig.<br />
1). To enable this diffusi<strong>on</strong>-mechanism, <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
surface <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> joining area must be free from<br />
<str<strong>on</strong>g>oxide</str<strong>on</strong>g>s and be protected against <str<strong>on</strong>g>the</str<strong>on</strong>g> renewed<br />
formati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>oxide</str<strong>on</strong>g>s during soldering/brazing.<br />
Therefore, <str<strong>on</strong>g>the</str<strong>on</strong>g>re are two prec<strong>on</strong>diti<strong>on</strong>s to be<br />
fulfilled when brazing, using a flux:<br />
• The melting temperature <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> braze<br />
must be below <str<strong>on</strong>g>the</str<strong>on</strong>g> melting temperature<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> parent metal<br />
• The surface <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> material must be<br />
completely free from <str<strong>on</strong>g>oxide</str<strong>on</strong>g>s<br />
• <str<strong>on</strong>g>the</str<strong>on</strong>g> flux must be intensive enough having<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> adequate effective temperature.<br />
2. The process ranges<br />
Brazing <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> is classified into brazing<br />
and soldering. At brazing, filler metals with<br />
melting temperatures above 450°C are used.<br />
Solders, having a melting point below 450°C,<br />
are called solder filler metals and <str<strong>on</strong>g>the</str<strong>on</strong>g> process<br />
is called soldering or s<str<strong>on</strong>g>of</str<strong>on</strong>g>t-soldering.<br />
The process temperature can be freely<br />
chosen, but it must be within <str<strong>on</strong>g>the</str<strong>on</strong>g> solidus temperature<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> filler metal and <str<strong>on</strong>g>the</str<strong>on</strong>g> melting<br />
temperature <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> parent metal. The flux will<br />
be chosen matching <str<strong>on</strong>g>the</str<strong>on</strong>g> soldering or brazing<br />
temperature; <str<strong>on</strong>g>the</str<strong>on</strong>g> effective temperature and<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> chemical intensity must be coordinated<br />
with <str<strong>on</strong>g>the</str<strong>on</strong>g> soldering/brazing process.<br />
More generally, <str<strong>on</strong>g>the</str<strong>on</strong>g> higher <str<strong>on</strong>g>the</str<strong>on</strong>g> brazing<br />
temperature, <str<strong>on</strong>g>the</str<strong>on</strong>g> higher is <str<strong>on</strong>g>the</str<strong>on</strong>g> mechanical<br />
strength.<br />
3. Structural requirements <strong>on</strong> brazing<br />
During brazing usually a brazing gap is produced<br />
by a braze drawn into <str<strong>on</strong>g>the</str<strong>on</strong>g> gap due to<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> capillary forces (capillary brazing). The<br />
braze displaces <str<strong>on</strong>g>the</str<strong>on</strong>g> flux as so<strong>on</strong> as <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>oxide</str<strong>on</strong>g>s<br />
are dissolved <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> joining surface. A relatively<br />
large-surface joint is produced and <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
braze <str<strong>on</strong>g>layer</str<strong>on</strong>g> located in <str<strong>on</strong>g>the</str<strong>on</strong>g> soldering gap will<br />
be mechanically streng<str<strong>on</strong>g>the</str<strong>on</strong>g>ned if a load is exerted<br />
<strong>on</strong> it. By this means c<strong>on</strong>siderable forces<br />
may be exerted that are able to exceed <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
strength <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> parent metal.<br />
4. Properties <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g> brazed joints<br />
4.1 Brazed joints: The strength <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
brazed joint <str<strong>on</strong>g>of</str<strong>on</strong>g>ten is <str<strong>on</strong>g>the</str<strong>on</strong>g> same as a<br />
welded joint if <str<strong>on</strong>g>the</str<strong>on</strong>g> ‘joint is suitable for brazing’.<br />
During brazing <str<strong>on</strong>g>of</str<strong>on</strong>g> Al-materials <str<strong>on</strong>g>of</str<strong>on</strong>g> higher<br />
strength as well as <str<strong>on</strong>g>of</str<strong>on</strong>g> Al-cast alloys <str<strong>on</strong>g>the</str<strong>on</strong>g>re is<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> risk <str<strong>on</strong>g>of</str<strong>on</strong>g> a melt down <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> surfaces to be<br />
joined since <str<strong>on</strong>g>the</str<strong>on</strong>g> melting temperature <str<strong>on</strong>g>of</str<strong>on</strong>g> such<br />
type <str<strong>on</strong>g>of</str<strong>on</strong>g> alloys can be near <str<strong>on</strong>g>the</str<strong>on</strong>g> melting point <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> brazing filler metal. The chemical resistance<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> a brazed joint <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> comm<strong>on</strong>ly used<br />
braze material Al88Si is not worse than that<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> a welded joint. It is true that brazed joints<br />
can be anodized, but in <str<strong>on</strong>g>the</str<strong>on</strong>g> joining area (braze<br />
<str<strong>on</strong>g>layer</str<strong>on</strong>g>) <str<strong>on</strong>g>the</str<strong>on</strong>g>y will get a darker colour.<br />
4.2 Soldered joints: Both, strength and corrosi<strong>on</strong><br />
resistance <str<strong>on</strong>g>of</str<strong>on</strong>g> soldered joints are much<br />
lower. A dry envir<strong>on</strong>ment or corrosi<strong>on</strong> protecti<strong>on</strong><br />
(lacquering, greasing) will <str<strong>on</strong>g>the</str<strong>on</strong>g>n become<br />
necessary. It is nei<str<strong>on</strong>g>the</str<strong>on</strong>g>r possible to<br />
perform anodic oxidati<strong>on</strong> nor to have oper-<br />
ating temperatures c<strong>on</strong>siderably above<br />
100°C.<br />
Fig. 1: Built-up <str<strong>on</strong>g>of</str<strong>on</strong>g> a brazed joint by diffusi<strong>on</strong> (Source: Hydro Aluminium)<br />
54 <strong>ALU</strong>MINIUM · EAC CONGRESS 2011