Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
Influence of the natural aluminium oxide layer on ... - ALU-WEB.DE
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<str<strong>on</strong>g>Influence</str<strong>on</strong>g> <str<strong>on</strong>g>of</str<strong>on</strong>g> raw material c<strong>on</strong>stituti<strong>on</strong> <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> quality <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
gloss alloy-type extrusi<strong>on</strong> billets – a report from practice<br />
Klaus H<str<strong>on</strong>g>of</str<strong>on</strong>g>fmann, Ralf Munk, Marcel Rosefort and Dietmar Bramh<str<strong>on</strong>g>of</str<strong>on</strong>g>f, Trimet Aluminium AG<br />
The Trimet group provides <str<strong>on</strong>g>the</str<strong>on</strong>g> <str<strong>on</strong>g>aluminium</str<strong>on</strong>g><br />
processing industry with primary metal,<br />
alloys, semi-finished products, castings<br />
and recycling. The competences <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
business unit Primary Products are electrolysis<br />
and c<strong>on</strong>tinuous casting. Products<br />
are rolling slabs, extrusi<strong>on</strong> and forging<br />
billets, hot dip-coating alloys, initial products<br />
for safety parts and liquid <str<strong>on</strong>g>aluminium</str<strong>on</strong>g>.<br />
Due to <str<strong>on</strong>g>the</str<strong>on</strong>g> demand for high quality<br />
and services regarding <str<strong>on</strong>g>the</str<strong>on</strong>g>se products in<br />
particular <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> automotive industry it<br />
is essential to enforce and secure quality<br />
c<strong>on</strong>trol. All <str<strong>on</strong>g>the</str<strong>on</strong>g>se high quality products<br />
from Trimet, especially <str<strong>on</strong>g>the</str<strong>on</strong>g> safety parts,<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> gloss alloys and parts with functi<strong>on</strong>al<br />
surfaces for automotive applicati<strong>on</strong>s, are<br />
characterized by an extremely homogenous<br />
microstructure without<br />
internal defects or inclusi<strong>on</strong>s.<br />
Within our permanent quality<br />
improvement programme an examinati<strong>on</strong><br />
has been carried out to<br />
measure <str<strong>on</strong>g>the</str<strong>on</strong>g> influence <str<strong>on</strong>g>of</str<strong>on</strong>g> raw material<br />
c<strong>on</strong>stituti<strong>on</strong> <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> product<br />
quality. Therefore <str<strong>on</strong>g>the</str<strong>on</strong>g> use <str<strong>on</strong>g>of</str<strong>on</strong>g> liquid<br />
metal, ingot metal and mixtures <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
<str<strong>on</strong>g>the</str<strong>on</strong>g>se has been tested. The paper<br />
covers <str<strong>on</strong>g>the</str<strong>on</strong>g> essential producti<strong>on</strong><br />
steps for such challenging high<br />
quality billets. It gives a report<br />
<strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> quality requirements, <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
qualifying <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> alloying material and <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
process parameters. Especially <str<strong>on</strong>g>the</str<strong>on</strong>g> methods<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> analysis, like PoDFa and inclusi<strong>on</strong><br />
identificati<strong>on</strong>, and <str<strong>on</strong>g>the</str<strong>on</strong>g> correlati<strong>on</strong>s between<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> process parameters, <str<strong>on</strong>g>the</str<strong>on</strong>g> feedstock<br />
and metal quality are described.<br />
The market for extrusi<strong>on</strong> billets for bright surface<br />
products in Europe is bigger than 15,000<br />
t<strong>on</strong>nes a year. The highest demand for this<br />
special material comes from <str<strong>on</strong>g>the</str<strong>on</strong>g> automotive<br />
industry. There it is used for trim parts, ro<str<strong>on</strong>g>of</str<strong>on</strong>g><br />
racks and cover plates. But <str<strong>on</strong>g>the</str<strong>on</strong>g>re is also a<br />
market for this material in <str<strong>on</strong>g>the</str<strong>on</strong>g> lighting and audio<br />
industry. One can say that <str<strong>on</strong>g>the</str<strong>on</strong>g> time <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
black coated trims is over – for <str<strong>on</strong>g>the</str<strong>on</strong>g> moment.<br />
To fulfil <str<strong>on</strong>g>the</str<strong>on</strong>g> very challenging specificati<strong>on</strong>s<br />
for <str<strong>on</strong>g>the</str<strong>on</strong>g> final parts, <str<strong>on</strong>g>the</str<strong>on</strong>g> whole process from <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
alumina for <str<strong>on</strong>g>the</str<strong>on</strong>g> electrolyses up to <str<strong>on</strong>g>the</str<strong>on</strong>g> anodising<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> final part has to be fully tuned and<br />
straight designed. All changes in this process<br />
chain have to be scrutinised, and all changes<br />
have to be discussed and well co-ordinated<br />
between <str<strong>on</strong>g>the</str<strong>on</strong>g> partners <str<strong>on</strong>g>of</str<strong>on</strong>g> this sensitive process<br />
chain.<br />
So, why change such a sensitive process?<br />
If we want to improve <str<strong>on</strong>g>the</str<strong>on</strong>g> quality <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> end<br />
product, we will have to change <str<strong>on</strong>g>the</str<strong>on</strong>g> process<br />
from time to time, or <str<strong>on</strong>g>the</str<strong>on</strong>g>re are technical needs<br />
to change a step in <str<strong>on</strong>g>the</str<strong>on</strong>g> process. This paper discusses<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> influence <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> solid/liquid metal<br />
ratio.<br />
The trimal BQ process<br />
Trimet developed a special process named BQ<br />
(Brilliant Quality) to fulfil all <str<strong>on</strong>g>the</str<strong>on</strong>g>se requirements<br />
for a brilliant end product.<br />
The trimal BQ process is a special process<br />
for producing extrusi<strong>on</strong> billets, to fulfil high<br />
requirements and to cover all <str<strong>on</strong>g>the</str<strong>on</strong>g> producti<strong>on</strong><br />
steps and parameters that are adjusted for <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
end product: <str<strong>on</strong>g>the</str<strong>on</strong>g> alumina, melting, casting, homogenizing,<br />
testing.<br />
This process includes all parts <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> pro-<br />
Producti<strong>on</strong> flow in <str<strong>on</strong>g>the</str<strong>on</strong>g> casthouse<br />
Images: Trimet<br />
EXTRUSION<br />
ducti<strong>on</strong> chain starting with <str<strong>on</strong>g>the</str<strong>on</strong>g> alumina and<br />
anodes for <str<strong>on</strong>g>the</str<strong>on</strong>g> electrolysis at <str<strong>on</strong>g>the</str<strong>on</strong>g> Essen or<br />
Hamburg smelter to produce <str<strong>on</strong>g>the</str<strong>on</strong>g> liquid and<br />
solid raw material. Followed by alloying, metal<br />
treatment, grain refining and casting, finished<br />
up with <str<strong>on</strong>g>the</str<strong>on</strong>g> customised homogenizing process<br />
unique for <str<strong>on</strong>g>the</str<strong>on</strong>g>se billets.<br />
The electrolysis process<br />
At <str<strong>on</strong>g>the</str<strong>on</strong>g> electrolysis <str<strong>on</strong>g>the</str<strong>on</strong>g>re are several pots operated<br />
as high purity pots. For <str<strong>on</strong>g>the</str<strong>on</strong>g>se pots <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
alumina is not used in <str<strong>on</strong>g>the</str<strong>on</strong>g> waste gas purificati<strong>on</strong><br />
process to avoid <str<strong>on</strong>g>the</str<strong>on</strong>g> enrichment <str<strong>on</strong>g>of</str<strong>on</strong>g> o<str<strong>on</strong>g>the</str<strong>on</strong>g>r<br />
elements. The anodes are hand selected according<br />
to <str<strong>on</strong>g>the</str<strong>on</strong>g>ir metal c<strong>on</strong>tent and <str<strong>on</strong>g>the</str<strong>on</strong>g>ir operating<br />
life in <str<strong>on</strong>g>the</str<strong>on</strong>g> cells is shorter than in <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
standard pots.<br />
The c<strong>on</strong>trol <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> pots is d<strong>on</strong>e by<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> Trimet 9-box matrix model [1]. This<br />
is increasing current efficiency and reducing<br />
energy c<strong>on</strong>sumpti<strong>on</strong>. After <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
transport, crucible with <str<strong>on</strong>g>the</str<strong>on</strong>g> pot room<br />
metal is arriving at <str<strong>on</strong>g>the</str<strong>on</strong>g> casthouse <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
dross is accurately removed from <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
metal surface. Now <str<strong>on</strong>g>the</str<strong>on</strong>g> metal is transferred<br />
to <strong>on</strong>e <str<strong>on</strong>g>of</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> melting furnaces or<br />
casted into sow forms.<br />
Melting and casting<br />
The process in <str<strong>on</strong>g>the</str<strong>on</strong>g> casthouse (see flow<br />
chart) starts with <str<strong>on</strong>g>the</str<strong>on</strong>g> loading <str<strong>on</strong>g>of</str<strong>on</strong>g> solid metal into<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> gas fired melting furnace. When <str<strong>on</strong>g>the</str<strong>on</strong>g> solid<br />
metal is heated up to <str<strong>on</strong>g>the</str<strong>on</strong>g> required temperature<br />
<str<strong>on</strong>g>the</str<strong>on</strong>g> hot pot room metal (approx. 930°C)<br />
is added to <str<strong>on</strong>g>the</str<strong>on</strong>g> furnace. In this step we use <str<strong>on</strong>g>the</str<strong>on</strong>g><br />
energy which is stored in <str<strong>on</strong>g>the</str<strong>on</strong>g> pot room metal<br />
to bring <str<strong>on</strong>g>the</str<strong>on</strong>g> sows into <str<strong>on</strong>g>the</str<strong>on</strong>g> liquid state. The liq-<br />
<strong>ALU</strong>MINIUM · EAC CONGRESS 2011 31