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well as in <strong>the</strong> tube-to-header joints<br />

of <strong>the</strong> manifold section. The tube-to-<br />

header joint,s could be repaired by<br />

rebrazing, but <strong>the</strong> leaks in <strong>the</strong> body<br />

of <strong>the</strong> unit are almost impossible to<br />

repair successfully.<br />

Examination of <strong>the</strong> completed unit,<br />

revealed several probable causes for<br />

<strong>the</strong> leaks and excessive distortion.<br />

This examination has led to techniques<br />

for overcoming <strong>the</strong>se flaws in future<br />

brazing operations. The tube-to-fin<br />

leaks were thought to be caused by<br />

excessive use of Nicrohraz alloy,<br />

with <strong>the</strong> resultant dissolving away of<br />

<strong>the</strong> tube walls. The bad distortion<br />

a1 so tended to aggravate this situ-<br />

ation by allowing puddling of <strong>the</strong><br />

molten brazing alloy. The formation<br />

of "hot spots" in <strong>the</strong> body of <strong>the</strong><br />

assembly was also thought to he a<br />

prevalent condition. A very rapid<br />

heating rate was also an important<br />

factor in <strong>the</strong> warpage.<br />

Techniqucs that are planned for<br />

incorporation in fur<strong>the</strong>r brazing<br />

operations are <strong>the</strong> use of lesser<br />

quantities of Nicrobraz, <strong>the</strong> use of<br />

several aspirators to promote more<br />

even hydragen flow between <strong>the</strong> €ins,<br />

<strong>the</strong> build-up of <strong>the</strong> whole assembly off<br />

<strong>the</strong> can hottom to overcome <strong>the</strong> drastic<br />

initial heating rate, and <strong>the</strong> use of<br />

a slightly lower brazing temperature.<br />

Brazing of Copper to Inconef, The<br />

need for a Satisfactory brazing alloy<br />

for joining copper fins to Inconel<br />

tubing has been emphasized. The<br />

resultant braze should have relatively<br />

high strength at 1500°F and should<br />

also be a diffusion barrier against<br />

capper penetration into <strong>the</strong> Inconel<br />

during service. It seems likely that<br />

some alloy o<strong>the</strong>r than a copper-base<br />

alloy would best fill <strong>the</strong>se require-<br />

ments. Nicrobrazing at 1900°F is very<br />

promising, but <strong>the</strong> alloy does not<br />

completely me1 t at this temperature.<br />

It is hoped, however, that <strong>the</strong> use of<br />

o<strong>the</strong>r alloys very similar in compo-<br />

sition to Nicrobraz but of somewhat<br />

PERIOD ENQING DECEMBER 10, 1952<br />

lower melting point w i l l result in a<br />

satisfactory brazed joint.<br />

In view of <strong>the</strong> possibility that it<br />

might be advisable to use copper-base<br />

alloy for <strong>the</strong> production of <strong>the</strong>se<br />

tube-to-fin joints, several such<br />

alloys are being investigated. Small<br />

m e l t s of Cu-Re, Cu-Si, Cu-Sn, and<br />

Cu-Mn alloys have been prepared and<br />

are to be tested for flowability<br />

char act eri s ti c s , oxidation resistance ,<br />

and room- and elevated-temperature<br />

tensile strengths.<br />

EVALUATION TESTS OF BRAZING ALLOYS<br />

G. M. Slaughter Y. G. Lane<br />

C. E. Schubert<br />

Metallurgy Division<br />

The results of recent high -tempera -<br />

ture oxidation tests and static cor -<br />

rosion tests in sodium hydroxide,<br />

sodium, and lithium are summarized<br />

in Table 12.4. The high -temperature<br />

oxidation tests were conducted in<br />

a stream of moist air at 1500°F on T<br />

specimens of Inconel and type 316<br />

stainless steel brazed with <strong>the</strong><br />

various alloys. The samples tested<br />

in molten sodium hydroxide at 1500°F<br />

were A nickel T j oints brazed with<br />

<strong>the</strong>se alloys. Brazed Inconel and<br />

type 316 stainless steel T joints were<br />

used as specimens for <strong>the</strong> corrosion<br />

tests in sodium and lithium. The<br />

tensile strength of several brazed<br />

joints has been examined at, room and<br />

1500" F temper a tures.<br />

Oxidation of Brazing Alloys. Ex-<br />

amination of metallographic sections<br />

of <strong>the</strong> high -temperature oxidation<br />

specimens showed <strong>the</strong> 60% Pd-40% N i<br />

alloy to be <strong>the</strong> most oxidation re-<br />

sistant of <strong>the</strong> brazing alloys tested.<br />

This alloy was unattacked when in<br />

contact with <strong>the</strong> base metals tested;<br />

<strong>the</strong> Inconel joint is shown in Fig.<br />

12.5. An example of severe oxidation<br />

is shown in Fig. 12.6, which is <strong>the</strong><br />

photomicrograph ofatype 316 stainless<br />

steel joint brazed with <strong>the</strong> 64% Ag-33%<br />

L65

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