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ANP PROJECT QUARTERLY PIJQGRESS REPORT<br />

13. HEAT TRANSFER AND PHYSICAL PROPERTIES RESEARCH<br />

H. F. Poppendiek, Reactor ExperimenLal Engineering Division<br />

'The <strong>the</strong>rmal conductivity of <strong>the</strong><br />

fluoride mixture NaF-BeF2 (57-43 mole<br />

%) was experimentally determined to<br />

be 2.4 Btu/hr*ft."F over a temperaturr<br />

range of 452 to 586°C. This result<br />

is comparable with <strong>the</strong> <strong>the</strong>rmal con-<br />

ductivi ties previously obtained for<br />

some of <strong>the</strong> o<strong>the</strong>r fluoride mixtures.<br />

Two new <strong>the</strong>rmal conductivity devices<br />

have been developed and successfully<br />

tested with ordinary liquids.<br />

The enthalpies and heat capacities<br />

of fuel mixture NaF-KF-ZrF,-UF,<br />

(4.8-50.1-41.3-3.8 mole %) have been<br />

obtained. The heat capacity can be<br />

represented by c = 0.28 +_ 0.015<br />

P<br />

cal/cm."C over <strong>the</strong> temperature range<br />

540 to 900°C.<br />

The viscosities and densities of<br />

<strong>the</strong> fluoride mixtures NaF-ZrF, (50-50<br />

mole 760) and NaF-ZrF,-UF, (50-25-25<br />

mole 7%) have been measured with <strong>the</strong><br />

modified Brookfield viscometer. The<br />

viscosity of <strong>the</strong> first mixture ranged<br />

from 15 cp at 610°C to 5 cp at 1030°C.<br />

The viscosity of <strong>the</strong> second mixture<br />

ranged from 20 cp at 650°C to 11 cp<br />

at 880°C. These results are compared<br />

w i t X <strong>the</strong> viscosity measurements<br />

previously determined for some of <strong>the</strong><br />

0 <strong>the</strong>r fluoride mix tures. Development<br />

of <strong>the</strong> capillary viscometer is conti<br />

nuing.<br />

The vapor pressure of NaZrF, increases<br />

from 8 mm Hg at 800°C to 30<br />

mm Hg at 900°C; this behavior is<br />

similar to that previously reported<br />

for <strong>the</strong> NaF-ZrF,-UF, (50-46-4 mole X)<br />

mixture. Experimental values of <strong>the</strong><br />

vapor pressure of BeF2 measured at<br />

RMI agreed with values calculated at<br />

ORNL .<br />

Preliminary experiment a1 heat<br />

transfer coefficients have been<br />

pbtained for <strong>the</strong> case of turbulently<br />

flowing NaF-KF-LiF mixture in a long<br />

tube. It appears that heat transfer<br />

with this mixture can probably be<br />

described by <strong>the</strong> usual forced-convection<br />

174<br />

expressions characterizing ordinary<br />

fluids, as was found to be <strong>the</strong> case<br />

for mol ten sodium hydroxide.<br />

Sever a1 <strong>the</strong>rmal analyses pertaining<br />

to <strong>the</strong> reflector-moderated reactor<br />

have been conducted. One study was<br />

made concerning <strong>the</strong> heat generation<br />

within <strong>the</strong> reflector and shell of <strong>the</strong><br />

reactor. Ano<strong>the</strong>r analysis consisted<br />

of preparing design charts for cooling-<br />

hole distributions in reactor re-<br />

flectors. An attempt to minimize <strong>the</strong><br />

weight and volume of air radiators<br />

has been initiated.<br />

A pyrex <strong>the</strong>rmal convection harp<br />

has been designed and constructed for<br />

an experimental inquiry into harp<br />

convection velocities. The experi-<br />

mental dat,a are to be used to check<br />

<strong>the</strong> validity of analytical methods<br />

used to predict <strong>the</strong> circulation<br />

velocities.<br />

An investigation has been initiated<br />

in an attempt to derive a heat-momentum<br />

transfer analogy for <strong>the</strong> annulus in<br />

much <strong>the</strong> same way as it has been<br />

derived for <strong>the</strong> pipe system.<br />

An experiment has been designed<br />

that w i l l make possible an experimental<br />

study of <strong>the</strong> heat transfer chasac-<br />

teristics of a simple, fuel-circulating<br />

system; a long pipe w i l l be used in<br />

which <strong>the</strong> flowing fluid is heated<br />

internally by an electric current.<br />

The experimental results w i l l be<br />

compared with <strong>the</strong> previously obtained<br />

<strong>the</strong>oretical results.<br />

THERMAL CONDUCTIVITY OF LIQUIDS<br />

W. D. Powers R. M. Burnett<br />

S. J. Claiborne W. 8. Harrison<br />

Reactor Experiment a1 Engineering<br />

Division<br />

A <strong>the</strong>rmal conductivity deiice<br />

similar to <strong>the</strong> one described previ-<br />

ously(') was used to study <strong>the</strong> fluoride<br />

(l)L. F. Basel end M. Tobias, ANP Quar. Prog.<br />

Rep. Dec. 10. 1950. ORNL-919, p. 196.

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