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dry anaerobic digestion of municipal solid waste and digestate ...

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For instance, Mumme et al., (2010) reported an increase in TS concentration from 15.8 to<br />

22.1% continuously since day 39 (during feeding steps with higher OLR <strong>of</strong> 12.7 <strong>and</strong> 17 kg<br />

VS/m 3 d). Moreover, compaction <strong>of</strong> <strong>solid</strong>-state bed was also observed during the same<br />

time. The increase in TS content <strong>of</strong> reactor medium has been found to decrease VS<br />

removal <strong>of</strong> the digester as proved in section 2.4.2. Similarly, increase in TS <strong>of</strong> <strong>digestate</strong><br />

also increases remaining methane formation potential <strong>of</strong> <strong>digestate</strong>. Both the TKN <strong>and</strong><br />

NH4–N accumulate in the <strong>solid</strong> residues <strong>of</strong> a continuously operated digester, which is just<br />

similar to that in liquid <strong>digestate</strong>.<br />

Fuchs et al., (2008) analyzed one hundred compost <strong>and</strong> <strong>digestate</strong> samples representative <strong>of</strong><br />

the different composting systems <strong>and</strong> qualities <strong>and</strong> concluded that the respiration rate,<br />

enzymatic activities <strong>and</strong> phytotoxicity varied greatly which depend on maturity <strong>and</strong><br />

management process. Mature composts showed less respiration rates <strong>and</strong> enzymatic<br />

activity. In Europe humic substances are described as parameters for quality <strong>of</strong> composts in<br />

addition to low contents <strong>of</strong> pollutants (Binner et al., 2008). Unhurried degradation with<br />

long lasting biological reactivity <strong>of</strong> the feedstock is important for high compost quality that<br />

leads to the formation <strong>of</strong> more humic acids. Anaerobic pretreatment seems to be positive<br />

for the development <strong>of</strong> humic acids during the following rotting period. In contrast,<br />

intensive supply <strong>of</strong> oxygen mineralizes the metabolic products quickly <strong>and</strong> completely <strong>and</strong><br />

discharges into air. Pure sewage sludge or sewage sludge with low amount <strong>of</strong> yard <strong>waste</strong>s<br />

lead to a low development <strong>of</strong> humic acids.<br />

Tambone et al., (2010) studied a total <strong>of</strong> 23 samples <strong>of</strong> <strong>digestate</strong>s, ingestates, composts <strong>and</strong><br />

digested sludge to assess their amendment <strong>and</strong> fertilizing properties. The results shown that<br />

<strong>digestate</strong>s differed from ingestates <strong>and</strong> also from compost, although the starting organic<br />

mix influenced the <strong>digestate</strong> final characteristics. In amendment properties, compost <strong>and</strong><br />

<strong>digestate</strong> were better than digested sludge <strong>and</strong> all <strong>of</strong> these were better than ingestate.<br />

As to fertilizer properties, <strong>digestion</strong> produced <strong>digestate</strong> with very good fertilizing<br />

properties because <strong>of</strong> the high nutrient (N, P, K) content in available form. Thus, the<br />

<strong>digestate</strong> appears to be a good c<strong>and</strong>idate to replace inorganic fertilizers, also contributing,<br />

to the short-term soil organic matter turnover.<br />

2.9.2 Characteristics <strong>of</strong> liquid <strong>digestate</strong>s<br />

It has been found that the liquid <strong>digestate</strong> resulting from fermentation <strong>of</strong> farm manures,<br />

agricultural biomass, OFMSW <strong>and</strong> their combination from biogas plants provide liquid<br />

fertilizer. Typically, the liquid <strong>digestate</strong>s resulting from liquid-<strong>solid</strong> separation <strong>of</strong> digested<br />

residues contain low total <strong>solid</strong>s content (3-6 % <strong>of</strong> farm manure). Moreover, they are rich<br />

in nutrients such as N (> 6% <strong>of</strong> TS), NH 4-N (> 2% <strong>of</strong> TS), K (> 4% <strong>of</strong> TS), Ca <strong>and</strong> Mg.<br />

Because <strong>of</strong> high N content <strong>of</strong> liquid <strong>digestate</strong>s, their C/N ratio is very low (< 6), which<br />

makes them suitable for direct application to the field. The required C/N ratio for an<br />

organic fertilizer (or amendment) to be applied on soil is < 20 (Wood, 2008). However,<br />

high pH (about 8.5) <strong>of</strong> liquid <strong>digestate</strong>s makes them more prone to be lost to atmosphere<br />

through volatilization, when applied in the field especially at high ambient temperature.<br />

Thus special soil management practices need to be adopted to avoid this loss <strong>of</strong> N. The<br />

characteristics <strong>of</strong> liquid <strong>digestate</strong>s from different digesters as investigated by different<br />

environmentalists have been shown in Table 2.8.<br />

35

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