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dry anaerobic digestion of municipal solid waste and digestate ...

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2.9 Characteristics <strong>of</strong> Digestates 33<br />

2.9.1 Characteristics <strong>of</strong> <strong>solid</strong> <strong>digestate</strong>s 33<br />

2.9.2 Characteristics <strong>of</strong> liquid <strong>digestate</strong>s 35<br />

2.9.3 Presence <strong>of</strong> organic pollutants 37<br />

2.9.4 Presence <strong>of</strong> heavy metals 38<br />

2.9.5 GHG emission potential <strong>of</strong> <strong>digestate</strong> 38<br />

2.10 Management Aspects <strong>of</strong> Anaerobic Digestate 39<br />

2.10.1 Separation <strong>of</strong> liquid <strong>and</strong> <strong>solid</strong> <strong>digestate</strong> 39<br />

2.10.2 Direct l<strong>and</strong> application <strong>of</strong> liquid <strong>digestate</strong> 40<br />

2.10.3 Aerobic post-treatment <strong>of</strong> <strong>solid</strong> <strong>digestate</strong> <strong>and</strong> its effects on 40<br />

quality<br />

2.10.4 Digestate storage <strong>and</strong> its effects on characteristics 41<br />

2.11 Post Utilization Monitoring Issues <strong>of</strong> Anaerobic Digestate 42<br />

2.11.1 Effect <strong>of</strong> <strong>digestate</strong> application on soil 42<br />

2.11.2 Influence <strong>of</strong> <strong>digestate</strong> application on plant growth <strong>and</strong> health 42<br />

2.12 Research Needs for the Dissertation 43<br />

3 Methodology 44<br />

3.1 Inoculum <strong>and</strong> Simulations <strong>of</strong> Waste 45<br />

3.1.1 Inoculum for <strong>anaerobic</strong> <strong>digestion</strong> experiments 45<br />

3.1.2 Simulations <strong>of</strong> <strong>waste</strong> 45<br />

3.2 Experimental Set-up 46<br />

3.2.1 Experimental set-up for gas formation potential test 46<br />

3.2.2 Experimental set-up for pilot-scale experiments 46<br />

3.3 Experimental Conditions 47<br />

3.3.1 Experimental conditions for gas formation potential test 47<br />

3.3.2 Experimental conditions for Phase I pilot experiment 48<br />

3.3.3 Experimental conditions for Phase II pilot experiment 50<br />

3.4 Digestate Management <strong>and</strong> GHG Emissions Estimation (Phase III) 51<br />

3.4.1 Storage <strong>of</strong> <strong>digestate</strong> 52<br />

3.4.2 Dewatering <strong>of</strong> <strong>digestate</strong> 52<br />

3.4.3 Curing <strong>of</strong> dewatered <strong>digestate</strong> 53<br />

3.4.4 Estimation <strong>of</strong> GHG emissions in the <strong>digestate</strong> management<br />

system<br />

55<br />

3.5 Analytical Methods 58<br />

4 Results <strong>and</strong> Discussion 60<br />

4.1 Gas Formation Potential <strong>of</strong> Waste 60<br />

4.2 Effect <strong>of</strong> C/N Ratio <strong>and</strong> Ammonia-N Accumulation on ITDAR<br />

(Results <strong>of</strong> Phase I Pilot Experiment)<br />

62<br />

4.2.1 Performance <strong>of</strong> ITDAR during start-up <strong>and</strong> continuous<br />

operations<br />

63<br />

4.2.2 Effect <strong>of</strong> C/N ratio <strong>and</strong> ammonia-N accumulation in ITDAR 65<br />

4.2.3 Summary <strong>of</strong> the effect <strong>of</strong> ammonia-N accumulation in ITDAR 68<br />

4.2.4 Energy balance <strong>of</strong> ITDAR in Phase I pilot experiment 70<br />

4.3 Optimization <strong>of</strong> a Pilot-Scale Thermophilic Dry Anaerobic Digester<br />

(Results <strong>of</strong> Phase II Pilot Experiment)<br />

71<br />

4.3.1 Start-up <strong>of</strong> ITDAR in phase II pilot experiment 71<br />

4.3.2 Stability parameters <strong>of</strong> ITDAR: Effect <strong>of</strong> organic loading rate 74<br />

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