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TECHNOLOGY<br />

Fig. 2: Organisation of scrap yard for recycling<br />

of wrought aluminium alloys from<br />

post-consumed scrap in accordance with<br />

the mo<strong>de</strong>l<br />

Fig. 3: Providing the pre-melt ‘recycling-friendly’<br />

composition of<br />

wrought aluminium alloy by combining<br />

different scrap streams of postconsumed<br />

scrap<br />

are <strong>de</strong>termined by the chemical composition<br />

of the individual scrap streams available in<br />

the scrap yard and involved in creating the incoming<br />

scrap mixture pre-melt composition.<br />

In practice, the system of equations (24) is<br />

applied to numerical mo<strong>de</strong>lling of the recycling-friendly<br />

composition, or, in other words,<br />

for selecting the (proper combination of) tolerance<br />

limits, ∆X i (i = 1, 2, 3, … , n), of alloying<br />

elements un<strong>de</strong>r which: (i) the selected<br />

mechanical properties of the alloy remain the<br />

same as in the standard one,<br />

and (ii) the chemical composition<br />

of the recycling-friendly<br />

alloy is the same as the premelt<br />

chemical composition of<br />

the incoming scrap mixture<br />

(formulated with the minimal<br />

addition of primary aluminium<br />

and alloying elements).<br />

The main priorities in formulation<br />

of the recyclingfriendly<br />

compositions are:<br />

1. The minimal addition of<br />

primary aluminium and alloying<br />

elements<br />

2. The maximal consumption<br />

of regular scrap streams,<br />

daily available in the scrap yard<br />

3. The non-standard alloy composition for<br />

which the selected mechanical properties remain<br />

the same as in the standard one.<br />

The practical way to do this is by mo<strong>de</strong>lling,<br />

starting from the chemical composition of<br />

the scrap streams. The precondition is that the<br />

chemical composition of the recycling-friendly<br />

Fig. 4: Processing steps in mo<strong>de</strong>lling the ‘recycling-friendly’ composition for the <strong>de</strong>sired alloy properties<br />

alloy should be the same as the pre-melt composition<br />

of the incoming mixture consisting<br />

of the combination of various scrap streams<br />

with no or minimal addition of primary aluminium<br />

and alloying elements. In addition, the<br />

<strong>de</strong>viations of the recycling-friendly from the<br />

standard concentrations of alloying elements<br />

should be as small as possible.<br />

In the first step it is necessary to consi<strong>de</strong>r<br />

the impact of alloying elements with maximal<br />

<strong>de</strong>viation of their concentrations from the<br />

standard prescribed. The negative impact of<br />

these elements on alloy properties should be<br />

reduced by minimising the concentration of<br />

others which finally results in the same alloy<br />

properties.<br />

The recycling-friendly compositions of<br />

wrought aluminium alloys should be mo<strong>de</strong>lled<br />

in accordance with the following two<br />

criteria: (i) the selected chemical composition<br />

and compositional tolerance limits of a recycling-friendly<br />

wrought aluminium alloy should<br />

fulfil market expectations regarding the alloy<br />

properties; and (ii) the prescribed recyclingfriendly<br />

alloy composition should be routinely<br />

achievable by mixing scrap streams fabricated<br />

in the scrap yard by scrap separation (with or<br />

without minimal addition of primary aluminium<br />

and alloying elements).<br />

In or<strong>de</strong>r to achieve these two goals, it is<br />

necessary to <strong>de</strong>fine the industrial levels of<br />

wrought aluminium scrap sorting. An example<br />

of the practical levels of sorting of post-consumed<br />

wrought aluminium scrap is presented<br />

in Table 3. Planning the optimal number of<br />

scrap streams, as illustrated in Fig. 2, their<br />

chemical composition and the compositional<br />

tolerance limits of alloying elements for effective<br />

blending of the pre-melting mixture, Fig.<br />

3, with minimal (or even without) addition of<br />

pure alloying elements and primary aluminium<br />

is essential for successful running of the<br />

recycling plant and the final business result.<br />

Therefore, a<strong>de</strong>quate organisation of the<br />

scrap separation streams should provi<strong>de</strong> answers<br />

to the following key questions of scrap<br />

processing:<br />

• How many scrap streams should be<br />

produced by sorting wrought aluminium<br />

wastes in the scrap yard<br />

• How many alloys (just a single one,<br />

a mixture of two or more) should be<br />

involved in these streams<br />

• What should the chemical compositions<br />

be (qualitatively, regarding alloying<br />

elements and also quantitatively,<br />

consi<strong>de</strong>ring their concentrations as<br />

well as the compositional tolerance<br />

limits) of those streams, and finally<br />

• For which wrought aluminium alloys<br />

60 ALUMINIUM · 7-8/2013

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