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special - ALUMINIUM-Nachrichten – ALU-WEB.DE

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SPECIAL<br />

<strong><strong>ALU</strong>MINIUM</strong> SMELTING INDUSTRY<br />

Theory<br />

The theory is described in a more detailed<br />

manner in reference [4]. Let us briefly mention<br />

that the alumina distribution in the bath<br />

is determined by the following partial differential<br />

equation:<br />

c: Alumina concentration in the bath<br />

D: Alumina diffusion coefficient<br />

u: Bath velocity field generated by MHD<br />

Lorentz force and by the release of bubbles<br />

If we consider fluctuations around the stationary<br />

state:<br />

(2)<br />

The velocity field is generated by Lorentz<br />

force field and by the bubbles. When the<br />

number of bubbles produced, per m 2 and per<br />

second, is too large, we cannot use a numerical<br />

approach describing the motion of each<br />

bubble separately.<br />

There are essentially two standard ways to<br />

overcome this difficulty. The first consists of<br />

performing some kind of averaging over the<br />

equations and over the corresponding fields.<br />

The second bypasses the averaging and directly<br />

postulates the flow equations for each<br />

phase.<br />

One of the main difficulties encountered<br />

when performing an averaging process is related<br />

to the possible jumps that fields can suffer<br />

at the boundaries between the two phases.<br />

One way to overcome this problem consists<br />

in extending the domain of definition of each<br />

motion equation to the domain occupied by<br />

the two phases. This is achieved by multiplying<br />

each equation by the characteristic function<br />

corresponding to its domain of definition.<br />

Derivatives are then performed in the sense<br />

of distributions which allows us to keep track<br />

of these discontinuities in the averaging process.<br />

Whatever choice we make, the resulting<br />

equations will contain terms which reflect<br />

the interaction between the two phases. The<br />

exact shapes of these terms are not known;<br />

they have to be defined through constitutive<br />

equations.<br />

(3)<br />

Taking into account the first law of Fick, eq.<br />

3 becomes: in Fig. 3. From the two figures, the alumina<br />

concentration field appears as only slightly<br />

modified by the velocity field. However, when<br />

An estimation shows that D turb is of the order<br />

of 0.2 m 2 /s.<br />

Industrial cell<br />

(4)<br />

The problem has been solved for a 180 kA cell<br />

using two point feeders. On the feeders, the<br />

alumina concentration is set to 5% of the bath<br />

weight. When presenting a stationary solution,<br />

this assumes continuous feeding. But we can<br />

easily analyse the<br />

impact of dump<br />

feeding. Fig. 1 corresponds<br />

to the<br />

stationary alumina<br />

distribution,<br />

when the velocity<br />

is neglected. The<br />

concentration is<br />

shown under the<br />

anodes. The two<br />

feeder locations<br />

appear clearly in<br />

the figure. The<br />

asymmetry of the<br />

diffusion pattern<br />

reflects the larger<br />

channel width at<br />

the feeders. A difference<br />

of close<br />

to 2.5% alumina<br />

concentration can<br />

be observed at<br />

the surface of the<br />

anodes. The vertical<br />

variation of<br />

alumina is 0.5%<br />

under the feeders,<br />

but it is negligible<br />

away from<br />

the feeders.<br />

Fig. 2 shows<br />

the velocity field<br />

generated by<br />

the bubbles and<br />

Lorentz force in<br />

this particular<br />

cell.<br />

The impact of<br />

the velocity field<br />

on the stationary<br />

solution of the<br />

alumina concentration<br />

is shown<br />

considering the concentration evolution, the<br />

time needed for reaching the stationary state<br />

is reduced by a factor 2 when the velocity field<br />

is acting. Therefore the velocity field plays an<br />

important role in the feeding process (alumina<br />

dumps).<br />

To highlight the role of the velocity field,<br />

Fig. 4 shows the difference between the alumina<br />

concentration field due only to the diffusion<br />

compared with that in presence of the<br />

velocity field. The greatest differences are observed<br />

at the ends of the cell, due essentially<br />

to the MHD effects. High negative values re-<br />

Fig. 1: Alumina concentration at the anode surface assuming no velocity field<br />

Fig. 2: Velocity field in the bath of the cell<br />

Fig. 3: Alumina concentration at the anode surface in presence of the velocity field<br />

Fig. 4: Alumina concentration variation due to the velocity field<br />

© Kan-nak<br />

<strong><strong>ALU</strong>MINIUM</strong> · 1-2/2013 59

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