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Gas Turbine Exhaust Treatment 137<br />

obtain effective cooling a liquid with a high heat of vaporization is<br />

preferred and water has a high heat of vaporization. Both water and<br />

steam injection increase the power output of the gas turbine by adding<br />

to the mass flow through the turbine.<br />

WATER INJECTION:<br />

During the early development of gas turbines, water was injected<br />

into the compressor, diffuser, or combustor to increase power<br />

output. This technique was applied to both the aircraft “jet” gas<br />

turbine engine to increase takeoff thrust, and the stationary heavy<br />

industrial gas turbines for peaking power. Today, in order to control<br />

the formation of organic NO, demineralized/deionized water is injected<br />

directly into the combustion zones of the gas turbine thereby<br />

influencing the chemical reaction of the combustion process. In addition<br />

to lowering the flame and gas temperatures, vaporized water<br />

also increases the mass flow through the engine. As a result, at a<br />

constant power output, combustion and turbine temperatures are<br />

reduced. The combination of the reduced combustion temperatures<br />

and changes in the chemical reaction can reduce NO x<br />

formation up<br />

to 80%. The amount of water necessary to accomplish this reduction<br />

in NO x<br />

is a function of the diffuser, combustor, and fuel nozzle<br />

design. Water injection rates are generally quoted as a water-tofuel<br />

ratio or as a percentage of compressor inlet air flow. The water<br />

injection rate for a typical 80 MW heavy frame gas turbine would<br />

be 0.6 water-to-fuel ratio or 1.15 % of total air flow. The amount of<br />

water injected into the diffuser or the combustor is limited by several<br />

factors. Water injection moves the operating line closer to the<br />

compressor surge line (Figure 9-4). Also, too much water will quench<br />

the combustion flame, resulting in flame-out.<br />

The water used for NO x<br />

control is demineralized and deionized<br />

to eliminate deposits from forming on the hot metal surfaces of<br />

the combustor, turbine nozzles, and turbine blades. When handling<br />

demineralized/deionized water, care must be taken to select materials<br />

that are resistant to its highly reactive attack. Therefore, piping<br />

should be AISI 304L and valves and pumps should be 316L stainless<br />

steel.

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