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Yearbook 2013/2014 - ehedg

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Flow behaviour of liquid jets impinging on vertical walls 67<br />

by the falling film. Soil in this region will be removed by the<br />

action of detergent and lower shear stresses, as reported<br />

by Morison and Thorpe (2002). 1 Under some conditions<br />

the falling film will narrow below the impingent plane and<br />

give poor contact with the soil, as shown in Figure 2 (b). It is<br />

therefore important to be able to predict the transition from<br />

the wide, gravity, film flow behaviour to the narrow, rivulet<br />

regime.<br />

Predicting the film jump<br />

A model for the film jump has recently been developed. 2 This<br />

allows R to be predicted from<br />

¼<br />

⎡ m 3 ⎤<br />

R = 0.276 ⎢ ⎯⎯⎯⎯⎯⎯ ⎥<br />

⎣ μργ(1− cos b) ⎦<br />

(1)<br />

In this equation, m is the jet mass flow rate; μ is the viscosity<br />

of the liquid and ρ is its density; γ is the surface tension, and<br />

β is the contact angle of the liquid on the substrate.<br />

Figure 3 shows good agreement between experimental<br />

data and the model for water on Perspex. Nozzle sizes, d N<br />

,<br />

typical of those used in industrial practice have been tested.<br />

Comparison with other data sets, including those reported<br />

in Morison and Thorpe (2002), are reported in Wilson et al.<br />

(2011) and Wang et al. (<strong>2013</strong>). 1–3<br />

surfactant molecules had time to collect at the solid/liquid/air<br />

interface, gave poor agreement with the measured values.<br />

This indicates that dynamic surface tension effects are<br />

important in these flows.<br />

A second important finding reported in Wang et al. (<strong>2013</strong>)<br />

is that at higher flow rates and with larger nozzles, R was<br />

independent of the nature of the substrate. This indicates<br />

a change in the phenomena controlling the flow pattern at<br />

higher flow rates from one controlled mainly by interfacial<br />

forces to one where fluid inertia become important. Using<br />

a contact angle of 90° in Equation (1) gave reasonable<br />

predictions for R in these cases.<br />

Predicting the film width<br />

The relationship between W and R cannot be obtained using<br />

the simple models behind Equation (1). Measurements of<br />

W (= 2Rc in Figure 3) indicate that Rc ≈ 2R at lower flow<br />

rates and approaches Rc ≈ 4/3R at higher flow rates. These<br />

empirical results allow W to be estimated.<br />

Falling film flow patterns<br />

The tendency to exhibit gravity or rivulet flow in the region<br />

below the impingement plane has been found to follow the<br />

criterion given by Hartley and Murgatroyd (1964) for the<br />

stability of wide falling liquid films. 4 This says that film will be<br />

stable if the wetting rate, defined as m/W, is larger than the<br />

critical value given by<br />

m<br />

⁄ W<br />

≥ 1.69 (μρ/g) 0.2 [γ(1− cos b)] 0.6 (2)<br />

Here g is the acceleration due to gravity. Equation (2) holds<br />

for vertical surfaces; for inclined walls, g is modified to<br />

account for the angle of slope.<br />

We have found that Equation (2) gives reasonable predictions<br />

of the transition from the gravity to rivulet regimes for these<br />

falling films. Equation (2) has also been found to apply for<br />

solutions containing a surfactant, using the values of γ and<br />

b obtained from equilibrium contact angle measurements.<br />

Surfactants which promote wetting on the soil or substrate<br />

will give smaller values of b and therefore, from Equation<br />

(2), reduce the flow rate required to avoid rivulet formation<br />

(as W is less sensitive to surfactant content).<br />

Figure 3. Comparison of experimental measurements of R with<br />

values predicted from Equation (1) for water on Perspex for<br />

different nozzle sizes and temperatures. Reproduced from Wang et<br />

al. (<strong>2013</strong>) with permission.<br />

Equation (1) shows that R is larger for liquids with a small<br />

contact angle (i.e., ones that wet the surface) and for liquids<br />

with a lower surface tension. Surfactants are often added<br />

to promote wetting and change the contact angle. Recent<br />

work has demonstrated that the effect of surfactants on<br />

R comes mainly through their influence on the surface<br />

tension. 3 Predictions of R using Equation (1) using contact<br />

angles measured under equilibrium conditions, where the<br />

Figure 4 shows an example for water jets impinging on a<br />

vertical glass wall. Solid symbols indicate that the falling film<br />

exhibited gravity flow, while open symbols denote rivulet flow<br />

behaviour.<br />

The data are plotted in terms of the Eötvös number, a<br />

dimensionless width, and a dimensionless flow rate, F, given<br />

by<br />

and<br />

Eo = ρgW 2 ⁄ γ (3)<br />

F = ρgm 2 ⁄ γμ2 (4)

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