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1. magnetic confinement - ENEA - Fusione

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3. FUSION TECHNOLOGY 93<br />

3.8 Liquid Metal Technology and<br />

Hydrogen Effects on Materials<br />

Fig. 3.31 - Area reduction<br />

as a function of hydrogen<br />

content at room and high<br />

temperature.<br />

Area reduction /Area red. virgin mat. (%)<br />

120<br />

100<br />

80<br />

60<br />

40<br />

20<br />

EUROFER steel<br />

T =20°C<br />

T =100°C<br />

T =200°C<br />

0<br />

0 1 2 3 4 5 6 7 8 9<br />

cylindrical<br />

specimens that had<br />

been previously<br />

electrochemically<br />

charged with<br />

hydrogen (contents<br />

of up to 3 wppm) at<br />

high temperature<br />

(90°). The experimental<br />

activities<br />

were performed in<br />

collaboration with<br />

the University of<br />

Pisa.<br />

Hydrogen content (wppm)<br />

As expected, the<br />

hydrogen concentration necessary to have a marked decrease in the area reduction<br />

coefficient was found to be quite high compared to that determined at room<br />

temperature (fig. 3.31).<br />

The experimental activity on hydrogen embrittlement will be completed during first<br />

months of 2002.<br />

3.8.5 Water detritiation systems (EU Task TTBA-D02)<br />

The aim is to assess a design to simplify the WCLL blanket concept by eliminating<br />

the TPBs on the double walled tubes of the primary cooling system and recovering a<br />

significant part of the bred tritium directly through the water detritiation system<br />

(WDS).<br />

From previous studies, it was found that this approach to tritium management<br />

strategy is feasible from a techno-economic point of view only if a steady-state<br />

tritium concentration of several Ci/kg is allowed in the primary cooling loops. In<br />

other words, the tritium specific activity in the primary cooling system must be a<br />

good deal higher than that foreseen in the reference design (1Ci/kg).<br />

A detailed safety analysis on the consequences of a relatively high tritium specific<br />

activity in the primary coolant was, therefore, performed in collaboration with the<br />

University of Bologna. The environmental tritium release was determined for an exvessel<br />

loss of coolant accident (LOCA) in normal operation. The tritium specific<br />

activity considered corresponded to the “economical optimum” for a water<br />

detritiation system, based on electrolysis, distillation columns + vapour phase<br />

catalytic exchange and combined electrolysis catalytic exchange (CECE), in all cases<br />

with a tritium permeation rate (TPR) of 10 g/day from the breeder into the coolant.<br />

Such a TPR corresponds to a PRF of 10 for the tritium permeation barriers. This value<br />

is achievable, in principle, only by using double walled EUROFER97 tubes with<br />

copper as brazing material. A water leak rate of 2 kg/h from the primary cooling<br />

circuit was assumed, with <strong>1.</strong>9 kg/h towards the steam generator vault and the<br />

remaining 0.1 kg/h into the secondary circuit through the steam generators.<br />

For an ex-vessel LOCA, even in the worst case, which corresponds to the highest<br />

enthalpy content of the cooling water, the environmental tritium release was<br />

determined to be much lower than the limit of 5 g of tritium in HTO form; this is the<br />

maximum acceptable value according to the ITER Guidelines for Environmental<br />

Tritium Release.

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