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Calibration curves for KF-600 seriesusing PS standardMolecular weight (Polystyrene)10 710 610 510 410 3KF-604KF-603KF-602.5KF-602KF-601KF-606KF-605KF-606MCalibration curves for KF-400HQ seriesusing PS standardMolecular weight (Polystyrene)10 7 Elution volume (mL)10 610 510 410 310 2KF-404HQKF-403HQKF-402.5HQKF-401HQKF-402HQStyrene-Acrylonitrile copolymerSample : Styrene-acrylonitrile (30:70) copolymerStandard analysiscolumns10 21.0 1.5 2.0 2.5 3.0 3.5 4.0Elution volume (mL)101.0 1.5 2.0 2.5 3.0 3.5 4.06 8 10 12 14minColumn : Shodex GPC KF-600 seriesEluent : THFFlow rate : 0.5mL/minDetector : UV(254nm)Column temp. : Room temp.Comparison of standard, rapid analysis and high performace semi-micro columnsStandard typeKF-802.5 x 250μL injectionHigh performance typeKF-402.5HQ x 210μL injectionRapid analysis typeKF-602.5 x 210μL injection056.0mLColumn : Shodex GPC KF-400HQ seriesEluent : THFFlow rate : 0.3mL/minDetector : UV(254nm)Column temp. : Room temp.5.7mL21mL10 15 20 25 minLC/MS analysis of additives (Irganox1010) in polymerSample : EPON1001 0.2%The analysis of the additives that are present in polymer usually includes a pretreatment step. However, our SECcolumns can separate the additives from the polymer and introduce only the low-molecular-weight fractioncontaining the additives into MS, thus enabling easy and highly sensitive analysis without any pretreatment step.UV(210nm)Sample : Cup of instant noodles (styrene foam) 1000mg/L, 5μLm/z=1176(Negative)IRGANOX 1010Column : Shodex GPC KF-606M x 2Eluent : 10mM LiBr in DMFFlow rate : 0.5mL/minDetector : RI(small cell volume)Column temp. : 40˚CReducing the analysis time to less than half of that for the standardcolumn (KF-802.5) requires KF-602.5 which enables high-speed analysis.On the other hand, KF-402.5HQ has a number of theoretical plates 1.5times larger than that of the standard column, thereby improvingresolution especially in the analysis of molecules that have a small tomedium molecular weight. Both columns spend solvent amounting toonly about one third of the quantity spent by the standard column and areeco-friendly.Column : Shodex GPC KF-802.5 x 2Shodex GPC KF-402.5HQ x 2Shodex GPC KF-602.5 x 2Eluent : THFFlow rate : (KF-802.5) 1.0mL/min(KF-402.5HQ) 0.3mL/min(KF-602.5) 0.6mL/minDetector : (KF-802.5) RI(conventional type)(KF-402.5HQ, KF-602.5) RI(small cell volume)Column temp. : 40˚CPhthalatesSample : 10μL1. Dioctylphthalate 0.1%2. Dibutyllphthalate 0.1%3. Dipropylphthalate 0.1%4. Diethylphthalate 0.1%5. Dimethylphthalate 0.1%6. Propylbenzene 0.2%7. Ethylbenzene 0.2%8. Toluene 0.2%9. Benzene 0.2%23456 78 957Organic SEC (GPC) columns : Rapid Analysis, High Performance Analysisnot detected101 2 3 45 6 7 8 9 10 11 12 13 14 15 16min01 2 3 45 6 7 8 9 10 11 12 13 14 15 16min812 16 20 minColumn : Shodex GPC KF-402HQ x 2Eluent : THFFlow rate : 0.3mL/minDetector : UV(210nm), APCI-MS(SIM)Column temp. : 40˚CColumn : Shodex GPC KF-401HQ x 2Eluent : THFFlow rate : 0.3mL/minDetector : UV(254nm) (small cell volume)Column temp. : 40˚C