TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
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10:30 19. Studies on biologically important<br />
binary complexes in solution: The systems<br />
beryllium (II) and cobalt (II)- homoserine.<br />
B. B. Tewari, B. B. Tewari<br />
10:50 20. Zn(II) and Cu(II) detection with<br />
simple Schiff base systems. S. Khatua,<br />
J. Kang, K. Kim, H. Park, D. G. Churchill<br />
11:10 21. Development of triggereable chelating<br />
agents as probes for metal-induced<br />
oxidative stress. L. M. Hyman,<br />
K. J. Franz<br />
11:30 22. Further studies of bis(carboxylato)<br />
platinum(IV) compounds: Correlation between,<br />
liphoilicity, reduction potential,<br />
cellular accumulation and cytotoxicity.<br />
M. R. Reithofer, A. Bytzek,<br />
S. M. Valiahdi, C. R. Kowol, M. Groessl,<br />
M. Galanski, C. G. Hartinger,<br />
M. A. Jakupec, B. K. Keppler<br />
11:50 23. Anti-Fenton chemistry and detecting<br />
oxidative stress induced by metal and<br />
H 2O 2 in living cells. Y. Wei, Y. Zhang,<br />
Z. Liu, M. Guo<br />
12:30 24. Access to well-defined Ru(I) and<br />
Os(I) metalloradicals. A. Takaoka,<br />
L. C. Gerber, J. C. Peters<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, Organizer<br />
F. Beckford, Presiding<br />
8:30 25. Single-walled metal–organic nanotubes.<br />
K. Lu, H. Wu, Y. Jao, T. Tseng,<br />
S. Peng<br />
8:50 26. Magnificent FOX-7 can be tamed.<br />
S. Garg, H. Gao, B. Twamley,<br />
J. M. Shreeve<br />
9:10 27. Investigations of transition metalthiosemicarbazone<br />
complexes as medicinal<br />
agents. F. Beckford<br />
9:30 28. Mechanistic studies on the inhibition<br />
of enzymes and zinc finger transcription<br />
factors with cobalt(III) Schiff base<br />
complexes. T. A. Atesin,T.J.Meade<br />
9:50 29. Common fixatives used in the preservation<br />
of biological tissues.<br />
S. S. Mantravadi<br />
10:10 30. Copper cross-linked palindromic<br />
bipyridine substituted artificial tripeptides<br />
and the effects of anions on structure.<br />
J. A. Gallagher, L. A. Levine,<br />
M. E. Williams*<br />
10:30 31. Aminoethylglycine-modified ruthenium<br />
complexes: Scaffolds for photocatalysts.<br />
C. P. Myers, M. E. Williams*<br />
10:50 32. Duplex formation of ligand substituted<br />
aminoethylglycine di- and tri-peptides<br />
with Cu �2 . M. B. Coppock,<br />
J. Miller, M. E. Williams*<br />
11:10 33. Photophysical properties, DNA<br />
photocleavage, and photocytotoxicity of<br />
a series of dppn dirhodium (II,II) complexes.<br />
L. E. Joyce, J. Aguirre,<br />
A. M. Angeles-Boza, A. Chouai,<br />
P. K. Fu-Giles, K. R. Dunbar, C. Turro<br />
11:30 34. Photodynamic therapy for skin<br />
carcinomas. R. A. Khanke,P.K.Fu<br />
11:50 35. Impact of triarylboron on the luminescence<br />
of Pt(II) acetylides: Enhanced<br />
phosphorescence and chemical sensing.<br />
C. Sun, Z. M. Hudson, S. Wang<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Structure and Properties<br />
B. Donovan-Merkert, D. Nelson,<br />
Organizers<br />
P. Dinolfo, Presiding<br />
8:30 36. Studying protein-inorganic nanoparticle<br />
interactions in ferritin model systems.<br />
L. Zhang, D. Liu, J. Cheung-Lau,<br />
J. Swift, C. Butts, I. J. Dmochowski<br />
8:50 37. Perfluorographane: Synthesis and<br />
measurement of electrical and mechanical<br />
properties. J. S. Burgess,<br />
J. T. Robinson, M. Zalalutdinov,<br />
K. Perkins, P. Campbell, E. S. Snow,<br />
B. H. Houston, J. W. Baldwin<br />
9:10 38. Layer-by-layer formation of molecular<br />
multilayers using “click” chemistry:<br />
Synthetic versatility and thin-film characterization.<br />
P. H. Dinolfo, P. K. Palomaki,<br />
A. Krawicz<br />
9:30 39. Synthesis, electronic structure, and<br />
alignment of graphene thin films. V. Lee,<br />
R. V. Dennis, C. Jaye, D. A. Fischer,<br />
S. Banerjee<br />
9:50 40. Synthesis, reaction, characterization,<br />
and properties of high density energetic<br />
alkoxynitroiminotetrazoles. Y. Joo,<br />
J. M. Shreeve<br />
10:10 41. Microemulsion strategy for the<br />
synthesis of nano-LiFePO 4/C composites.<br />
S. Jheng, J. R. Carey, J. Chen<br />
10:30 Intermission<br />
10:50 42. Theoretical studies and investigations<br />
of a proposed new allotrope of carbon.<br />
P. J. Bonk<br />
11:10 43. High power oscillating thermoelectric<br />
waves from exothermic reactions<br />
around nanoscale thermal conduits.<br />
M. S. Strano, J. T. Abrahamson,<br />
W. Choi, J. Han, K. Kalantar-zadeh<br />
11:30 44. Electrostatic charging of fumed<br />
silica particles: Effect of surface treatment<br />
with alkylfluorosilanes. J. Liu,<br />
J. K. Floess, H. Tu, D. Fomitchev<br />
11:50 45. Catalytic activity of aggregated<br />
gold nanoparticles upon irradiation of<br />
light. J. Kim, B. W. Lavin<br />
12:10 46. <strong>Chemical</strong> processing of ferroelectric<br />
nanostructures with variable architectural<br />
complexity. G. Caruntu,<br />
S. Adireddy, A. Yourdkhani, C. Lin<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Properties and Applications<br />
S. Wong, Organizer<br />
D. Dudis, Presiding<br />
8:30 47. Dynamic thin film fabrication of Palladium<br />
nanomaterials for application in<br />
hydrogen gas sensing. J. Zou, S. Iyer,<br />
C. Raston<br />
8:50 48. Graphene and nanowire transistors<br />
for cellular interfaces and electrical recording.<br />
T. Cohen-Karni, Q. Qing,<br />
L. Qiang, Y. Fang, C. M. Lieber<br />
9:10 49. Size-dependant magnetism in lanthanide<br />
chalcogenide nanomaterials.<br />
W. L. Boncher, S. L. Stoll<br />
9:30 50. Energy generation in carbon nanotube<br />
induced by the chemical reaction:<br />
Thermopower waves. W. Choi,S.Hong,<br />
J. Abrahamson, J. Han, C. Song, N. Nair,<br />
S. Baik, M. Strano<br />
9:50 51. Fullerene-based Superatom thermoelectric<br />
materials. D. S. Dudis,<br />
M. Check, H. A. Seibel, J. B. Ferguson,<br />
B. Elliott, J. Gengler, M. Leamy<br />
10:20 Intermission<br />
10:40 52. Effect of surfactant and surfactant<br />
content on electrical conductivity of single<br />
walled carbon nanotubes thin films.<br />
J. Hahn<br />
11:10 53. Novel, lanthanide-based nanoparticles<br />
for NIR to UV energy conversion.<br />
J. A. Ayres, I. N. Stanton, M. J. Therien<br />
11:30 54. Engineering nanoparticle catalysis<br />
via a multimetallic core/shell structure.<br />
V. Mazumder,S.Sun<br />
11:50 55. Withdrawn<br />
12:10 56. Enhanced solar energy conversion<br />
at quantum dot sensitized TiO 2 photonic<br />
crystals and disordered films by slow<br />
light effects. M. El Harakeh, S. Bayram,<br />
S. Jaber, L. Halaoui<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Organometallic Chemistry<br />
Applications to Materials and Polymer<br />
Science<br />
N. Radu, Organizer<br />
E. Chen, Presiding<br />
9:00 57. Chiroptical and stereoregular polymers<br />
from achiral polar vinyl monomers<br />
by chiral metallocenium catalysts.<br />
E. Y. Chen<br />
9:20 58. “Click” synthesis of heteroleptic cyclometalated<br />
iridium(III) and platinum(II)<br />
complexes. S. Liu,T.M.Swager<br />
9:40 59. Tuning of electronic bandgap in<br />
conjugated polymers by chlorotricarbonyl<br />
rhenium(I) complexes. C. S. Mak,<br />
W. Cheung, Q. Leung, W. Chan<br />
10:00 60. Structure and catalysis of oxidesupported<br />
Ir-dimer catalysts for transfer<br />
hydrogenation. S. Muratsugu,<br />
Y. Kushida, H. Nakai, K. Isobe, T. Sasaki,<br />
M. Tada<br />
10:20 Intermission<br />
10:25 61. Isocyanate- and isothiocyanatederived<br />
Grubbs-Hoveyda type catalysts:<br />
Synthesis, structure, and activity.<br />
M. R. Buchmeiser, S. Kumar, I. Ahmad<br />
10:45 62. Ring-opening metathesis polymerization-based<br />
pore-size-selective<br />
functionalization of glycidyl methacrylatebased<br />
monolithic media: Access to sizestable<br />
nanoparticles for ligand-free metal<br />
catalysis. M. R. Buchmeiser, R. Bandari,<br />
T. Hoeche, K. Dirnberger, A. Prager<br />
11:05 63. Cobalt catalysts for the copolymerization<br />
of epoxides and carbon dioxide.<br />
M. R. Kember, C. K. Williams<br />
11:25 64. Hybrid polyoxometalates embedded<br />
in porous polymeric materials as heterogeneous<br />
catalytic systems.<br />
M. Carraro, M. Gardan, M. Bonchio,<br />
A. Sartorel, G. Scorrano<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Main Group Chemistry<br />
B. Donovan-Merkert, Organizer<br />
F. Gabbai, Presiding<br />
9:00 65. Dimethyl sulfide adduct of 9,10-dihydro-9,10-diboraanthracene:<br />
A powerful<br />
ditopic reagent for hydroboration and<br />
other transformations. A. Lorbach,<br />
M. Bolte, H. Lerner, M. Wagner<br />
9:20 66. Approaches to a novel boronbased<br />
cationic Lewis acid. A. Schnurr,<br />
M. Bolte, M. Wagner<br />
9:40 67. Synthesis of oligotopic arylborohydrides:<br />
Coordination chemistry and hydroboration<br />
reactivity. D. Franz,<br />
M. Wagner, M. Bolte<br />
10:00 68. Chiral organoborane derivatives<br />
based on the 1,2-ferrocenyl framework.<br />
J. Chen, T. Pakkarisamy,<br />
K. Venkatasubbaiah, F. Jäkle<br />
10:20 69. Carbene-stabilization of unusual<br />
main group molecules. Y. Wang,<br />
M. Abraham, P. V. Schleyer,<br />
G. H. Robinson<br />
10:40 Intermission<br />
10:50 70. Predicting the observed effect of<br />
force on S N2 cleavage kinetics of C–O,<br />
Si–O, and P–O bonds. T. J. Kucharski,<br />
Q. Yang, S. Akbulatov, Z. Huang,<br />
R. Boulatov<br />
11:10 71. Protonated clusters of M@Sn 9H 3and<br />
their relationships to the fused deltahedral<br />
clusters. F. S. Kocak, P. Y. Zavalij,<br />
B. W. Eichhorn<br />
11:30 72. Synthesis and anion-binding<br />
properties of a telluronium borane.<br />
H. Zhao,F.P.Gabbaï<br />
SUNDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Young Investigator Symposium<br />
F. Walker, Organizer, Presiding<br />
1:30 73. Mechanochromic luminescence of<br />
difluoroboron �-diketonate molecular solids.<br />
G. Zhang, J. Lu, M. Sabat,<br />
C. L. Fraser<br />
2:00 74. Magnetic resonance imaging<br />
agents for selective copper detection.<br />
E. L. Que,C.J.Chang<br />
2:30 75. Carbon monoxide-induced cleavage<br />
of dinitrogen promoted by group 4<br />
metallocene compounds.<br />
D. J. Knobloch, E. Lobkovsky,<br />
P. J. Chirik<br />
3:00 76. Synthesis and anion binding properties<br />
of cationic main group Lewis acids.<br />
Y. Kim,F.P.Gabbaï<br />
3:30 Intermission<br />
3:40 77. Synthetic and mechanistic studies<br />
of the ring-opening and denitrogenation<br />
of pyridine and picolines by a Ti-C multiple<br />
bond. A. R. Fout, B. C. Bailey,<br />
D. M. Buck, H. Fan, J. C. Huffman,<br />
M. Baik, D. J. Mindiola<br />
4:10 78. Pathways of hydrogen evolution<br />
catalyzed by cobalt(II) diglyoxime complexes.<br />
J. L. Dempsey, J. R. Winkler,<br />
H. B. Gray<br />
4:40 79. Optical resonances in semiconductor<br />
nanowires. L. Cao, M. L. Brongersma<br />
5:10 80. Chalcogels: Novel porous metalchalcogenide<br />
aerogels. S. Bag,<br />
M. G. Kanatzidis<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Bioinorganic Chemistry<br />
Enzymes and Coenzymes<br />
M. Millar, Organizer<br />
E. Rybak-Akimova, Presiding<br />
1:30 81. Nature of the ferryl heme species in<br />
Compounds I and II. E. Raven,<br />
A. Gumiero, P. C. Moody<br />
1:50 82. Open conformational states of<br />
P450cam and a detailed pathway for<br />
opening of the substrate access channel.<br />
D. B. Goodin, Y. Lee, E. C. Glazer,<br />
R. F. Wilson, I. Rupniewski<br />
2:10 83. Using myoglobin as a model to<br />
study electron transfer in cytochromes<br />
P450 on the single molecule level.<br />
J. E. Jett, D. Li, D. Lederman,<br />
P. M. Gannett<br />
2:30 84. N 2 and H 2 activation by �-diketiminato<br />
Nickel(I) complexes and hydrogenase<br />
activity of resulting hydrides.<br />
C. Limberg, S. Pfirrmann, R. Stößer,<br />
B. Braun, C. Herwig<br />
2:50 85. ONIOM Study on a missing piece in<br />
our understanding of heme chemistry:<br />
Bacterial tryptophan 2,3-dioxygenase<br />
(TDO) with dual oxidants. L. Chung,X.Li,<br />
K. Morokuma<br />
3:10 86. Studying the mechanism of NO reduction<br />
in flavodiiron proteins with a flavin-free<br />
enzyme. T. Hayashi, J. Caranto,<br />
D. A. Wampler, D. M. Kurtz, Jr,<br />
P. T. Moenne-Loccoz<br />
3:30 Intermission<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–61