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TECHNICAL PROGRAM - American Chemical Society Publications

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10:30 19. Studies on biologically important<br />

binary complexes in solution: The systems<br />

beryllium (II) and cobalt (II)- homoserine.<br />

B. B. Tewari, B. B. Tewari<br />

10:50 20. Zn(II) and Cu(II) detection with<br />

simple Schiff base systems. S. Khatua,<br />

J. Kang, K. Kim, H. Park, D. G. Churchill<br />

11:10 21. Development of triggereable chelating<br />

agents as probes for metal-induced<br />

oxidative stress. L. M. Hyman,<br />

K. J. Franz<br />

11:30 22. Further studies of bis(carboxylato)<br />

platinum(IV) compounds: Correlation between,<br />

liphoilicity, reduction potential,<br />

cellular accumulation and cytotoxicity.<br />

M. R. Reithofer, A. Bytzek,<br />

S. M. Valiahdi, C. R. Kowol, M. Groessl,<br />

M. Galanski, C. G. Hartinger,<br />

M. A. Jakupec, B. K. Keppler<br />

11:50 23. Anti-Fenton chemistry and detecting<br />

oxidative stress induced by metal and<br />

H 2O 2 in living cells. Y. Wei, Y. Zhang,<br />

Z. Liu, M. Guo<br />

12:30 24. Access to well-defined Ru(I) and<br />

Os(I) metalloradicals. A. Takaoka,<br />

L. C. Gerber, J. C. Peters<br />

Section E<br />

Boston Convention & Exhibition Center<br />

Room 257A<br />

General Inorganic Chemistry<br />

B. Donovan-Merkert, Organizer<br />

F. Beckford, Presiding<br />

8:30 25. Single-walled metal–organic nanotubes.<br />

K. Lu, H. Wu, Y. Jao, T. Tseng,<br />

S. Peng<br />

8:50 26. Magnificent FOX-7 can be tamed.<br />

S. Garg, H. Gao, B. Twamley,<br />

J. M. Shreeve<br />

9:10 27. Investigations of transition metalthiosemicarbazone<br />

complexes as medicinal<br />

agents. F. Beckford<br />

9:30 28. Mechanistic studies on the inhibition<br />

of enzymes and zinc finger transcription<br />

factors with cobalt(III) Schiff base<br />

complexes. T. A. Atesin,T.J.Meade<br />

9:50 29. Common fixatives used in the preservation<br />

of biological tissues.<br />

S. S. Mantravadi<br />

10:10 30. Copper cross-linked palindromic<br />

bipyridine substituted artificial tripeptides<br />

and the effects of anions on structure.<br />

J. A. Gallagher, L. A. Levine,<br />

M. E. Williams*<br />

10:30 31. Aminoethylglycine-modified ruthenium<br />

complexes: Scaffolds for photocatalysts.<br />

C. P. Myers, M. E. Williams*<br />

10:50 32. Duplex formation of ligand substituted<br />

aminoethylglycine di- and tri-peptides<br />

with Cu �2 . M. B. Coppock,<br />

J. Miller, M. E. Williams*<br />

11:10 33. Photophysical properties, DNA<br />

photocleavage, and photocytotoxicity of<br />

a series of dppn dirhodium (II,II) complexes.<br />

L. E. Joyce, J. Aguirre,<br />

A. M. Angeles-Boza, A. Chouai,<br />

P. K. Fu-Giles, K. R. Dunbar, C. Turro<br />

11:30 34. Photodynamic therapy for skin<br />

carcinomas. R. A. Khanke,P.K.Fu<br />

11:50 35. Impact of triarylboron on the luminescence<br />

of Pt(II) acetylides: Enhanced<br />

phosphorescence and chemical sensing.<br />

C. Sun, Z. M. Hudson, S. Wang<br />

Section F<br />

Boston Convention & Exhibition Center<br />

Room 257B<br />

Chemistry of Materials<br />

Structure and Properties<br />

B. Donovan-Merkert, D. Nelson,<br />

Organizers<br />

P. Dinolfo, Presiding<br />

8:30 36. Studying protein-inorganic nanoparticle<br />

interactions in ferritin model systems.<br />

L. Zhang, D. Liu, J. Cheung-Lau,<br />

J. Swift, C. Butts, I. J. Dmochowski<br />

8:50 37. Perfluorographane: Synthesis and<br />

measurement of electrical and mechanical<br />

properties. J. S. Burgess,<br />

J. T. Robinson, M. Zalalutdinov,<br />

K. Perkins, P. Campbell, E. S. Snow,<br />

B. H. Houston, J. W. Baldwin<br />

9:10 38. Layer-by-layer formation of molecular<br />

multilayers using “click” chemistry:<br />

Synthetic versatility and thin-film characterization.<br />

P. H. Dinolfo, P. K. Palomaki,<br />

A. Krawicz<br />

9:30 39. Synthesis, electronic structure, and<br />

alignment of graphene thin films. V. Lee,<br />

R. V. Dennis, C. Jaye, D. A. Fischer,<br />

S. Banerjee<br />

9:50 40. Synthesis, reaction, characterization,<br />

and properties of high density energetic<br />

alkoxynitroiminotetrazoles. Y. Joo,<br />

J. M. Shreeve<br />

10:10 41. Microemulsion strategy for the<br />

synthesis of nano-LiFePO 4/C composites.<br />

S. Jheng, J. R. Carey, J. Chen<br />

10:30 Intermission<br />

10:50 42. Theoretical studies and investigations<br />

of a proposed new allotrope of carbon.<br />

P. J. Bonk<br />

11:10 43. High power oscillating thermoelectric<br />

waves from exothermic reactions<br />

around nanoscale thermal conduits.<br />

M. S. Strano, J. T. Abrahamson,<br />

W. Choi, J. Han, K. Kalantar-zadeh<br />

11:30 44. Electrostatic charging of fumed<br />

silica particles: Effect of surface treatment<br />

with alkylfluorosilanes. J. Liu,<br />

J. K. Floess, H. Tu, D. Fomitchev<br />

11:50 45. Catalytic activity of aggregated<br />

gold nanoparticles upon irradiation of<br />

light. J. Kim, B. W. Lavin<br />

12:10 46. <strong>Chemical</strong> processing of ferroelectric<br />

nanostructures with variable architectural<br />

complexity. G. Caruntu,<br />

S. Adireddy, A. Yourdkhani, C. Lin<br />

Section G<br />

Boston Convention & Exhibition Center<br />

Room 256<br />

Nanoscience<br />

Properties and Applications<br />

S. Wong, Organizer<br />

D. Dudis, Presiding<br />

8:30 47. Dynamic thin film fabrication of Palladium<br />

nanomaterials for application in<br />

hydrogen gas sensing. J. Zou, S. Iyer,<br />

C. Raston<br />

8:50 48. Graphene and nanowire transistors<br />

for cellular interfaces and electrical recording.<br />

T. Cohen-Karni, Q. Qing,<br />

L. Qiang, Y. Fang, C. M. Lieber<br />

9:10 49. Size-dependant magnetism in lanthanide<br />

chalcogenide nanomaterials.<br />

W. L. Boncher, S. L. Stoll<br />

9:30 50. Energy generation in carbon nanotube<br />

induced by the chemical reaction:<br />

Thermopower waves. W. Choi,S.Hong,<br />

J. Abrahamson, J. Han, C. Song, N. Nair,<br />

S. Baik, M. Strano<br />

9:50 51. Fullerene-based Superatom thermoelectric<br />

materials. D. S. Dudis,<br />

M. Check, H. A. Seibel, J. B. Ferguson,<br />

B. Elliott, J. Gengler, M. Leamy<br />

10:20 Intermission<br />

10:40 52. Effect of surfactant and surfactant<br />

content on electrical conductivity of single<br />

walled carbon nanotubes thin films.<br />

J. Hahn<br />

11:10 53. Novel, lanthanide-based nanoparticles<br />

for NIR to UV energy conversion.<br />

J. A. Ayres, I. N. Stanton, M. J. Therien<br />

11:30 54. Engineering nanoparticle catalysis<br />

via a multimetallic core/shell structure.<br />

V. Mazumder,S.Sun<br />

11:50 55. Withdrawn<br />

12:10 56. Enhanced solar energy conversion<br />

at quantum dot sensitized TiO 2 photonic<br />

crystals and disordered films by slow<br />

light effects. M. El Harakeh, S. Bayram,<br />

S. Jaber, L. Halaoui<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Room 258A<br />

Organometallic Chemistry<br />

Applications to Materials and Polymer<br />

Science<br />

N. Radu, Organizer<br />

E. Chen, Presiding<br />

9:00 57. Chiroptical and stereoregular polymers<br />

from achiral polar vinyl monomers<br />

by chiral metallocenium catalysts.<br />

E. Y. Chen<br />

9:20 58. “Click” synthesis of heteroleptic cyclometalated<br />

iridium(III) and platinum(II)<br />

complexes. S. Liu,T.M.Swager<br />

9:40 59. Tuning of electronic bandgap in<br />

conjugated polymers by chlorotricarbonyl<br />

rhenium(I) complexes. C. S. Mak,<br />

W. Cheung, Q. Leung, W. Chan<br />

10:00 60. Structure and catalysis of oxidesupported<br />

Ir-dimer catalysts for transfer<br />

hydrogenation. S. Muratsugu,<br />

Y. Kushida, H. Nakai, K. Isobe, T. Sasaki,<br />

M. Tada<br />

10:20 Intermission<br />

10:25 61. Isocyanate- and isothiocyanatederived<br />

Grubbs-Hoveyda type catalysts:<br />

Synthesis, structure, and activity.<br />

M. R. Buchmeiser, S. Kumar, I. Ahmad<br />

10:45 62. Ring-opening metathesis polymerization-based<br />

pore-size-selective<br />

functionalization of glycidyl methacrylatebased<br />

monolithic media: Access to sizestable<br />

nanoparticles for ligand-free metal<br />

catalysis. M. R. Buchmeiser, R. Bandari,<br />

T. Hoeche, K. Dirnberger, A. Prager<br />

11:05 63. Cobalt catalysts for the copolymerization<br />

of epoxides and carbon dioxide.<br />

M. R. Kember, C. K. Williams<br />

11:25 64. Hybrid polyoxometalates embedded<br />

in porous polymeric materials as heterogeneous<br />

catalytic systems.<br />

M. Carraro, M. Gardan, M. Bonchio,<br />

A. Sartorel, G. Scorrano<br />

Section C<br />

Boston Convention & Exhibition Center<br />

Room 258B<br />

Main Group Chemistry<br />

B. Donovan-Merkert, Organizer<br />

F. Gabbai, Presiding<br />

9:00 65. Dimethyl sulfide adduct of 9,10-dihydro-9,10-diboraanthracene:<br />

A powerful<br />

ditopic reagent for hydroboration and<br />

other transformations. A. Lorbach,<br />

M. Bolte, H. Lerner, M. Wagner<br />

9:20 66. Approaches to a novel boronbased<br />

cationic Lewis acid. A. Schnurr,<br />

M. Bolte, M. Wagner<br />

9:40 67. Synthesis of oligotopic arylborohydrides:<br />

Coordination chemistry and hydroboration<br />

reactivity. D. Franz,<br />

M. Wagner, M. Bolte<br />

10:00 68. Chiral organoborane derivatives<br />

based on the 1,2-ferrocenyl framework.<br />

J. Chen, T. Pakkarisamy,<br />

K. Venkatasubbaiah, F. Jäkle<br />

10:20 69. Carbene-stabilization of unusual<br />

main group molecules. Y. Wang,<br />

M. Abraham, P. V. Schleyer,<br />

G. H. Robinson<br />

10:40 Intermission<br />

10:50 70. Predicting the observed effect of<br />

force on S N2 cleavage kinetics of C–O,<br />

Si–O, and P–O bonds. T. J. Kucharski,<br />

Q. Yang, S. Akbulatov, Z. Huang,<br />

R. Boulatov<br />

11:10 71. Protonated clusters of M@Sn 9H 3and<br />

their relationships to the fused deltahedral<br />

clusters. F. S. Kocak, P. Y. Zavalij,<br />

B. W. Eichhorn<br />

11:30 72. Synthesis and anion-binding<br />

properties of a telluronium borane.<br />

H. Zhao,F.P.Gabbaï<br />

SUNDAY AFTERNOON<br />

Section B<br />

Boston Convention & Exhibition Center<br />

Room 258C<br />

Young Investigator Symposium<br />

F. Walker, Organizer, Presiding<br />

1:30 73. Mechanochromic luminescence of<br />

difluoroboron �-diketonate molecular solids.<br />

G. Zhang, J. Lu, M. Sabat,<br />

C. L. Fraser<br />

2:00 74. Magnetic resonance imaging<br />

agents for selective copper detection.<br />

E. L. Que,C.J.Chang<br />

2:30 75. Carbon monoxide-induced cleavage<br />

of dinitrogen promoted by group 4<br />

metallocene compounds.<br />

D. J. Knobloch, E. Lobkovsky,<br />

P. J. Chirik<br />

3:00 76. Synthesis and anion binding properties<br />

of cationic main group Lewis acids.<br />

Y. Kim,F.P.Gabbaï<br />

3:30 Intermission<br />

3:40 77. Synthetic and mechanistic studies<br />

of the ring-opening and denitrogenation<br />

of pyridine and picolines by a Ti-C multiple<br />

bond. A. R. Fout, B. C. Bailey,<br />

D. M. Buck, H. Fan, J. C. Huffman,<br />

M. Baik, D. J. Mindiola<br />

4:10 78. Pathways of hydrogen evolution<br />

catalyzed by cobalt(II) diglyoxime complexes.<br />

J. L. Dempsey, J. R. Winkler,<br />

H. B. Gray<br />

4:40 79. Optical resonances in semiconductor<br />

nanowires. L. Cao, M. L. Brongersma<br />

5:10 80. Chalcogels: Novel porous metalchalcogenide<br />

aerogels. S. Bag,<br />

M. G. Kanatzidis<br />

Section C<br />

Boston Convention & Exhibition Center<br />

Room 258B<br />

Bioinorganic Chemistry<br />

Enzymes and Coenzymes<br />

M. Millar, Organizer<br />

E. Rybak-Akimova, Presiding<br />

1:30 81. Nature of the ferryl heme species in<br />

Compounds I and II. E. Raven,<br />

A. Gumiero, P. C. Moody<br />

1:50 82. Open conformational states of<br />

P450cam and a detailed pathway for<br />

opening of the substrate access channel.<br />

D. B. Goodin, Y. Lee, E. C. Glazer,<br />

R. F. Wilson, I. Rupniewski<br />

2:10 83. Using myoglobin as a model to<br />

study electron transfer in cytochromes<br />

P450 on the single molecule level.<br />

J. E. Jett, D. Li, D. Lederman,<br />

P. M. Gannett<br />

2:30 84. N 2 and H 2 activation by �-diketiminato<br />

Nickel(I) complexes and hydrogenase<br />

activity of resulting hydrides.<br />

C. Limberg, S. Pfirrmann, R. Stößer,<br />

B. Braun, C. Herwig<br />

2:50 85. ONIOM Study on a missing piece in<br />

our understanding of heme chemistry:<br />

Bacterial tryptophan 2,3-dioxygenase<br />

(TDO) with dual oxidants. L. Chung,X.Li,<br />

K. Morokuma<br />

3:10 86. Studying the mechanism of NO reduction<br />

in flavodiiron proteins with a flavin-free<br />

enzyme. T. Hayashi, J. Caranto,<br />

D. A. Wampler, D. M. Kurtz, Jr,<br />

P. T. Moenne-Loccoz<br />

3:30 Intermission<br />

The official technical program<br />

for the 240th National Meeting<br />

is available at:<br />

www.acs.org/boston2010<br />

INOR<br />

TECH–61

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