TECHNICAL PROGRAM - American Chemical Society Publications

ORGN TECHNICAL PROGRAM
4:20 563. Catalysis by metal nanoparticles.
B. C. Ranu
4:40 564. New iron complexes and their catalytic
activity in C-C and C-O bond forming
reactions. E. B. Bauer, M. Lenze,
P. Shejwalkar
Section G
Boston Convention & Exhibition Center
Room 207
Material, Devices and Switches
S. Sieburth, Organizer
I. Aprahamian, Presiding
1:00 565. Solution processable high band
gap hosts based on carbazole functionalized
cyclic phosphazene cores for application
in organic light-emitting diodes.
M. Soh, S. Santamaria, H. Bolink,
A. Sellinger
1:20 566. Synthesis of phenylene-containing
acenoid structures. R. R. Parkhurst,
T. M. Swager
1:40 567. Photochemically triggered radical
reactions on graphitic carbons. L. Soldi,
R. J. Cullen, D. Jayasundara, D. Murphy,
E. Scanlan, S. Giordani, P. E. Colavita
2:00 568. Optimization of OLED power efficiency
by chemical structure modification.
A. B. Padmaperuma, P. K. Koech,
L. Cosimbescu, E. Polikarpov,
A. Von Ruden, J. E. Rainbolt,
J. S. Swensen, L. Wang, J. T. Darsell,
D. J. Gaspar
2:20 569. Development and utility of a lightresponsive
MRI T2 agent. E. A. Osborne,
A. Y. Louie
2:40 570. C 3-symmetric conjugation supported
by tris(hydrazone) platform: Elucidation
of tautomeric state and application
to amine vapor sensing. H. Lee,X.Song,
H. Park, D. Lee
3:00 571. Connecting metal centers in solution
with water soluble multi-walled carbon
nanotubes. J. M. Schnorr,
T. M. Swager
3:20 572. N, N�-dicarbazolyl-4,4�-biphenyl
(CBP) isomers with high triplet energies
as hosts for blue phosphorescence: Synthesis,
spectroscopy, and OLEDs.
P. Anzenbacher, G. V. Zyryanov,
C. Pérez-Bolívar, S. Takizawa
3:40 573. Gilch and Horner-Wittig Routes to
poly(p-phenylene vinylene) derivatives incorporating
monoalkyl defect-free 9,9-dialkyl-1,4-fluorenylene
units.
B. J. Laughlin,R.C.Smith
4:00 574. Poly(p-phenylenevinylene) derivatives
with defined conjugation segments
and post-polymerization modification
with chromophores. A. A. Buelt,
R. C. Smith
4:20 575. Wound healing modulation and
acceleration with novel nitric oxide releasing
hybrid nanoparticles.
A. Friedman, G. Han, L. Martinez,
J. Nosanchuk, J. Friedman
4:40 576. Nanoparticles as a novel topical
delivery vehicle for therapeutics targeting
erectile dysfunction. A. Friedman,
G. Han, M. Tar, A. Melman, K. Davies,
J. Friedman
5:00 577. Mimicry of amyloid �-sheets.
P. Cheng,J.S.Nowick
92–TECH
‡ Cooperative Cosponsorship
Section A
Boston Convention & Exhibition Center
Ballroom East
Arthur C. Cope and Arthur C. Cope
Scholars Award Symposium
S. Sieburth, Organizer
P. A. Evans, Presiding
1:20 578. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). C—H Oxidation in
organic synthesis. M. White
2:00 579. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Complexity building
reactions: Recent case studies.
J. Johnson
2:40 580. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Palladium-catalyzed
oxidation reactions for organic synthesis.
M. S. Sigman
3:20 581. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Carbon dichloride:
Dihalocarbenes sixty years after Hine.
R. A. Moss
4:00 582. Award Address (Arthur C. Cope
Award Sponsored by Arthur C. Cope
Fund). Pericyclic reactions: Reactivity,
mechanisms, and dynamics. K. N. Houk
Natural Products Biosynthesis Sponsored
by BIOL, Cosponsored by MEDI and ORGN
Oligonucleotide Therapeutics Sponsored by
CARB, Cosponsored by ANYL, BIOL, MEDI,
and ORGN
TUESDAY EVENING
Section A
Boston Convention & Exhibition Center
Hall C
Asymmetric Reactions and Syntheses,
Biologically-Related Molecules &
Processes, Material, Devices & Switches
and Peptides, Proteins & Amino Acids
A. Abdel-Magid, Organizer
8:00–10:00
583. Phosphine-catalyzed enantioselective
formation of �-arylthio �,�-unsaturated
esters from activated allenes.
Y. Fujiwara, J. Sun, G. C. Fu
584. Asymmetric aldol addition to cyclopentylpropynone
gives key intermediate to
antiviral drug candidate. J. Sieser,
R. A. Singer, P. Bowles, D. Lafrance
585. Enantioselective total synthesis of
streptorubin B. D. X. Hu, M. D. Clift,
R. J. Thomson
586. Enantioselective bromolactonization of
conjugated enynes. W. Zhang, S. Zheng,
N. Liu, J. B. Werness, W. Tang
587. Organocatalytic enantioselective hydroxyalkylation
of indoles with trifluoroacetaldehyde
hemiacetal catalyzed by
cinchona alkaloids. D. Borkin,S.Landge,
B. Torok
588. Enantioselective Friedel-Crafts alkylation
of indoles with chiral �-phenyl benzylic
cations: Asymmetric synthesis of
anti-1,1,2-triarylalkanes. J. Y. Chung,
D. Mancheno, P. G. Dormer, R. G. Ball,
N. N. Tsou
589. Sulfinimine-mediated asymmetric synthesis
of anti-a-alkyl b-amino Weinreb
amides and ketones. P. Xu, F. A. Davis
590. Asymmetric transfer hydrogenation of
quinolines using tethered Ru (II) catalysts.
V. Parekh, I. Lennon, J. Ramsden,
M. Wills
591. Highly active water-soluble and recyclable
organocatalyst for the asymmetric
1,4-conjugate addition of carbanion to
�,�-unsaturated aldehydes. B. Ni,
S. Ghosh, K. Dhungana, A. D. Headley
592. Stereoselective copper-catalyzed synthesis
of chiral 1,2- hydroxyalkyl moieties.
M. Fañanás Mastral, B. L. Feringa
593. Highly efficient synthesis of chiral epoxides
via borane reduction of 2-haloketones
catalyzed by spiroborate ester:
Application to the synthesis of optically
pure 1,2-hydroxy ethers and 1,2-azido alcohols.
M. Ortiz-Marciales, K. Huang,
H. Wang, M. De Jesús, C. Torruellas,
W. Correa, V. Stepanenko
594. Facile synthesis of [1,2,4]-triazolo[4,3-
A]-pyridine and related derivatives. J. Liu,
X. Lin, E. Liu
595. Origin of stereoselectivity induced by
Evans’ oxazolidinones in furan–oxyallyl
(4�3) cycloadditions. E. H. Krenske,
K. Houk, A. G. Lohse, J. E. Antoline,
R. P. Hsung
596. First asymmetric total synthesis of 3,3�biflavanone.
B. Ma
597. Highly selective organocatalytic
Michael-Michael cascade reaction gives
fused carbocycles. P. G. McGarraugh,
S. E. Brenner
598. Novel applications of BINOL-phosphates
in asymmetric catalysis.
A. Zamfir, C. Baudequin, S. B. Tsogoeva
599. Asymmetric ketone and imine reductions
using ruthenium catalysts.
J. Hopewell, M. Wills, J. E. Martins
600. Catalytic asymmetric synthesis of highly
functionalized cis-aziridines via a general
method for versatile diazoketones.
H. Ren,W.D.Wulff
601. Asymmetric synthesis of di- and trisubstituted
cyclopropanes through an intramolecular
ring closure.
M. M. Mulhern, J. M. Kallemeyn, Y. Ku
602. Synthetic strategies towards the synthesis
of enantiopure diamines predicted
to be a hundred million fold more basic
than the original proton sponge.
S. Purser, R. W. Alder, C. P. Butts,
G. C. Lloyd-Jones
603. Asymmetric organocatalysis using
DPEN and proline derivatives.
C. V. Manville, M. Wills, G. Docherty,
G. Woodwood, R. Padda
604. Recyclable fluorous organocatalysts for
asymmetric synthesis. Z. Zhang,
L. Wang, H. Zeng, W. Zhang
605. Double stereodifferentiation in the imine
substituent in aziridinations with diazoesters.
L. Huang, Y. Zhang,
W. D. Wulff
606. CB-1 receptor antagonist process development.
E. Reiff, L. Hobson,
S. Brueggemeier, R. Deshpande,
L. Greene, S. Kim, J. Li, L. Li, D. Lin,
O. Lyngberg, M. Mahoney, G. Powers,
X. Qian, B. Remy, V. Rosso, M. Sandoval,
E. Tang, P. Tattersall, K. TenHuisen,
C. Wei
607. Donor-acceptor cyclopropanes as
building blocks in (3�2) annulation reactions.
A. T. Parsons, A. G. Smith,
J. S. Johnson
608. Practical stereoselective synthesis of
(�)-polyoxamic acid via enatioselective
phase-transfer catalytic Michael reaction
and diastereoselective dihydroxylation.
Y. Lee,S.Jew,H.Park
609. Synthesis of microsclerodermins F, G,
H&I.A. H. Rathi, T. J. Donohoe
610. Development of a practical and efficient
synthesis of chloromethyl 2-ethoxy-2methylpropanoate.
W. Cai,
R. Colon-Cruz, N. D. Ide, Z. Peng,
J. A. Ragan, B. C. Vanderplas
611. Design and synthesis of VANOL and
VAPOL derivatives as new ligands.
Y. Guan,W.D.Wulff
612. Sample loading techniques for large
scale flash chromatography. J. E. Silver,
O. Mneimne, R. Pipes, M. Drooby
613. Asymmetric electrocyclization induced
by chiral oxazoline auxiliaries. K. Kim,
K. A. Parker
614. Vinylogous Mukaiyama approaches towards
the stereoselective synthesis of
bielschowskysin and norsecurinines.
A. G. Macabeo, O. Reiser
615. Organocatalytic addition of oxindoles to
nitrosobenzene. R. Rios, X. Companyó,
A. Moyano
616. Regiocontrolled asymmetric �,�-bisand
�,�,��,��-tetraalkylation of ketones
via N-amino cyclic carbamate chiral auxiliaries.
S. E. Wengryniuk,D.Lim,
D. M. Coltart
617. Design and synthesis of Cobalt(II) porphyrin
catalysts for stereoselective interand
intro-molecular cyclopropanation.
X. Xu, S. Zhu, X. Cui, H. Lu, R. Joshua,
P. Zhang
618. Synthesis of functionalized cyclopentenones
via Diels-Alder reaction of anthracene.
G. Eaksinitkun,
W. Phutdhawong, W. Phutdhawong
619. Enantioselective synthesis of 1-vinyltetrahydroisoquinolines
via Pd-catalyzed intramolecular
allylic amination using novel
diphosphonites and its application for the
formal total syntheses of Schulzeines
A-C. C. Lin,I.Ojima
620. Enantioselective synthesis of 1-vinyltetrahydroisoquinolines
through Pd-catalyzed
intramolecular asymmetric allylic
amination using novel monophosphoramidite
ligands. C. Chien,I.Ojima
621. Optically active 2-aryl cycloalkanones
by catalytic asymmetric carbon insertion.
V. L. Rendina,D.C.Moebius,
J. S. Kingsbury
622. Structure enantioselectivity relationship
studies involving cinchona alkaloid
dimers for the the stereoselective organocatalytic
chlorolactonization.
S. E. Marshall, R. Yousefi,
A. Jaganathan, B. Borhan
623. Recent developments in the Pauson
Khand reaction of allenol-acetates.
S. Majumder, K. M. Brummond
624. Asymmetric synthesis of cyclic cis-�amino
acid derivatives using sulfinimines
and prochiral Weinreb amide enolates.
N. Theddu, F. Davis
625. Synthesis of novel Spiroaminoborates
esters derived from nonracemic 1,2-Aminoalcohols.
M. De Jesús, M. M. Padilla,
V. Stepanenko, M. Ortiz
626. Catalytic enantioselective synthesis of
chiral allylboronates. J. E. Schultz,
G. R. Cook
627. Asymmetric [4 � 3] cycloaddition applied
to the synthesis of barekoxide and
barekol. Y. Lian, L. Miller, R. Sarpong,
H. M. Davies
628. Highly enantioselective rhodium-catalyzed
cyclopropenation of terminal
alkynes with styryldiazoacetates.
J. F. Briones
629. Chiral promoters to control the stereochemical
outcome of glycosylation reactions.
D. Liu, S. Sarrafpour, W. Guo,
B. M. Goulart, C. S. Bennett
630. Toward the asymmetric total synthesis
of antascomicin B via an asymmetric
transfer hydrogenation, an Ireland-
Claisen (ICR), and an allylic diazene (ADR)
rearrangement sequence. D. R. Clay,
M. C. McIntosh
631. Studies toward the enantioselective
syntheses of 3-hydroxy-2-oxindole containing
natural products. A. J. Ostlund,
B. Narayanaganesh, G. R. Cook
632. Ring opening of aziridinium ions: Synthesis
of enantiomerically pure amines
and substituted trans-allyl amines.
X. Sun, Y. Chen, H. Song, I. Sin,
M. Dadwal, H. Chong
633. Synthesis and enantioselective and regioselective
ring opening of aziridinium
ions. Y. Chen, H. Song, X. Sun,
W. Sawyer, I. Sin, M. Dadwal, H. Chong
634. Rate accelerated Wittig reactions using
water as a medium employing stabilized
ylides and aldehydes. M. B. Bergdahl,
A. El-Batta, C. Jiang, A. L. Cooksy
635. Double stereo-differentiation of chiral
imines in catalytic asymmetric aziridination
reaction. M. Mukherjee,
V. R. Pulgam, W. D. Wulff
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