TECHNICAL PROGRAM - American Chemical Society Publications

ORGN TECHNICAL PROGRAM
4:40 424. Practical large scale synthesis of
(4R,5R)-(-)-4,5-O-isoproylidene-2-cyclopentanone.
V. R. Neelagiri, C. Moon,
M. Neelagiri, K. Vines,H.Kim,R.Rajur
Section G
Boston Convention & Exhibition Center
Room 207
Physical Organic Chemistry: Calculations,
Mechanisms, Photochemistry and High-
Energy Species
S. Sieburth, Organizer
E. Greer, Presiding
1:00 425. Synthesis and characterization of
the first nonacene derivative. I. Kaur,
G. P. Miller
1:20 426. Rational design of pentacene derivatives
with truly exceptional photooxidative
resistances. I. Kaur, G. P. Miller
1:40 427. Ionic liquid impact on reaction
outcomes: A rational mechanism-based
approach. A. K. Croft,J.B.Harper,
H. Yau, S. G. Jones, S. A. Barnes,
J. M. Hook
2:00 428. Computational studies on site-selective
C-H oxidation. R. S. Paton,
K. N. Houk
2:20 429. Perylenediimide as base-pair surrogates
in DNA hairpins: Effect of the
number of base-pairs separating two PDI
chromophores on stability and spectroscopic
properties. T. A. Zeidan,
F. D. Lewis
2:40 430. Theoretical study of the groundstate
electronics of acenes and substituted
acenes including organothio substituted
pentacenes, heptacenes, and
nonacenes. R. P. Kopreski, G. P. Miller
3:00 431. Probing CH – � interactions by
dynamic NMR studies of substituted
o-quinodimethane [60]fullerene Diels-Alder
adducts. R. P. Kopreski,J.B.Briggs,
G. P. Miller
3:20 432. Bis-Peptide scaffolds as designed
probes for electron transfer phenomena.
M. F. Parker, C. E. Schafmeister,
D. H. Waldeck
3:40 433. Reduction of 4-tertbutylcyclohexanone
with complex metalhydrides.
S. Narayan, W. Diehl, J. Townsend
4:00 434. pH-responsive particles for anticancer
drug delivery. B. Gordon, D. Lim,
E. Achinivu, C. Luckett, S. Ehrman,
D. English
4:20 435. Regio-selective radiofluorination
of diaryliodonium salts. Y. Lee,
M. Hodoscek, J. Chun, V. W. Pike
Section B
Boston Convention & Exhibition Center
Room 205A/B
Robert Burns Woodward Memorial
Symposium
R. Williams, L. T. Scott, Organizers
W. Greenlee, Organizer, Presiding
1:30 436. Looking back: Linkage through
structure, symmetry, synthesis, spectroscopy,
and mechanism. T. R. Hoye
2:20 437. Quinine! A story of chemistry, history,
personalities, and ethics.
R. M. Williams,A.C.Smith
3:10 Coffee Break
3:30 438. Was plagiarism involved in the development
of the Woodward—Hoffmann
rules? J. I. Seeman
4:20 439. Towards linking tumor genomic
signatures to cancer therapeutics.
S. L. Schreiber
90–TECH
‡ Cooperative Cosponsorship
Chemistry and Policy: Solving Problems at
the Interface
The Scientist in Public Service, Energy, and
Innovation Sponsored by CHED,
Cosponsored by AGRO, ANYL, CHAS, COLL,
HIST, I&EC, INOR, NUCL, ORGN, POLY, and
PRES
MONDAY EVENING
Boston Convention & Exhibition Center
Hall C
Sci-Mix
A. Abdel-Magid, Organizer
8:00–10:00
155, 156, 163, 188, 198, 202, 204, 210, 216,
223, 227, 229, 231, 252, 254, 271, 299.
See previous listings.
583, 588, 590, 592, 595, 603, 615, 616, 624,
631, 638, 641, 657, 658, 662, 666, 672,
702, 708, 724, 740, 742, 744, 932, 934,
936, 939, 940, 948, 949, 950, 959, 981,
987, 988, 993, 997, 1008, 1021, 1023,
1039, 1070, 1082, 1085, 1091, 1092. See
subsequent listings.
TUESDAY MORNING
Section A
Boston Convention & Exhibition Center
Ballroom East
Arthur C. Cope and Arthur C. Cope
Scholars Award Symposium
S. Sieburth, Organizer
G. Molander, Presiding
8:00 440. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Orotidine 5�monophosphate
decarboxylase: Mechanism
and intrinsic binding energy.
J. A. Gerlt
8:40 441. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Molecular reporters
for cellular imaging based on synthetic
fluorophores and enzymatic ligases.
A. Y. Ting
9:20 442. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Molecular imaging
approaches to understanding chemistry
in the brain. C. J. Chang
10:00 443. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Organic synthesis
and molecular design in today’s medicine.
A. K. Ghosh
10:40 444. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Chemical intervention
into bacterial cell-cell signaling.
H. E. Blackwell
11:20 445. Award Address (Arthur C. Cope
Scholar Award (CSM) Sponsored by
Arthur C. Cope Fund). Imaging of single
organic molecules in motion.
E. Nakamura
Section B
Boston Convention & Exhibition Center
Room 205A/B
Young Academic Investigators
L. McElwee-White, H. Davies, Organizers,
Presiding
8:00 446. Strong CH hydrogen bonds and
the photodriven regulation of anions.
A. H. Flood, Y. Hua, K. P. McDonald,
S. Lee
8:30 447. Chemical insights from molecular
force probes. R. Boulatov
9:00 448. Cyclopropenones and cyclopropenium
ions: Reaction, design, and catalysis.
T. Lambert
9:30 449. Developing the basic science and
applications of boron(B)-nitrogen(N)-containing
heterocycles. A. J. Marwitz,
E. R. Abbey, P. G. Campbell, A. N. Lamm,
S. Liu
10:00 450. Enantioselective approach to
lactones: Design, scope, and mechanism.
V. M. Dong
10:30 451. Metallonitrene/alkyne metathesis
and beyond: Transition metal catalyzed
oxidative amination for organic synthesis.
S. B. Blakey
11:00 452. Design and development of catalytic
reactions involving organometallic
nucleophiles. E. R. Jarvo
11:30 453. Transition-metal catalyzed fluorination.
T. Ritter
Section C
Boston Convention & Exhibition Center
Room 206A
New Reactions and Methodology
S. Sieburth, Organizer
T. Driver, Presiding
8:00 454. Rapid synthetic organic reaction
analysis using ion mobility spectrometry.
C. A. Krueger, C. Wu, A. J. Midey,
S. X. Li, F. J. Antosz, Z. Zhang, G. Goetz
8:20 455. Nucleophilic catalysis by anilines
in reactions of reducing carbohydrates.
M. B. Thygesen, H. Munch, K. J. Jensen
8:40 456. Diversity-oriented synthesis of
Gewald thiophene scaffolds via isocyanide-based
multicomponent reactions.
Y. Huang,A.Dömling
9:00 457. Spiropiperidine and fused ring
systems from pyridine dearomatization.
S. G. Parameswarappa,F.C.Pigge
9:20 458. Allylic C—H amination for the
preparation of syn-1,3-amino alcohol motifs.
G. T. Rice, M. White
9:40 459. Novel approach to the synthesis
of omeprazole: An anti-peptic ulcer
agent. R. Bandichhor
10:00 460. Ru-catalyzed ring-closing metathesis-isomerization
cascade reactions.
T. E. Nielsen, E. Ascic, J. F. Jensen
10:20 461. Bismuth-initiated reactions toward
stereoselective syntheses of tetrahydropyrans
and dihydropyrans.
R. J. Hinkle, R. F. Lambert,
S. E. Ammann, L. C. Speight, J. Liu,
Y. Lian
10:40 462. Pyridine elaboration through direct
functionalization reactions.
J. J. Mousseau, A. B. Charette
11:00 463. Palladium-catalyzed functionalization
of alkenes via C-H activation using
hypervalent iodine reagents.
L. T. Pilarski, N. Selander, D. Böse,
K. J. Szabó
11:20 464. Asymmetric addition of organoindium
and organobismuth reagents
to electrophilic carbons.
N. Balasubramanian, G. R. Cook,
A. J. Ostlund
11:40 465. Metal-free alkene dioxygenations
using hydroxamic acids. V. A. Schmidt,
E. J. Alexanian
12:00 466. Formal [2 � 2 � 2] cycloaddition
strategy based on an intramolecular
propargylic ene reaction/Diels-Alder cycloaddition
cascade.
J. M. Robinson-Surry, T. Sakai,
R. L. Danheiser
Section D
Boston Convention & Exhibition Center
Room 203
Heterocycles and Aromatics
S. Sieburth, Organizer
W. Zhang, Presiding
8:00 467. Patterns of �-electron delocalization
in aromatic and antiaromatic organic
compounds in the light of the Hückel’s
4n�2 rule. J. Poater, F. Feixas, E. Matito,
M. Solà
8:20 468. Multicomponent reaction of cyanoacetamides:
One starting material and
many scaffolds. K. Wang, A. Doemling
8:40 469. Convenient approach for the synthesis
of isoxazoles and application to
nucleoside and oligonucleotide conjugation.
A. M. Jawalekar, F. P. Rutjes,
F. L. van Delft
9:00 470. Selective C-H arylation and alkenylation
of free-(NH2) adenines and related
heterocycles: Rapid access to potent
Hsp90 inhibitors. S. Sahnoun,
S. Messaoudi, J. Peyrat, J. Brion,
M. Alami
9:20 471. Isolation and characterization of
an unusual N-alkenyl pyridone.
C. E. Anderson
9:40 472. Reactivity of tethered diyne-�,�unsaturated
carbonyl compounds in
[2�2�2] cyclizations: Synthesis and diversification
of densely functionalized
heterocyclic scaffolds. A. L. Jones,
J. K. Snyder
10:00 473. 2D adapted Su-Schrieffer-Heeger
model for conducting polymer polypyrrole.
M. Li,X.Lin
10:20 474. Efficient synthesis of a thioglycosylated
chlorins and isobacteriochlorins
for bioimaging and diagnostics. S. Singh,
J. P. Tome, M. Vinodu, C. M. Drain
10:40 475. Rhodium-catalyzed cycloaddition
of benzamides and alkynes via C-H/
N-H activation. T. K. Hyster,T.Rovis
11:00 476. Preparation and evaluation of
steroid-porphyrin conjugates as photodynamic
therapy agents. S. Sadler,R.Ray,
G. B. Jones
11:20 477. Aromaticity indices of thiophene
and furan based on the NMR spectroscopic
studies of 1-aryl-3-heteroarylpropen-1-ones.
C. Lee
Section F
Boston Convention & Exhibition Center
Room 204B
Metal-Mediated Reactions and Syntheses
S. Sieburth, Organizer
C. Douglas, Presiding
8:00 478. Relating catalyst structure to reactivity:
A rationally-designed NHC-Pd catalyst
for amination and sulfination.
M. G. Organ
8:20 479. Development of a Pd(II)-catalyzed
3-step cascade sequence to produce
1-aryl-3-vinyl-isoindolines. F. J. Williams,
E. Jarvo
8:40 480. Novel and rapid access to Lysergic
acid: A remarkable triple tandem
domino reaction. A. Boyer, T. Gilles,
M. Lautens
9:00 481. Silylene transfer to allylic sulfides:
Episulfonium ion formation to afford substituted
silacyclobutanes. B. J. Ager,
L. E. Bourque, K. M. Buchner,
K. A. Woerpel
9:20 482. Palladium-NHC catalyzed cyclopentannulation
of diazabicyclic alkenes:
Direct access to cyclopenta[b]benzofuran
derivatives. B. Bhanu Prasad,
A. E. Buechele, S. R. Gilbertson
9:40 483. Nickel-catalyzed reductive crosscoupling
of aryl halides with alkyl halides.
D. A. Everson,D.J.Weix
10:00 484. Apparent copper(II) catalyzed
azide-alkyne cycloaddition.
W. S. Brotherton,L.Zhu
10:20 485. Systematic investigation into the
nature of Au (I) catalysts using propargyl
Claisen rearrangements. D. V. Vidhani,
M. E. Krafft, J. W. Cran, M. Mariappan
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