TECHNICAL PROGRAM - American Chemical Society Publications

INOR TECHNICAL PROGRAM
231. Biotransformation using artificial cofactors
photogenerated by metal complexes.
J. Kim,J.A.Kim
232. Synthesis and structure of intermediates
in copper-catalyzed alkylation of diphenylphosphine.
M. F. Cain,
R. P. Hughes, D. S. Glueck, J. A. Golen,
C. E. Moore, A. L. Rheingold
Section I
Boston Convention & Exhibition Center
Hall C
Organometallic Chemistry
Catalysis
N. Radu, Organizer
7:00–9:00
233. Synthesis, characterization and reactivity
of a novel arylspiroboronate ester.
G. M. Lee, C. M. Vogels, A. Decken,
S. A. Westcott
234. Approaches to the synthesis of C 3symmetric
P-stereogenic triphosphine ligands.
M. F. Cain, D. S. Glueck
235. Platinum (II) catalysts for the hydroarylation
of olefins: Effect of ligand donor
strength on catalytic activity.
M. R. Friedfeld,B.A.McKeown,
M. Sabat, T. B. Gunnoe
236. Transformation of bridging methylene
to methyl in complexes of Rh/Os and Ru/
Ir. R. L. DeKock, B. J. Burkhart,
B. M. Brandsen
237. Double activation of the geminal
carbon�hydrogen bonds in 1,3-butadiene
by a diiridium complex.
B. J. Burkhart,R.L.DeKock
238. Formation of methyl acrylate from CO 2
and ethylene via methylation of nickelalactones.
C. Bruckmeier,
M. W. Lehenmeier, R. Reichardt,
S. Vagin, B. Rieger
239. Visible light-driven hydrogen production
catalyzed by nickel and cobalt catalysts
containing cyclic phosphine ligands with
pendant bases. M. P. McLaughlin,
T. M. McCormick, R. S. Eisenberg,
P. L. Holland
240. Catalytic epoxidation of alkenes using
tripodal titanium polyhedral oligomeric
silsesquioxane (Ti-POSS). E. H. Aish,
M. Crocker, F. T. Ladipo
241. Palladium-catalyzed synthesis of carbazoles
via C-C cleavage. S. L. Rogers,
A. R. Chianese
242. Synthesis, characterization, and catalytic
activity of iridium-CCC-pincer complexes.
A. Mo, A. R. Chianese
243. Rigid, sterically diverse N-heterocyclic
carbene-pyridine chelates: Synthesis,
mild palladation, and palladium-catalyzed
allylic substitution. P. T. Bremer,
A. R. Chianese
244. Preparation of ruthenium carbene complexes
based on a novel NHCP ligand for
ROMP reactions. H. Salem, M. Schmitt,
U. Blumbach, P. Hofmann
245. Cationic Pt and Pd complexes for C—H
bond functionalization. M. H. Emmert,
M. S. Sanford
246. Theoretical studies of the activation of
carbon dioxide using transition metal
�-diketiminato complexes. C. Liu,
T. Cundari, A. Wilson
247. How might intermediate Q of methane
monooxygenase oxidize strong C-H
bonds: Mechanistic insights from studying
synthetic models. G. Xue,R.DeHont,
E. Münck, L. Que, Jr.
248. Search for the catalytic allylic CH-amination
of alkenes by Pd(II) and Pt(II) complexes
supported by bis-(di-t-butylphosphino)methane
(dtbpm). M. Ferreira,
P. Hofmann, V. B. Romakh, C. Jokisch
249. Novel dinuclear Ru-complex for water
oxidation. E. V. Johnston, E. A. Karlsson,
M. D. Kärkäs, B. Lee, B. Åkermark
64–TECH
‡ Cooperative Cosponsorship
Section J
Boston Convention & Exhibition Center
Hall C
Environmental Aspects of Inorganic
Chemistry
B. Donovan-Merkert, Organizer
7:00–9:00
250. DFT calculations leading to multiscale
modeling of CO 2 solutions.
O. A. Olatunji-Ojo, T. R. Cundari,
S. K. Boetcher
251. Comparison between acid aerosol exposure
of asthmatic schoolchildren and
traffic density in metropolitan Taipei.
C. Lin,I.Mao,Y.Chen,F.Sung,M.Chen
252. Characterization and carbon dioxide reactivity
of dinuclear molybdenum complexes.
C. T. Tran,E.Kim
253. Activation of CO 2 by bis(dithiolene-
)tungsten complexes relevant to DMSO
reductase. J. Seo,E.Kim
254. Rhodamine based sensor for nerve gas
mimics: Crystal structures and structure
function relationship. A. J. Weerasinghe,
C. S. Schmiesing, E. Sinn
MONDAY MORNING
Section C
Boston Convention & Exhibition Center
Room 258B
Organometallic Chemistry
Synthesis and Characterization
N. Radu, Organizer
C. Thomas, M. Buchmeiser, Presiding
8:30 255. Alkyne chemistry of low valent Cr
complexes supported by �-diimine ligands.
J. Shen,G.P.Yap,
K. H. Theopold
8:50 256. Coordination of a novel family of
tridentate bis-aryloxide-NHC chelating ligands
to Ti(IV) and Zr(IV): Synthesis,
structure, reactivity and use of the derived
complexes in the controlled ROP of
rac-lactide. S. Dagorne,
S. Bellemin-Laponnaz, C. Romain
9:10 257. Electronic factors affecting metalmetal
interactions in early/late heterobimetallics:
Substituent effects in Pt/Zr
bis(phosphinoamide) complexes.
B. G. Cooper,C.M.Thomas,
C. M. Fafard
9:30 258. Unique primary carbon-nitrogen
bond scission across a W-W multiple
bond and methyl dehydrogenation.
S. Sarkar, J. A. Culver, A. R. Peloquin,
I. Giviriga, K. A. Abboud, A. S. Veige
9:50 Intermission
9:55 259. Amidinate-supported tungsten(VI)
silyl complexes. M. E. Fasulo, T. D. Tilley
10:15 260. Synthesis, interconversion, and
reactivity of titanaaziridines and titanaoxiranes.
L. Li, K. E. Kristian, J. R. Norton
10:35 261. Carbon dioxide reduction by
low-valent molybdenum complexes.
W. H. Bernskoetter, B. Tyler
10:55 262. When “dispersion” means “cohesion”:
The crucial role of London force
in bimetallic systems. J. Djukic,
S. Grimme, T. Schwabe, I. Hyla-Kryspin
11:15 263. Mid-valent early transition metal
chemistry with derivatives of the bicyclic
guanidinate hpp — (hexahydropyrimidopyrimidinate).
L. Messerle
11:35 264. Polymer-supported, CO 2-protected
N-heterocyclic carbenes: Synthesis
and application in organo- and organometallic
catalysis. M. R. Buchmeiser,
G. M. Pawar
Section D
Boston Convention & Exhibition Center
Room 259A/B
Luminescence and Magnetism of
Lanthanide-Containing Materials
A. De Bettencourt Dias, Organizer
C. Cahill, Organizer, Presiding
8:30 Introductory Remarks
8:35 265. Luminescent Eu(III) complexes incorporated
into bulge-like structures in
DNA selectively bind small molecules.
J. R. Morrow, J. J. Kim, M. G. Frith,
R. Haner
9:05 266. Synthesis, crystal chemistry and
magnetic properties of RE 5–xMg xGe 4
(RE � Gd-Lu and Y) and RE 5–xLi xGe 4
(RE � Nd, Sm, Gd). S. Bobev
9:35 267. Controlling and exploiting energy
transfer pathways in luminescent lanthanide
complexes. S. Faulkner
10:05 Intermission
10:15 268. Benefits from polarized luminescence
of Ln(III)-containing systems.
G. Muller
10:45 269. Lanthanide-based hybrid nanoparticles
for biomedical imaging. W. Lin
11:15 270. Naphthalimide sensitized lanthanide(III)
luminescence. A. H. Shelton,
D. Sykes, M. D. Ward
11:35 271. Room temperature colloidal synthesis
of magnetic EuTe nanoparticles.
W. He, S. Somarajan, D. Koktysh,
J. Dickerson
11:55 Concluding Remarks
Section E
Boston Convention & Exhibition Center
Room 257A
Inorganic Chemistry
M. Millar, S. Koch, Organizers
J. Protasiewicz, W. Armstrong, Presiding
8:30 272. Inorganic physiology: Remodeling
of the cellular metallome in infectious disease
and mammalian development.
T. V. O’Halloran
9:10 273. Facile photochemical release of
NO from a rhodium nitrosyl complex.
A. Bakac, W. Song, K. Kristian
9:30 274. Electroactive cages and their linear
conjugates: Inorganic-organic hybrid
platforms for chemical sensing and electron
transport. D. Lee
9:50 275. Structural chemistry and properties
of metal organic frameworks based
on polyazaheteroaromatic ligands.
W. Ouellette, A. V. Prosvirin,
K. R. Dunbar, J. A. Zubieta
10:10 276. Platinum in molecules and platinum
in chains. L. H. Doerrer
10:30 277. Postsynthetic modification of
aluminum-based metal-organic frameworks.
S. M. Cohen
10:50 278. Synthesis and reactivity of metal
ion clusters. S. Banerjee, X. Zhang,
W. Lo, S. Vaddypally, W. H. Armstrong
11:10 279. Synthesis and iron chemistry of
novel biomimetic triptycene-based ligands.
Y. Li, S. J. Lippard
11:30 280. Phosphorus as a carbon-copy
and as a photo-copy. J. D. Protasiewicz,
M. P. Washington, V. B. Gudimetla
11:50 281. Selective aerobic oxidation reactions
involving organometallic C-H activation
pathways. S. S. Stahl
12:10 282. Catalytic, selective C-H bond
functionalizations with main group reagents.
J. F. Hartwig, D. W. Robbins,
C. W. Liskey, E. M. Simmons
Section F
Boston Convention & Exhibition Center
Room 257B
Chemistry of Materials
Magnetism and Electronic Effects
D. Nelson, Organizer
G. Halder, I. Bersuker, Presiding
8:30 283. Single-molecule magnetic and dipolar
bistability induced by the Jahn-
Teller effect. I. B. Bersuker,
P. Garcia-Fernandez
8:50 284. Cobalt coordination and clustering
in �-Co(OH) 2: Tuning magnetic properties
with kinetically controlled hydrolysis.
J. R. Neilson, J. A. Kurzman,
B. C. Melot, D. P. Shoemaker,
R. Seshadri, D. E. Morse
9:10 285. Catalysts supported on magnetic
mesocellular foams for versatile organic
transformations. S. Lee,S.N.Riduan,
N. Erathodiyil, J. Lim, Y. Han, J. Y. Ying
9:30 286. Magnetic and structural studies of
the frustrated kagomé antiferromagnet
Herbertsmithite, ZnCu 3(OH) 6Cl 2 and its
structural analogs. D. E. Freedman,
T. McQueen, R. Chisnell, T. Han,
Y. S. Lee, D. G. Nocera
9:50 287. Pressure-induced sequential orbital
reorientation in a magnetic framework
material. G. J. Halder,
K. W. Chapman, J. A. Schlueter,
J. L. Manson
10:10 Intermission
10:30 288. Phase controlled synthesis of
iron silicide (Fe 3Si and FeSi 2) nanoparticles
in solution. V. Chikan, N. Dahal
10:50 289. Synthesis, electronic structure,
and phase transitions of M xV 2O 5 nanostructures.
C. J. Patridge, S. Banerjee
11:10 290. Efficient charge transfer antenna
tetrathiafulvalene ligand for the sensitization
of Yb(III) luminescence. L. Ouahab,
F. Pointillart, T. Cauchy, O. Cador,
S. Golhen, O. Maury
11:30 291. Solvation effects on spin-crossover
complexes. J. Tao
11:50 292. True-Blue Alq 3: Combined substituent
effect in 8-hydroxyquinoline ligands
on emission color and triplet energy
tuning. P. Anzenbacher,
C. Pérez-Bolívar, S. Takizawa,
G. Nishimura, V. A. Montes
Section G
Boston Convention & Exhibition Center
Room 256
Nanoscience
One-dimensional Structures
S. Wong, Organizer
B. Wiley, Presiding
8:30 293. Gallium functionalization of nitrogen-doped
carbon nanotubes to form
gallium nitride carbon nanotube hybrid
material. T. J. Simmons,
M. Bravo Sanchez, E. Lopez Luna,
M. A. Vidal Borbolla,
H. Navarro Contreras
8:50 294. Fabrication and physical properties
of ZnO/CuO heterostructured nanowires.
K. Liao, P. Shimpi, P. Gao
9:10 295. Synthesis of single-crystalline 1D
LiNbO 3 nanorods. A. C. Santulli,
H. Zhou, S. Berweger, M. B. Raschke,
E. Sutter, S. S. Wong
9:30 296. Nonaqueous synthesis of molybdenum
dioxide nanorodes: Comprehensive
study of growth of nanoparticles, insitu
EXAFS monitoring of inorganic
reaction mechanism and their electrochemical
properties. D. Koziej,
A. Hintennach, J. Grunwaldt,
M. D. Rossell, P. Novak, M. Niederberger
9:50 297. Exfoliation of boron nitride nanotubes
prepared from a solid gas chemical
reaction. C. Hung, J. Hurst
10:10 Intermission
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