TECHNICAL PROGRAM - American Chemical Society Publications

10:40 486. Utilization of Stille cross coupling
protocol for the synthesis of series of biaryl-8-oxabicyclo[3.2.1]octane-2-carboxylic
acid methyl esters. L. Torun,
P. C. Meltzer
11:00 487. Palladium-catalyzed propargylic
substitution with phosphorus nucleophiles.
M. Kalek, M. Jezowska,
J. Stawinski
Section G
Boston Convention & Exhibition Center
Room 207
Material, Devices and Switches
S. Sieburth, Organizer
E. Bauer, Presiding
8:00 488. Luminescent phosphonium-bearing
polyelectrolytes. E. G. Tennyson,
T. Maltais, R. C. Smith
8:20 489. Novel crosslinking agents for the
control of inter-pi-system interactions in
organic semiconducting polymers.
A. Mangalum, R. C. Smith
8:40 490. High performance organic field effect
transistors from an organic single
crystal micro-ribbons by solution process.
Y. Zhou, T. Lei, J. Pei, J. Wang
9:00 491. Corannulene based blue emitters.
P. Bachawala,J.Mack
9:20 492. Easy access to a family of polymer
catalysts from modular star polymers.
V. O. Rodionov, H. Gao, S. Scroggins,
D. A. Unruh, A. Avestro, J. M. Fréchet
9:40 493. Chemical vapor detection using
reduced graphene oxide. S. K. Manohar
10:00 494. Boolean solid-state porosity
switching in a molecular organic solid.
J. T. Jones, T. Mitra, T. Hasell,
D. Holden, J. Bacsa, A. Steiner,
A. Trewin, A. I. Cooper
10:20 495. Supramolecular coupling agents
for adhesion promotion at interfaces.
C. A. Anderson, D. W. Kuykendall,
E. M. Briggs, S. C. Zimmerman
10:40 496. Redox active mesoporous hybrid
materials by incooperation of (oligo)phenothiazines
into structured silica phases.
A. W. Franz
11:00 497. Functionalizable boron-incorporating
polycyclic aromatics built upon the
seven-membered borepin ring structure.
A. Caruso Jr., M. A. Siegler, J. D. Tovar
11:20 498. Sub-ppm nerve agent detection
with chemically functionalized silicon
nanoribbon field-effect transistors.
A. Carella, S. Clavaguera, C. Celle,
L. Caillier, S. Lenfant, D. Vuillaume,
J. Simonato
11:40 499. Synthesis and characterization of
sulfated, dextran coated iron oxide nanoparticles
for MRI of macrophages. C. Tu,
A. Louie
12:00 500. Expansile polymeric nanoparticles
for the treatment of breast cancer.
K. V. Zubris, A. P. Griset, R. Liu,
Y. L. Colson, M. W. Grinstaff
Section E
Boston Convention & Exhibition Center
Room 204A
Total Synthesis of Complex Molecules
S. Sieburth, Organizer
S. Wiskur, Presiding
8:20 501. Synthetic studies on muraymycin
A1. M. Kurosu, K. Li, C. Schneider
8:40 502. Spirodiepoxide-based domino sequences
in total synthesis. L. J. Williams
9:00 503. Concise access to Xenicane diterpenes
and close biogenetic relatives.
L. J. Williams
9:20 504. Fused bicyclo[2.2.2]octanes: Toward
the core of atropurpuran.
M. J. Smith, J. A. Malona, E. J. Sorensen
9:40 505. Enantioselective synthesis of (�)isolysergol
via ring closing metathesis.
J. A. Deck, S. F. Martin
10:00 506. Synthetic efforts mediate a
structural reassigment of the M. tuberculosis-produced
natural product, Edaxadiene.
J. E. Spangler, C. A. Carson,
E. J. Sorensen
10:20 507. De novo asymmetric synthesis of
several cleistriosides and cleistetrosides.
B. Wu, M. Li, G. A. O’Doherty
10:40 508. Evaluation of an oxidative BDring
formation from a Diels-Alder derived
pyrrole-imidazole intermediate en route
to the polyheterocyclic core of
palau’amine. T. Doundoulakis,
C. J. Lovely
11:00 509. Fragment-based domain shuffling:
An approach facilitating downstream
drug discovery. E. Comer,
A. Clabault, H. Liu, L. A. Marcaurelle
11:20 510. Total synthesis of jadomycin A
and cyclitol analog of jadomycin B.
E. U. Sharif, G. A. O’Doherty
11:40 511. Enantioselective synthesis of indole
alkaloids of the ervatamine-silicine
group. B. Checa, N. Llor, M. Amat,
J. Bosch
Oligonucleotide Therapeutics Sponsored by
CARB, Cosponsored by ANYL, BIOL, MEDI,
and ORGN
Process Chemistry: The Role of Organic
Synthesis in Early Clinical Drug
Development Sponsored by MEDI,
Cosponsored by ORGN
TUESDAY AFTERNOON
Section B
Boston Convention & Exhibition Center
Room 205A/B
Young Academic Investigators
L. McElwee-White, H. Davies, Organizers,
Presiding
1:00 512. Stimuli-responsive polymer-protein
conjugates and “sweet-tooth” micelles.
B. S. Sumerlin
1:30 513. Chemical tools for mapping protein
S-nitrosation. M. Xian
2:00 514. Engineering Streptomyces bacteria
as lignocellulosic biorefineries.
J. K. Sello
2:30 515. Painting the cysteine chapel: New
tools to probe oxidation biology.
K. S. Carroll
3:00 516. Studying the bacterial cytoskeleton
using a chemical biological approach
provides new opportunities for antibiotic
development. D. B. Weibel,Y.Eun,
M. Foss
3:30 517. Chemical approaches to the investigation
of protein-membrane binding
interactions using synthetic lipid probes.
M. D. Best, M. D. Smith, D. Gong,
M. M. Rowland, H. E. Bostic, E. A. Losey
4:00 518. New unnatural products by harnessing
biosynthesis. R. J. Goss
4:30 519. Development and application of
carbon–carbon bond forming reactions
for organic synthesis. R. J. Thomson
Section C
Boston Convention & Exhibition Center
Room 206A
New Technologies to Expedite Research in
Organic Chemistry
C. Welch, Organizer, Presiding
1:00 520. New tools and technologies for
supporting drug development.
J. M. Hawkins
1:30 521. Reaction discovery approaches to
chemical diversity. J. A. Porco
2:00 522. Low-barrier high-throughput experimentation
tools for efficient chemistry
development. S. D. Dreher
2:30 523. Automation for enabling high
throughput reaction discovery.
J. C. Conrad, D. W. MacMillan
3:00 524. Implementation of a flexible strategy
for automating decision-enabling
process development workflows.
E. Rubin, T. Kudla, M. Liu, J. Qiu,
V. Rosso, V. Vydra, R. Waltermire
3:30 525. Automation and robotics in an academic
organometallic chemistry research.
S. C. Virgil,K.M.Kuhn,
J. B. Matson, S. R. Golisz, N. Hazari,
R. H. Grubbs, J. E. Bercaw, B. M. Stoltz
4:00 526. Current state and future prospects
for high throughput mass directed purification
technologies. J. W. Eschelbach,
G. Bi, L. Miller, W. Goetzinger
4:30 527. Micro- and mesoscale flow synthesis
promoted by microwave irradiation:
Is it a sustainable technology?
M. G. Organ
Section D
Boston Convention & Exhibition Center
Room 203
Heterocycles and Aromatics
S. Sieburth, Organizer
D. Klumpp, Presiding
1:00 528. Novel monomers and polymerization
strategies for organic semiconducting
polymers. R. C. Smith
1:20 529. Steric coordination control in conducting
metallopolymers: Photophysics
and electrochemistry. R. C. Smith,S.He
1:40 530. N-heteroacenes: Promising materials
for organic electronic devices.
A. L. Appleton,U.H.Bunz
2:00 531. Construction of protected hydroxylated
pyrrolidines using nitrogencentered
radical cyclizations.
M. Zlotorzynska, H. Zhai, G. Sammis
2:20 532. Fluorous linker facilitated synthesis
of heterocyclic systems. W. Zhang
2:40 533. Process development of a Corticotropin-Releasing
Factor 1 (CRF1) receptor
antagonist. C. Sfouggatakis,
S. Broxer, M. Fitzgerald, J. P. Sherbine
3:00 534. Exploring the barriers to metalfree
carbon nanotube growth. E. H. Fort,
L. T. Scott
3:20 535. Solid-phase synthesis of cleavable
fluorescently labeled nucleotides for
DNA sequencing. K. Ko, E. Roller,
X. Huang
3:40 536. New synthetic route to benzannulated
corannulenes. N. J. Smith,
L. T. Scott
4:00 537. Design, synthesis and characterization
of a diverse pyrazolopyrrolidinone
library. L. E. Brown,S.E.Schaus
4:20 538. Progress toward a [10,10] carbon
nanotube end-cap. J. M. Quimby,
L. T. Scott
4:40 539. Resolution and racemization kinetics
of cross-bridged cyclam.
A. Y. Odendaal, B. T. Li, G. R. Weisman,
E. H. Wong, J. A. Golen, A. L. Rheingold
5:00 540. Synthesis of Lavendamycin analogs
via cycloisomerization reactions of
propargylamides. G. Verniest,
D. England, X. Wang, N. De Kimpe,
A. Padwa
Section E
Boston Convention & Exhibition Center
Room 204A
Molecular Recognition and Self-Assembly
S. Sieburth, Organizer
Y. Luk, Presiding
1:00 541. Noncovalent chemistry of �-extended
tetrathiafulvalene derivatives and
fullerenes. E. M. Perez, H. Isla,
M. Gallego, N. Martin
1:20 542. Cucurbit[n]uril – metal nanoparticle
composites: Synthesis, self-assembly,
and applications. T. Lee,S.Jones,
R. Coulston, O. A. Scherman
1:40 543. Triply interpenetrated covalent organic
cages. T. Hasell,X.Wu,
J. T. Jones, J. Bacsa, A. Steiner, T. Mitra,
A. Trewin, D. J. Adams, A. I. Cooper
2:00 544. Novel method for synthesizing
self-assembled porous organic cages.
S. Jiang, D. Adams, A. Trewin, A. Cooper
2:20 545. Anionic amphiphilic dendrimers as
broad spectrum antimicrobial agents.
M. A. Mintzer, M. W. Grinstaff
2:40 546. Coordination vs. hydrogen bonddriven
self-assembly: A directed stereospecific
single crystal – single crystal
(SCSC) solid-state photodimerization of a
trisubstituted olefin. E. Elacqua,
J. C. Sumrak, L. R. MacGillivray
3:00 547. Pharmaceutical co-crystals of
chiral APIs: Crystal engineering and solidstate
properties. E. Elacqua, S. Chen,
R. F. Henry, G. G. Zhang,
L. R. MacGillivray
3:20 548. Turn-on fluorescence: Utilizing the
principles of dynamic combinatorial
chemistry for developing molecular sensors.
M. V. Maddipatla, A. M. Roland,
M. L. Waters, M. R. Gagné
3:40 549. Preparation of [3]pseudorotaxanes
and pseudorotaxane-type non-covalent
polymers based on bis(meta-phenylene)-32-crown-10
cryptand. Z. Niu,
H. W. Gibson
4:00 550. Self-assembly of dendronized triphenylenes
into helical pyramidal columns
and chiral supramolecular spheres.
M. R. Imam, V. Percec
4:20 551. Supramolecular polymeric nanowires
with tunable colors: Nucleation
growth and direct functionalization.
T. Lei, C. Cheng, C. Zheng, Y. Zhou,
D. Liang, J. Pei
4:40 552. Assembly of phthalocyanines into
stacked columns within 2D covalent organic
frameworks. E. L. Spitler,
W. R. Dichtel
Section F
Boston Convention & Exhibition Center
Room 204B
Metal-Mediated Reactions and Syntheses
S. Sieburth, Organizer
E. Alexanian, Presiding
1:00 553. C-C Bond formation via double
C-H functionalization. B. DeBoef
1:20 554. Diastereoselective rhodium-catalyzed
ene-cycloisomerization of alkenylidenecyclopropanes:
Application to the
total synthesis of (–)-�-kainic acid.
P. A. Inglesby,P.A.Evans
1:40 555. Gold-catalyzed Claisen rearrangement
of allenyl vinyl ethers: Synthesis of
substituted 1,3-dienes. M. E. Krafft,
K. M. Hallal
2:00 556. Addressing synthetic challenges
via iridium-catalyzed C-H borylation.
D. W. Robbins, J. F. Hartwig
2:20 557. How to make a gold catalyst “immortal”.
T. Graf, N. B. Bowden
2:40 558. Iron-catalyzed 1,4-additions to
1,3-dienes. J. Wu, T. Ritter
3:00 559. Building molecular complexity by
carbon-carbon bond activation and related
catalytic processes. C. J. Douglas
3:20 560. Kinetic studies of metal promoted
cyclizations of aromatic enynes.
A. Franklin
3:40 561. Nickel-catalyzed direct synthesis
of 1,4-difunctionalized compounds.
S. K. Rodrigo,H.Guan
4:00 562. Efficient synthesis of �-hydroxy
ketones and �-amino ketones from allylic
alcohols by catalytic formation of ruthenium
enolates. A. Bartoszewicz,
M. Jezowska, K. Laymand,
B. Martín-Matute
The official technical program
for the 240th National Meeting
is available at:
www.acs.org/boston2010
ORGN
TECH–91