TECHNICAL PROGRAM - American Chemical Society Publications

10:30 298. Growth mechanism of copper
nanowires and their properties in flexible,
transparent conducting films.
A. R. Rathmell, S. M. Bergin, Y. Hua,
Z. Li, B. J. Wiley
11:00 299. Effects of salt selection on the
rapid synthesis of silver nanowires.
S. Nandikonda, E. W. Davis
11:20 300. Synthesis of Ni and FeNi coreshell
nanorods. N. Shukla, J. B. Miller,
E. Coletta, A. Ondeck, J. Chung Lee,
A. J. Gellman
11:40 301. One-pot hydrothermal synthesis
of silver nanowires via citrate reduction.
Z. Yang, H. Qian, H. Chen, J. N. Anker
12:00 302. Boron nitride nanotubes from
graphene sheets. S. Xie, R. Huang,
L. Zheng
Section A
Boston Convention & Exhibition Center
Room 258A
Commemoration of the Founding of the
ACS Journal Organometallics
Synthesis and Catalysis
D. Lichtenberger, Organizer
L. Liebeskind, Presiding
9:00 303. Synthesis and chemistry of electrophilic
iridium and rhodium pincer complexes.
M. Brookhart,
W. H. Bernskoetter, M. Findlater,
C. Schauer, M. D. Walter
9:30 304. Reductive coupling of carbon
monoxide in Re and Mn carbonyl complexes
with pendant Lewis acids.
J. E. Bercaw, N. West, J. A. Labinger,
S. Yu, A. Hazari, A. J. Miller
10:00 305. Organometallic chemistry of synthetic
methods. J. F. Hartwig
10:30 Intermission
10:45 306. From 5-membered metallacyclo-cumulenes,
–pentynes and –allenes
to 4-membered metalla-dihetero-cycloallenes
and its complexes. O. Theilmann,
A. Villinger, A. Schulz, M. Lamac,
K. Kaleta, T. Beweries, P. Arndt,
W. Baumann, A. Spannenberg,
U. Rosenthal
11:15 307. Unique chemical properties of
non-traditional metal-carbon bonds.
Z. Xie
11:45 308. Methane activation and functionalization
by a transient titanium alkylidyne.
D. J. Mindiola, J. A. Flores,
D. M. Buck, G. Chen, J. E. Bercaw,
J. G. Andino
Section B
Boston Convention & Exhibition Center
Room 258C
Inorganic Materials: Electrochemistry and
Battery Applications
A. Marschilok, K. Takeuchi, Organizers
E. Takeuchi, Organizer, Presiding
9:00 309. Opportunities for multiple electron
transfer in cathode materials.
E. S. Takeuchi, C. Lee, Y. Kim,
A. Subramanian, A. C. Marschilok,
K. J. Takeuchi
9:30 310. Electrochemistry-materials interactions
and impact on battery design.
Y. Chiang
10:00 311. Aqueous electrolyte energy storage:
Materials and devices. J. Whitacre
10:30 312. Li-diffusion mechanisms and the
role of coherency strains during twophase
reactions in titanate electrodes for
Li batteries. A. Van der Ven,
J. Bhattacharya, A. Dalton, Y. Wang
11:00 313. Development and application of
nanophosphate batteries. B. Riley
Chemistry and Policy: Solving Problems at
the Interface
The Interface, Health, Environment, and
Security Sponsored by CHED, Cosponsored
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,
HIST, I&EC, INOR, NUCL, ORGN, POLY,
PRES, SCHB, and WCC
MONDAY AFTERNOON
Section C
Boston Convention & Exhibition Center
Room 258B
Ligand Design and Metal Behavior
L. Doerrer, M. Millar, Organizers
S. Koch, Organizer, Presiding
1:30 Introductory Remarks
1:35 314. Catalytic reduction of dinitrogen
to ammonia with molybdenum under mild
conditions. R. R. Schrock, B. Hanna,
J. Chin, M. Reithofer
2:15 315. Designing polymetallic reaction
sites: Ligand control of M-M interactions.
T. Betley
2:45 316. Building bulkier �-diketiminate ligands
for applications in bioinorganic
chemistry and catalysis. P. L. Holland,
T. R. Dugan, B. R. Dible,
W. W. Brennessel
3:15 Intermission
3:25 317. Ligand effects on copper-oxygen
reactivity. W. B. Tolman
3:55 318. Nickel catalysts for hydrogen oxidation
and production containing diphosphine
ligands with pendant amine bases.
M. Rakowski-DuBois, D. DuBois,
R. M. Bullock
4:25 319. Regulating the primary and secondary
coordination sphere within transition
metal complexes through ligand design.
A. Borovik
4:55 320. Ligand effects on the chemistry of
O 2-reactive divalent metal enolate and
enediolate complexes. L. M. Berreau
Section D
Boston Convention & Exhibition Center
Room 259A/B
Luminescence and Magnetism of
Lanthanide-Containing Materials
C. Cahill, Organizer
A. De Bettencourt Dias, Organizer,
Presiding
1:30 Introductory Remarks
1:35 321. All oxygen donor ligands as efficient
antennae for lanthanide luminescence.
K. N. Raymond
2:05 322. Structure-relaxivity relationships
among macrocyclic gadolinium(III) complexes.
V. Jacques, S. Dumas,
M. T. Greenfield, W. Sun, J. S. Troughton,
P. Caravan
2:35 323. Interaction of luminescent lanthanide-functionalized
gold nanoparticles
with bovine serum albumin (BSA).
S. Comby, T. Gunnlaugsson
3:05 Intermission
3:15 324. Developing lanthanide-based responsive
complexes. S. Pope,
M. Andrews, J. Jones
3:45 325. Gd-labeled porous silica microparticles
with large relaxivities studied in
vivo by MRI. C. Landry, J. Steinbacher,
S. Lathrop, J. Hillegass, B. Mossman
4:15 326. Lanthanide complexes utilizing
bis(pyrazolyl)pyridine and beta-diketonate
ligands to efficiently sensitize lanthanide
luminescence. J. M. Stanley,
B. J. Holliday
4:35 327. Buckyball maracas: Chemical and
electrochemical properties of trimetallic
nitride endohedral fullerenes.
L. Echegoyen, N. Chen, J. Pinzin
4:55 328. Physical properties of PbEuS
nanocrystals. S. Somarajan,W.He,
D. Koktysh, J. Dickerson
5:15 Concluding Remarks
Section F
Boston Convention & Exhibition Center
Room 257B
Bioinorganic Chemistry
DNA, RNA and Enzymes
M. Millar, Organizer
C. Goldsmith, Presiding
1:30 329. Silver and its roles in combating
diseases. J. R. Ellis
1:50 330. Photo-enhanced oxidative DNA
cleavage with non-heme iron complexes.
Q. Li, G. Roelfes
2:10 331. Two metals are better than one:
Interactions between dinuclear metal
complexes and quadruplex DNA.
R. Vilar, K. Suntharalingam
2:30 332. Computational study of the
nucleobase electronic structure dynamics:
How to do a fast but accurate job.
S. Keinan, R. Venkatramani, A. Balaeff,
D. N. Beratan
2:50 333. Hydrolysis of plasmid DNA by
metal complexes of modified cyclen.
I. O. Kady
3:10 334. Turning genes on and off with
light. B. Ruble, J. L. Richards, X. Tang,
J. Griepenburg, I. J. Dmochowski
3:30 Intermission
3:40 335. Mechanism of assembly of the dimanganese(III)-tyrosyl
radical cofactor of
Escherichia coli class Ib ribonucleotide
reductase. J. A. Cotruvo,J.Stubbe
4:00 336. Site-specific incorporation of 3-nitrotyrosine
as a probe of pK a perturbation
of redox-active tyrosines in ribonucleotide
reductase. K. Yokoyama, U. Uhlin,
J. Stubbe
4:20 337. Characterization of radical intermediates
on the PCET pathway in aminotyrosine-substituted
ribonucleotide reductases.
E. C. Minnihan,
M. R. Seyedsayamdost, J. Stubbe
4:40 338. Identification of a radical intermediate
in the catalytic cycle of methyl-coenzyme
M reductase. M. Dey,X.Li,
J. Telser, G. Gerfen, B. M. Hoffman,
S. W. Ragsdale
Section G
Boston Convention & Exhibition Center
Room 256
Nanoscience
PUI/Community College Nanoscience
S. Wong, Organizer, Presiding
1:30 339. Unusual phenomena at nanometer-sized
electrochemical interfaces.
M. V. Mirkin, J. Velmurugan
2:00 340. Nanostructured 3D architectures
incorporating bioactivity.
A. S. Harper-Leatherman, M. Iftikhar,
A. Ndoi, S. J. Scappaticci
2:30 341. Immobilization of inorganic nanoparticles
into smart polymer nanogels for
integration of sensing, cell imaging, and
controlled drug delivery. W. Wu,J.Shen,
P. Banerjee, S. Zhou
3:00 Intermission
3:20 342. Directed self-assembly within laponite
nanoscaffolds. M. E. Hagerman
3:50 343. Silver nanoparticle thin films: Factors
influencing formation and stability.
N. T. Flynn,M.I.Vara
4:20 344. Formation of Tris(trimethoxysilylpropyl)
Isocynurate (TTPI) capped palladium
nanoparticles onto single-walled
carbon nanotubes. T. Hemraj-Benny,
M. Chauhan, C. Wong, E. Kim
Section A
Boston Convention & Exhibition Center
Room 258A
Commemoration of the Founding of the
ACS Journal Organometallics
Synthesis, Devices, Hydrogen, Catalysis
D. Lichtenberger, Organizer
T. Marks, Presiding
2:00 345. Luminescent organometallics:
From design to assembly and functions.
V. W. Yam
2:30 346. Activation of dihydrogen by pentaarylboroles.
W. Piers,C.Fan,
L. Mercier, A. Houghton, M. Parvez
3:00 347. Molecular catalysts for oxidation
of hydrogen and production of hydrogen:
Shoving protons around with pendant
amines. R. M. Bullock,J.Y.Yang,
E. S. Wiedner, K. D. Welch, D. L. DuBois
3:30 Intermission
3:45 348. Reactivity studies on M(� 5 -
C 5Me 5) complexes (M � Rh, Ir) of a cyclometalated
aryl phosphine ligand.
E. Carmona
4:15 349. PSiP-Pincer palladium complexes
for innovative catalytic reactions.
N. Iwasawa
4:45 350. Molecular magnesium(I) complexes:
From chemical landmarks to versatile
reagents. C. Jones
5:15 351. Carbene-stabilization of highly reactive
diatomic molecules.
G. H. Robinson
Section B
Boston Convention & Exhibition Center
Room 258C
Inorganic Materials: Electrochemistry and
Battery Applications
A. Marschilok, E. Takeuchi, Organizers
K. Takeuchi, Organizer, Presiding
2:00 352. Synthesis, characterization and
electrochemical properties of silver hollandite
(Ag xMn 8O 16). K. J. Takeuchi,
S. Zhu, A. C. Marschilok, E. S. Takeuchi
2:30 353. Materials challenges and opportunities
of lithium-ion battery technology.
A. Manthiram
3:00 354. Science and practical performance
of metal fluoride nanocomposites
for advanced energy storage. F. Badway,
N. Pereira, A. Gmitter, I. Plitz, L. Wu,
G. G. Amatucci
3:30 355. Advanced Li-ion battery cathode
materials for vehicle technologies.
M. M. Doeff, T. Conry, K. Kam, A. Chern
4:00 356. Targeting new materials.
K. R. Poeppelmeier
4:30 357. Synthesis, characterization and
electrochemical properties of magnetite
(Fe 3O 4). S. Zhu, A. C. Marschilok,
E. S. Takeuchi, K. J. Takeuchi
Section E
Boston Convention & Exhibition Center
Room 257A
Inorganic Spectroscopy and
Electrochemistry
S. Ronco, Organizer
H. Patterson, Presiding
2:00 358. Spectroscopic study of heterometallic
d 8 -d 10 and d 10 -d 10 exciplex nanoclusters
doped in alkali halide single crystals.
H. H. Patterson, F. Baril-Robert,
X. Li, D. A. Welch, C. L. Larochelle
2:20 359. Spectroscopic and electronic
structure studies of copper (II) binding to
His111 in the human prion protein fragment
106-115: Evaluating the role of protons
and methionine residues.
L. Rivillas-Acevedo, R. Grande-Aztatzi,
I. Lomelí, E. Barrios, S. Teloxa, J. García,
A. Vela, L. Quintanar
The official technical program
for the 240th National Meeting
is available at:
www.acs.org/boston2010
INOR
TECH–65