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TECHNICAL PROGRAM - American Chemical Society Publications

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INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />

3:40 87. NMR solution studies on NikR and<br />

UreE: Proteins involved in the biochemistry<br />

of nickel. S. Ciurli<br />

4:00 88. Carboxylic acids enhance the activity<br />

of biomimetic 3d-metal complexes in<br />

hydrogen peroxide activation reactions.<br />

E. V. Rybak-Akimova, O. V. Makhlynets,<br />

V. G. Organo, T. D. Palluccio<br />

4:20 89. Ligand and metal effects on the formation<br />

of O 2-reactive divalent metal enolate<br />

complexes: Evaluation of the influence<br />

of water. K. Grubel, K. Rudzka,<br />

C. Read, A. Fuller, L. M. Berreau,<br />

A. M. Arif<br />

4:40 90. Synthesis and stability of the clusters<br />

[Fe 4S 4(SR) 4] 2- in aqueous and partially<br />

aqueous media. W. Lo,T.A.Scott,<br />

R. H. Holm<br />

5:00 91. Site-differentiated iron-sulfur single<br />

cubanes as possible building blocks in<br />

the synthesis of higher-nuclearity clusters.<br />

A. Majumdar,L.Deng,R.H.Holm<br />

Section D<br />

Boston Convention & Exhibition Center<br />

Room 259A/B<br />

Coordination Chemistry<br />

Synthesis<br />

D. Crans, Organizer<br />

J. Scott, Presiding<br />

1:30 92. Zeolitic boron imidazolate frameworks.<br />

T. Wu, J. Zhang, C. Zhou,<br />

L. Wang, X. Bu, P. Feng<br />

1:50 93. Rational design of a porous metal<br />

organic framework and its gas absorption<br />

properties. X. Zhao,T.Wu,X.Bu,<br />

P. Feng<br />

2:10 94. Different ferroelectricity in two isostructural<br />

1D coordination polymers.<br />

L. Long<br />

2:30 95. Clathrochelate frameworks as the<br />

promising molecular scaffolds for new<br />

nanosized (photo)electronic devices and<br />

(radio)pharmaceuticals. Y. Z. Voloshin,<br />

O. A. Varzatskii, S. V. Shul’ga,<br />

A. S. Belov, I. G. Makarenko,<br />

K. Y. Zhizhin, N. T. Kuznetsov,<br />

Y. N. Bubnov<br />

2:50 96. Construction of high-nuclearity silver<br />

alkynyl clusters with anion templates.<br />

Q. Wang<br />

3:10 97. Magnetic chain compounds incorporating<br />

[ReCl 4(CN) 2] 2- . T. D. Harris,<br />

M. V. Bennett, R. Clerac, J. R. Long<br />

3:30 Intermission<br />

3:40 98. Using tripodal amine ligands to<br />

synthesize Cu-Gd bimetallic complexes.<br />

C. A. Barta, J. Post, B. Hervert, J. Kranz<br />

4:00 99. Synthesis of biorelevant zinc and<br />

copper complexes by utilizing bulky<br />

Tris(3-R-5-R�-1,2,4-triazolyl)borate<br />

(Ttz R,R� ) ligands. M. Kumar, E. T. Papish,<br />

M. Zeller<br />

4:20 100. New reactivity of anionic niobium<br />

phosphide complexes: Activation of P 4<br />

and generation of diatomic PN. D. Tofan,<br />

C. C. Cummins<br />

4:40 101. Design and development of reactive<br />

metal-ligand systems. C. C. Lu<br />

5:00 102. Trinuclear manganese clusters assembled<br />

with a novel tripodal tacn-based<br />

ligand. R. Cao, S. J. Lippard<br />

5:20 103. Synthesis and characterization of<br />

transition metal complexes supported by<br />

triazine-based ligands. K. D. Chisholm,<br />

J. Cull, J. Scott<br />

Section E<br />

Boston Convention & Exhibition Center<br />

Room 257A<br />

Electrochemistry<br />

62–TECH<br />

B. Donovan-Merkert, Organizer<br />

Y. Hao, Presiding<br />

‡ Cooperative Cosponsorship<br />

1:30 104. Development of non-flammable<br />

electrolytes for lithium ion batteries.<br />

S. Dalavi, M. Xu, B. Ravdel, B. L. Lucht<br />

1:50 105. Inhibition of electrolyte oxidation<br />

in lithium ion batteries with electrolyte additives.<br />

T. Markmaitree,L.Yang,<br />

B. Lucht<br />

2:10 106. Electrochemical reduction of dinitrogen<br />

to ammonia using the<br />

[HIPTN 3N]Mo catalyst. T. Munisamy,<br />

R. R. Schrock<br />

2:30 107. Oxygen evolution mediated by a<br />

cobalt based thin film electrocatalyst.<br />

Y. Surendranath, D. G. Nocera<br />

2:50 108. Investigation of photocatalytic hydrogen<br />

generation by light-initiated chronoamperometry.<br />

J. I. Goldsmith<br />

3:10 Intermission<br />

3:20 109. Electrocatalysis of oxygen evolution<br />

reaction in Li-air batteries for energy<br />

storage application. Y. Lu,<br />

H. A. Gasteiger, Y. Shao-Horn<br />

3:40 110. Remarkable reactivity of ruthenium<br />

catalyst for C-H activation: A case<br />

study of alcohol oxidation. A. Paul,<br />

J. Hull, Z. Chen, T. J. Meyer<br />

4:00 111. Electron transfer on vertically<br />

aligned carbon nanofibers. E. C. Landis,<br />

R. J. Hamers<br />

4:20 112. Effect of cationic species on the<br />

oxygen reduction reaction (ORR) activity<br />

of perovskite transition metal oxides in<br />

the alkaline environment: Elucidating the<br />

charge transfer mechanism on model oxide<br />

surfaces. J. Suntivich, N. Yabuuchi,<br />

H. A. Gasteiger, Y. Shao-horn<br />

4:40 113. Formation of Au nanoparticles<br />

through reduction of Na 3Au(SO 3) 2 by<br />

electrochemically evolved hydrogen.<br />

Y. Hao, Y. Li, C. Huang, C. Muangphat<br />

Section F<br />

Boston Convention & Exhibition Center<br />

Room 257B<br />

Chemistry of Materials<br />

Novel Applications<br />

D. Nelson, Organizer<br />

P. Kim, Presiding<br />

1:30 114. Employing permanganate oxidations<br />

in organic chemistry as a synthetic<br />

route toward LiMn 2O 4 spinel, a Li-ion<br />

battery cathode material. B. M. Bartlett,<br />

B. J. Liddle, B. P. Clifford<br />

1:50 115. Cobalt-based catalyst deposited<br />

on low-bandgap semiconductor photoanodes<br />

for visible-light induced water oxidation.<br />

R. Costi, E. R. Young, V. Bulovic,<br />

D. G. Nocera<br />

2:10 116. Hafnium (IV) and zirconium (IV)<br />

porphyrinato and phthalocyaninato diacetate<br />

complexes as new dyes for solar<br />

cell devices. I. Radivojevic, C. M. Drain,<br />

M. Sfeir, C. T. Black, B. P. Burton-Pye<br />

2:30 117. New Tantalum (oxy)nitride photocatalysts<br />

designed for overall water splitting<br />

under visible light. C. Ho,<br />

M. J. Randall, P. T. Snee, K. Low<br />

2:50 118. Role of inorganic anions in crystal<br />

engineering of novel materials for nonlinear<br />

optics based on hydrogen bonded<br />

salts of polarizable organic molecules.<br />

I. Nemec, I. Matulkova, M. Fridrichova,<br />

I. Cisarova, R. Gyepes, P. Nemec<br />

3:10 119. Hierarchical self-assembly of<br />

nanoparticles and nanofibers: Toward<br />

photocatalysis. F. O. Ochanda,<br />

M. R. Barnett<br />

3:30 Intermission<br />

3:50 120. Development of thin film cobalt<br />

metal anode as scaffold and Co 2� source<br />

for formation of cobalt-based water oxidation<br />

catalyst. E. R. Young, V. Bulovic<br />

4:10 121. Facile size-tuning of gold nanoparticles<br />

onto thiol functionalized carbon<br />

nanotubes and their electrocatalytic activity<br />

for oxygen reduction reaction.<br />

J. Kim, S. Lee, S. Chen, Y. Shao-Horn<br />

4:30 122. Phthalocyanines for thermoelectric<br />

applications. D. S. Dudis,<br />

J. Shumaker, C. Chen, J. B. Ferguson,<br />

J. E. Schmidt, E. Kemp, A. V. Fratini<br />

Section G<br />

Boston Convention & Exhibition Center<br />

Room 256<br />

Nanoscience<br />

Zero-dimensional Structures<br />

S. Wong, Organizer<br />

J. Pettibone, Presiding<br />

1:30 123. AuPt nanoparticles with a Pt-rich<br />

surface layer. Z. Xu, J. Suntivich, J. Kim,<br />

C. Carlton, H. Gasteiger, Y. Shao-Horn,<br />

K. Hamad-Schifferli<br />

1:50 124. Pd 0 ,Ag 0 , and Au 0 nanoparticles<br />

supported on porous, thermally stable<br />

M IV phosphonate frameworks.<br />

H. P. Perry, J. Law, A. Clearfield<br />

2:10 125. Synthesis and shape control of Pt<br />

and Pt-based alloy nanocrystals.<br />

Y. Kang, X. Ye, C. B. Murray<br />

2:30 126. Nanocomposite materials: A simple<br />

route toward effective supported<br />

nanocatalysts. S. E. Hunyadi Murph,<br />

E. B. Fox, S. Serkiz, H. Colon-Mercado,<br />

L. Sexton, R. D. Torres, M. Siegfried<br />

2:50 127. Growth and formation of tunable,<br />

monodisperse phosphine-protected gold<br />

clusters. J. M. Pettibone, J. W. Hudgens<br />

3:20 Intermission<br />

3:30 128. Shape controlled colloidal synthesis<br />

of rock-salt lead selenide nanocrystals.<br />

A. M. Jawaid, D. Asunskis,<br />

L. Hanley, P. T. Snee<br />

4:00 129. Quantitative and size-tunable<br />

quantum growth using sec-phosphine<br />

chalcogenide anion sources.<br />

C. M. Evans<br />

4:20 130. Rational synthesis of heterostructured<br />

nanoparticles with shape control.<br />

C. Wang, V. R. Stamenkovic,<br />

N. M. Markovic<br />

4:40 131. Generalized strategy for the photochemical<br />

synthesis of group II-VI nanoparticles.<br />

T. Warwick, W. Thornley,<br />

T. E. bitterwolf<br />

5:00 132. Simple synthesis of Pd-Fe3O4<br />

heterodimer nanocrystals and their applications<br />

to magnetically recyclable catalyst<br />

for Suzuki cross-coupling reactions.<br />

Y. Jang,T.Hyeon<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Room 258A<br />

Commemoration of the Founding of the<br />

ACS Journal Organometallics<br />

Reminiscences, Catalysis, Main Group,<br />

Organosilicon<br />

D. Lichtenberger, Organizer<br />

M. Bochmann, Presiding<br />

1:50 Introductory Remarks<br />

2:00 133. Third generation: Thousands of<br />

new catalysts for olefin metathesis.<br />

R. R. Schrock, A. J. King, S. Marinescu,<br />

Y. Zhao, A. Lichtscheidl, M. Flook,<br />

L. Gerber<br />

2:30 134. Dietmar Seyferth’s favorites: The<br />

elements of group 14. H. W. Roesky<br />

3:00 135. Researches on unusual molecular<br />

organic compounds of the lanthanides.<br />

M. F. Lappert<br />

3:30 Intermission<br />

3:45 136. New pathways in metal-mediated<br />

transformations of organosilicon compounds.<br />

D. Tilley<br />

4:15 137. Stoichiometric and catalytic reactions<br />

of the (pentamethylcyclopentadienyl)silicon(II)<br />

cation. P. Jutzi,<br />

K. Leszczynska, A. Mix, B. Rummel<br />

4:45 138. Heteroallenes E�C�E� (E, E��<br />

group 14 and 15 elements). J. Escudie<br />

5:15 139. Changing pathways by replacing<br />

carbon by silicon: Examples in d and f<br />

transition metal compounds.<br />

O. Eisenstein<br />

Synthetic Chemistry for Biological Imaging,<br />

Quantitation, and Discovery Sponsored by<br />

BIOL, Cosponsored by INOR<br />

SUNDAY EVENING<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Hall C<br />

Bioinorganic Chemistry<br />

M. Millar, Organizer<br />

7:00–9:00<br />

140. New chiral dinuclear platinum(II) complexes<br />

bridged by tartrate: Unique diastereoselective<br />

effect on antitumor growth<br />

inhibition. S. Kaizaki<br />

141. Analysis of DNA mismatches and potassium<br />

ions using an aptamer probe and<br />

light switch complex. J. Kim<br />

142. Detection of small molecules and ions<br />

using conformational changes of DNA<br />

aptamers. J. Kim, B. N. Oh,M.Cha<br />

143. Near-stoichiometric conversion of hydrogen<br />

peroxide to oxoiron(IV) intermediates<br />

at nonheme iron centers. F. Li,<br />

J. England, L. Que<br />

144. Olefin cis-dihydroxylation with bio-inspired<br />

iron catalysts containing facial N,<br />

N, O-ligands that mimic the active site of<br />

Rieske dioxygenases. Y. Feng,<br />

P. D. Oldenburg, L. Que<br />

145. Reaction paths in Mg(II) and Ca(II) catalyzed<br />

transesterification of an RNA model<br />

phosphodiester. D. O. Corona-Martínez,<br />

A. K. Yatsimirsky<br />

146. Reactivity of thiolate dinitrosyl iron<br />

complexes with dioxygen. H. Kalyvas,<br />

E. Kim<br />

147. Synthesis and dioxygen reactivity of Nbound<br />

dinitrosyl iron complexes.<br />

K. M. Skodje,N.Tran,E.Kim<br />

148. Investigating the NO reduction mechanism<br />

in terminal oxidases by low temperature<br />

photolysis studies. T. Hayashi,<br />

P. T. Moenne-Loccoz<br />

149. Active site of carbon monoxide dehydrogenase:<br />

Electronic structure studies of<br />

bridged molybdenum-copper complexes.<br />

A. Dinescu,J.Ash<br />

150. Investigating the nickel- and cobaltspecific<br />

response in the E. coli transcriptional<br />

derepressor, RcnR. K. A. Higgins,<br />

M. J. Maroney<br />

Section B<br />

Boston Convention & Exhibition Center<br />

Hall C<br />

General Inorganic Chemistry<br />

B. Donovan-Merkert, M. Millar, Organizers<br />

7:00–9:00<br />

151. Transition metal-salicylaldehyde complexes:<br />

Photophysical properties and applications.<br />

J. E. Bates, J. E. McGarrah<br />

152. Novel hydrogen-bonded host lattice<br />

built of 1-(diaminomethylene)thiourea and<br />

its derivative of 3-amino-1,2,4-thiadiazole-5-carbamate<br />

anion. J. Zhang, Q. Li<br />

153. Synthesis, luminescent and electrical<br />

characterization of two ruthenium complexes.<br />

S. Manickam, S. Sivasankaran,<br />

B. Varghese, R. Ramanathan<br />

154. Characterization of proton coupled<br />

electron transfer in a biomimetic oxomanganese<br />

complex: Evaluation of the DFT<br />

B3LYP level of theory. T. Wang,<br />

G. Brudvig, V. Batista<br />

155. New class of chiral ligands for the aqueous,<br />

lanthanide-catalyzed carbon–carbon<br />

bond-forming reactions. Y. Mei,<br />

P. Dissanayake, M. J. Allen<br />

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