TECHNICAL PROGRAM - American Chemical Society Publications

9:40 350. Probing tubulin interactions with
14-methyl epothilone D analogs.
E. M. Daly, R. E. Taylor
10:00 351. Triazole-gold catalysed synthesis
of �, � Unsaturated compounds from
propargyl acetate. L. S. Gautam,
D.Wang,X.M.Shi
10:20 352. Pyrimidine-Mannich base hybrids
as antitubercular agents: Facile synthesis
with ZnBF 4 in THF/water biphasic
system. M. S. Chorghade,
A. M. Rahatgaonkar, N. K. Longadge
10:40 353. Catalytic stereoselective allene
oxidation: Reagent controlled spirodiepoxide
formation. G. Hu, M. A. Drahl,
L. J. Williams
11:00 354. Asymmetric reduction by chiral
reagents. M. S. Chorghade,
R. S. CHORGHADE,R.H.Grubbs,
C. S. Daeffler
11:20 355. Organocatalytic synthesis of
spiro compounds. R. Rios,
X. Companyó, A. R. Alba, A. Moyano
11:40 356. Organocatalytic oxazolone addition
to 1,2-bisphenylsulfonylethene.
R. Rios, N. Bravo, A. R. Alba, G. Valero,
X. Companyó, A. Moyano
Section A
Boston Convention & Exhibition Center
Ballroom East
JOC: Defining the Frontiers of Organic
Chemistry for 75 Years
R. Boeckman, Organizer
C. Burrows, Organizer, Presiding
8:30 357. Organotrifluoroborates: Organoboron
reagents for the 21st century.
G. Molander
9:10 358. Fluorescent tools for chemical biology.
B. Imperiali
9:50 359. Explorations of organic chemistry
with catalytic amino acids and peptides.
S. J. Miller
10:30 360. Art of building small.
B. L. Feringa
11:10 361. Complex alkaloid total synthesis.
M. Movassaghi
11:50 Concluding Remarks (C. J. Burrows)
Section G
Boston Convention & Exhibition Center
Room 207
Physical Organic Chemistry: Calculations,
Mechanisms, Photochemistry and High-
Energy Species
S. Sieburth, Organizer
B. Shi, Presiding
8:40 362. Reactivity of photochemically
generated atomic oxygen in aqueous media.
R. D. McCulla
9:00 363. Gas-phase nucleophilic and elimination
reactions in simple alkyl nitrates.
J. M. Riveros, T. C. Correra
9:20 364. Mechanisms of lithium cuprate
coupling reactions: A computational
study. L. M. Pratt
9:40 365. Fiber-optic singlet-oxygen [ 1 O 2
( 1 ‚ g)] generator device serving as a point
selective sterilizer. D. Aebisher,
M. Zamadar, A. Mahendran, G. Ghosh,
C. McEntee, A. Greer
10:00 366. Exciton transfer rate between
conjugated polymer chains. Q. Lu,M.Li,
X. Lin
10:20 367. QM/MM molecular dynamics
simulations provide insight into the photoisomerization
mechanism of retinal in
rhodopsin and an artificial molecular
switch. I. Schapiro, M. Olivucci
10:40 368. Test to evaluate the performance
of aromaticity descriptors in all-metal and
semimetal clusters: An appraisal of electronic
and magnetic indicators of aromaticity.
J. Poater, F. Feixas,
J. Jimenez-Halla, E. Matito, M. Solà
11:00 369. The Thorpe-Ingold effect on
the Bergman cyclization of an elevencarbon
monocyclic enediyne: Theoretical
studies. E. M. Greer, O. Lavinda
11:20 370. Ab initio study of cerium(III) trapping
by the Schiff-base complex N,N�bis[2-(salicylideneamino)ethyl]ethane-
1,2-diamine for sensing applications.
A. L. Botelho, S. Gopalan, X. Lin
11:40 371. Functionalization of multilayer
fullerenes (carbon nanoonions) using diazonium
compounds and click chemistry.
K. Flavin, M. Chaur, L. Echegoyen,
S. Giordani
Chemistry and Policy: Solving Problems at
the Interface
The Interface, Health, Environment, and
Security Sponsored by CHED, Cosponsored
by AGRO, ANYL, BIOL, CCPA, CHAS, COLL,
HIST, I&EC, INOR, NUCL, ORGN, POLY,
PRES, SCHB, and WCC
MONDAY AFTERNOON
Section A
Boston Convention & Exhibition Center
Ballroom East
Tetrahedron Prize for Creativity in Organic
Chemistry
Contemporary Methods in Organic
Synthesis
S. Hall, D. Francissen, Organizers
S. Martin, Presiding
1:00 Introductory Remarks: Stephen F. Martin,
Presiding
1:05 372. New catalytic strategies for chemical
synthesis. M. J. Gaunt
2:00 373. Catalysis and cascades in complex
alkaloid natural product synthesis.
D. J. Dixon
2:55 374. Exocyclic and acyclic stereocontrol
in catalyzed reactions of ethylene:
Asymmetric hydrovinylation reactions in
natural product synthesis. T. RajanBabu
3:50 Intermission
3:55 Award Presentation: H. Waldmann & D.
Francissen
4:05 375. Award Address (Tetrahedron
Prize for Creativity in Organic Chemistry,
sponsored by Elsevier). Changing face of
organic synthesis. S. V. Ley
5:05 Concluding Remarks: S. F. Martin
Section C
Boston Convention & Exhibition Center
Room 206A
New Reactions and Methodology
S. Sieburth, Organizer
C. Larsen, Presiding
1:00 376. Organocatalytic amination of allenyl
esters and subsequent cyclization to
form azaproline derivatives. P. Maity,
S. D. Lepore
1:20 377. Enhanced hydrogen bond donor
catalysis. A. E. Mattson,S.S.So,
J. A. Burkett
1:40 378. Synthesis and fast Diels-Alder/
cross coupling reactions of boron substituted
1,3-dienes. L. Wang, M. E. Welker,
M. W. Wright, C. Day
2:00 379. Skeletal diversity via cationic rearrangements
of substituted dihydropyrans.
M. R. Medeiros, R. S. Narayan,
S. E. Schaus, J. A. Porco, Jr
2:20 380. Rhodium-catalyzed transformations
of non-sulfonyl 1,2,3-triazoles.
M. Zibinsky, V. Fokin
2:40 381. Attoreactors: Chemical reactions
carried out on a zeptomol (10 -21 mol)
scale. P. Anzenbacher, M. A. Palacios
3:00 382. XtalFluor-salts: Selective fluorination
reagents with enhanced thermal stability
and ease of handling. A. L’Heureux,
M. Couturier, F. Beaulieu, C. Bennett,
D. Bill, S. Clayton, F. LaFlamme,
M. Mirmehrabi, S. Tadayon, D. Tovell
3:20 383. Zinc-mediated chain extension as
an approach for the synthesis of papyracillic
acid C. J. R. Mazzone,
C. K. Zercher
3:40 384. Carbon-carbon bond formation
and pyrrole synthesis via the [3,3] sigmatropic
rearrangement of O-vinyl oxime
ethers. L. L. Anderson,H.Wang,
D. S. Mueller, R. Sachwani,
H. N. Londino, A. Papirnyak
4:00 385. Investigation onto the use of silica-supported
amines within packed-bed
and microstructured catalytic flow reactors.
L. Soldi, R. Maggi, G. Sartori,
S. Loebbecke
4:20 386. Para-selective direct arylation of
anisoles and aniline derivatives.
J. R. Brandt, C. Ciana, F. M. Meyer,
R. J. Phipps, M. J. Gaunt
4:40 387. Synthetic studies of a regiospecific
trisubstituted aziridine ring opening
reaction. B. Kelley, M. M. Joullie
5:00 388. Palladium-catalyzed intramolecular
carboesterification of olefin. Y. Li,
D. Song, D. M. Vy
Section D
Boston Convention & Exhibition Center
Room 203
Biologically-Related Molecules &
Processes
S. Sieburth, Organizer
K. Wang, Presiding
1:00 389. Synthesis of Pin1 WW domain libraries
via solid-phase phosphorylation.
X. R. Chen, A. Y. Mercedes-Camacho,
F. A. Etzkorn
1:20 390. Chemoselective Staudinger-phosphite
reactions: Applications to the phosphorylation
and PEGylation of proteins.
C. P. Hackenberger
1:40 391. Design of a continuous flow system
for the iterative cross aldol condensation
of aldehydes. S. A. France
2:00 392. Development of gadolinium and
xenon-based probes for MR molecular
imaging. B. DeBoef
2:20 393. Derivatives of ganglioside G M1 to
facilitate imaging and functional studies.
Z. Liu, K. Kumar
2:40 394. Novel inhibitors of fibroblast
growth factor receptor 1 kinase: Lead optimization
of thienopyrimidinones by
structure-based design. A. R. Ekkati,
K. P. Ravindranathan, V. Mandiyan,
J. H. Bae, J. Schlessinger,
W. L. Jorgensen
3:00 395. Synthesis and biological evaluation
of 3, 5-disubstituted isoxazolines as
potential antitumor agents.
M. S. Chorghae, A. M. Rahatgaonkar,
K. R. Lanjewar, B. D. Saraf
3:20 396. Pyrimidine derivatives as COX-1
and COX -2 inhibitors. M. S. Chorghade,
R. P. Dhankar, A. M. Rahatgaonkar
3:40 397. Mtb Bla-specific fluorescent
probes for tuberculosis detection and imaging.
H. Xie, J. Rao, J. Mire,
J. C. Sacchettini, Y. Kong, J. D. Cirillo
4:00 398. Discovery and synthetic development
of novel sterols as antileishmanial
agents. D. Abdelhamid,L.Pan,
A. Kinghorn, C. M. Lezama-Davila,
A. Satoskar, J. R. Fuchs
4:20 399. De novo asymmetric synthesis of
�-6-deoxyidopyranoside via Wharton rearrangement.
H. Wang,G.A.O’Doherty
4:40 400. Synthesis of a highly branched oligosaccharide.
G. A. O’Doherty, S. Kang
5:00 401. Protein cage polymer hybrid as a
potential MRI contrast agent.
M. J. Abedin, L. Liepold, M. Young,
T. Douglas
Section E
Boston Convention & Exhibition Center
Room 204A
Total Synthesis of Complex Molecules
S. Sieburth, Organizer
S. Waters, Presiding
1:00 402. Total synthesis of reserpine: Using
C-3 as an element for stereocontrol.
G. A. Barcan, O. Kwon
1:20 403. Electron transfer photoredox catalysis:
Applications in complex molecule
synthesis. J. M. Narayanam,
S. Diethelm, L. Furst, C. R. Stephenson
1:40 404. Convergent total synthesis of dinophysistoxin-2.
Y. Pang, C. J. Forsyth
2:00 405. Enantioselective formal total synthesis
of (�)-aspergillide C.
J. D. Panarese, S. P. Waters
2:20 406. Progress toward the total synthesis
of stemocurtisine utilizing an asymmetric
Stetter reaction. D. M. Rubush,
T. Rovis
2:40 407. Progress towards a total synthesis
of the selective cytotoxic natural product
maoecrystal V. D. D. McLeod,
W. J. Chain, M. Naylor, C. S. Jeffrey,
E. J. Sorensen
3:00 408. Approaches to the synthesis of
auxofuran. R. P. Loach, J. Boukouvalas
3:20 409. Total synthesis of Celogentin C via
stereoselective C-H activation. Y. Feng,
G. Chen
3:40 410. Studies toward the total synthesis
of acremoxanthones. A. J. Little,
J. A. Porco
4:00 411. Continued progress toward the
expedient syntheses of cephalostatin
“North 1” analogs. D. P. Jamieson,
P. L. Fuchs
4:20 412. De novo asymmetric synthesis of
Aspergillide. Y. Xing, G. A. O’Doherty
Section F
Boston Convention & Exhibition Center
Room 204B
Asymmetric Reactions and Syntheses
S. Sieburth, Organizer
S. Kulyk, Presiding
1:00 413. Enantioselective rhodium(II)-catalyzed
cyclopropanation of alkenes with
�-EWG diazoacetophenones: PMP-ketones
as stereoselectivity controllers.
V. N. Lindsay, A. B. Charette
1:20 414. Synthetic utility of W-alkylidene
monopyrrolide alkoxide complexes in olefin
metathesis. Y. Zhao, A. H. Hoveyda,
R. R. Schrock
1:40 415. Asymmetric arylhalogenation of
terminal olefins. A. Kubota,
M. S. Sanford
2:00 416. Asymmetric intramolecular alkene
cyanoamidation via carbon–carbon
sigma bond activation: Total synthesis of
(–)-Quebrachamine. V. J. Reddy,
C. J. Douglas
2:20 417. Asymmetric �-alkylation of ketones
via activated hydrazones.
D. M. Coltart
2:40 418. Toward the total synthesis of 20deoxyapoptolidinone.
V. M. Lombardo
3:00 419. New applications of asymmetric
dienamine catalysis. M. Christmann,
J. Stiller, E. Marques-Lopez, R. P. Herrera
3:20 420. Work toward the total synthesis of
pycnanthuquinone A via an asymmetric
Morita-Baylis-Hillman reaction.
A. M. Wensley, S. E. Schaus
3:40 421. Design and development of novel
chiral ligands for metal and organo catalysis.
S. Rasapalli,V.Kumbam,M.Yu
4:00 422. Development of the asymmetric
intermolecular Stetter reaction catalyzed
by N-heterocyclic carbenes. D. DiRocco
4:20 423. Chemical synthesis of micromide.
M. B. Bergdahl, I. Nevchas, M. Parker,
L. Wang, J. Duensing
The official technical program
for the 240th National Meeting
is available at:
www.acs.org/boston2010
ORGN
TECH–89