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TECHNICAL PROGRAM - American Chemical Society Publications

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INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />

9:30 613. Lanthanide-containing conducting<br />

metallopolymers for near-infrared lightemitting<br />

materials. X. Chen,Y.Yin,<br />

X. Yang, B. J. Holliday<br />

9:50 614. Nanostructured SiOC low dielectric<br />

film derived from inorganic polymer.<br />

Y. Kim, J. Kim, Y. Lee, W. Kwon, S. Kim,<br />

D. Choi<br />

10:10 Intermission<br />

10:30 615. Nanoscopic patterned materials<br />

with tunable dimensions via atomic layer<br />

deposition on block copolymers.<br />

Q. Peng, Y. Tseng, S. B. Darling,<br />

J. W. Elam<br />

10:50 616. Non-hydrolytic synthesis, characterization,<br />

and electronic structure of<br />

colloidal early transition metal oxide<br />

nanocrystals. S. W. Depner, K. R. Kort,<br />

C. Jaye, H. Zhang, D. A. Fischer,<br />

S. Banerjee<br />

11:10 617. Synthesis and characterization of<br />

amorphous pyrophosphates and their<br />

use in brushite bone cements. C. Slater,<br />

A. J. Wright, L. M. Grover, V. Burnell,<br />

D. Laurencin, J. A. Hriljac, M. E. Smith<br />

11:30 618. Hybrid polyoxometalates, from<br />

molecular catalysts to functional materials.<br />

M. Carraro, G. Modugno, A. Sartorel,<br />

M. Bonchio, G. Scorrano<br />

Section G<br />

Boston Convention & Exhibition Center<br />

Room 256<br />

Nanoscience<br />

Growth and Design<br />

S. Wong, Organizer<br />

I. Hakem, K. Balkus, Presiding<br />

8:30 619. Large scale ZnO nanodendrites<br />

converted by an in-situ carbothermal<br />

method and their application as gas sensors.<br />

P. Shimpi,P.Gao<br />

8:50 620. Thermal behavior study of<br />

�-Fe 2 O 3 and �-FeOOH nanocapsules<br />

structures. Y. Kim, R. Yu, J. Pee, K. Kim<br />

9:10 621. Tuning the metal-insulator phase<br />

transition in VO 2 nanostructures.<br />

L. Whittaker, T. Wu, C. Jaye, D. Fischer,<br />

S. Ganapathy, S. Banerjee<br />

9:30 622. Nanostructured vanadium oxides<br />

by chemical vapor transport and hydrothermal<br />

methods. J. M. Velazquez,<br />

C. Jaye, D. A. Fischer, S. Banerjee<br />

9:50 623. Vanadium oxide nanotube films<br />

prepared via pulsed laser ablation.<br />

K. Balkus, S. D. Perera, J. Bonso,<br />

J. Ferraris<br />

10:20 Intermission<br />

10:40 624. Experimental and theoretical<br />

evaluation of the distribution of functionality<br />

of surface modified nanoparticles.<br />

I. F. Hakem, J. Walker, A. Leech,<br />

J. Johnson, S. Donahue,<br />

M. R. Bockstaller<br />

11:10 625. Nanoclusters of dicyanocuprate<br />

(I) ions doped in different alkali halides.<br />

X. Li, D. A. Welch, F. Baril-Robert,<br />

H. H. Patterson<br />

11:30 626. Efficient assemby of photochromic<br />

spiropyran molecules on zeolite<br />

nanostructures. K. Dubois, E. Garcia,<br />

S. Bent, G. Li<br />

11:50 627. Controlling ice formation on<br />

nanostructured superhydrophobic surfaces.<br />

L. Mishchenko,B.Hatton,<br />

J. Taylor, V. Bahadur, T. Krupenkin,<br />

J. Aizenberg<br />

12:10 628. Large-scale soft colloidal template<br />

synthesis of 1.4 nm-thick CdSe<br />

nanosheets. J. Son, T. Hyeon<br />

70–TECH<br />

‡ Cooperative Cosponsorship<br />

Section C<br />

Boston Convention & Exhibition Center<br />

Room 258B<br />

Ligand Design and Metal Behavior<br />

L. Doerrer, S. Koch, Organizers<br />

M. Millar, Organizer, Presiding<br />

9:00 629. Coordination chemistry of bidentate<br />

and tridentate N-aryl-substituted imino-N-heterocyclic<br />

carbene ligands.<br />

G. G. Lavoie, S. Dastgir, A. C. Badaj,<br />

T. G. Larocque<br />

9:30 630. Ligands which provide hydrogen<br />

bonds near and far from the metal center.<br />

E. T. Papish, M. Kumar, I. Nieto,<br />

S. W. Shim, S. N. Oseback, N. A. Dixon,<br />

M. Zeller<br />

10:00 631. Ligands designed for mimicking<br />

the diiron centers of bacterial monooxygenases.<br />

L. Do, Y. Li, S. J. Lippard<br />

10:40 Intermission<br />

10:50 632. Fluorinated ligands vs. fluorine<br />

as a ligand. L. H. Doerrer<br />

11:20 633. Designing ligands to enforce<br />

multielectron excited state chemistry.<br />

D. G. Nocera<br />

12:00 634. On the use of various thiolate ligands<br />

to replicate the chemistry of metalcysteine<br />

centers in nature. M. Millar<br />

Section E<br />

Boston Convention & Exhibition Center<br />

Room 257A<br />

Lanthanide and Actinide Chemistry<br />

B. Donovan-Merkert, A. De Bettencourt<br />

Dias, Organizers<br />

S. Bart, Presiding<br />

9:00 635. Interaction between CMPO and<br />

HDEHP in combined TRUEX-TALSPEAK<br />

extraction process. P. Tkac,<br />

G. F. Vandegrift, G. Lumetta, A. Gelis<br />

9:20 636. Placement of lanthanide and actinide<br />

elements in the Periodic Table.<br />

G. Katz<br />

9:40 637. Metal-loaded liquid scintillator for<br />

neutrino experiment. S. Hans,M.Yeh,<br />

R. Hahn, L. Hu<br />

10:00 638. Synthesis and reactivity of uranium<br />

compounds containing redox-active<br />

�-diimine ligands. S. J. Kraft,<br />

P. E. Fanwick, S. C. Bart<br />

10:20 639. Encapsulation of the uranyl dication.<br />

O. B. Berryman, S. Beer, D. Ajami,<br />

J. Rebek Jr.<br />

10:40 Intermission<br />

10:50 640. Organometallic chemistry of lowvalent<br />

uranium complexes with hydrotris(pyrazolyl)borate<br />

ligands. S. C. Bart,<br />

E. M. Matson, P. E. Fanwick<br />

11:10 641. Transformation and curvature in<br />

uranyl diphosphonate system: Synthesis<br />

and structural characterization from single<br />

X-ray crystallography. P. O. Adelani,<br />

T. E. Albrecht-Schmitt<br />

11:30 642. Controllable optical properties of<br />

luminescent core-shell rare-earth ion<br />

doped nanoparticles. J. Dorman,<br />

J. P. Chang<br />

11:50 643. Novel lanthanide complexes as<br />

potential photodynamic therapeutic<br />

agents. S. Gangula, A. Blinder, P. K. Fu<br />

12:10 644. Strong ytterbium (III)-induced<br />

near-infrared emission by a BODIPYmodified<br />

bidentate ligand. H. He,<br />

Y. Zhong, A. Sykes<br />

A Half-Century at the Crossroads of<br />

Chemistry: Symposium in Honor of Royce<br />

Murrays 50 Years at Carolina<br />

Analytical Science Sponsored by ANYL,<br />

Cosponsored by INOR<br />

WEDNESDAY AFTERNOON<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Room 258A<br />

Organometallic Chemistry<br />

Synthesis and Characterization<br />

N. Radu, Organizer<br />

T. Betley, Presiding<br />

1:30 645. Photochemical reaction of 1-ferrocenyl-4-phenyl-1,3-butadiyne<br />

and<br />

Fe(CO) 5 in presence of CS 2 and S 8-powder.<br />

R. S. Ji, P. Mathur<br />

1:50 646. Metal complexes containing redox<br />

noninnocent aryldithiolate N-heterocyclic<br />

carbene ligands. B. Pan,C.M.Thomas<br />

2:10 647. Lithium dimethylcuprate and thiocarbonyl<br />

compounds: Observation, characterization<br />

and reactions of pi complexes.<br />

A. A. Thomas, Y. Moazami,<br />

J. D. Richter, S. H. Bertz, M. D. Murphy,<br />

C. A. Ogle<br />

2:30 648. Low energy solar neutrino spectrometer<br />

(LES). L. Hu, S. Rountree,<br />

R. Raghavan, S. Hans, M. Yeh,<br />

R. L. Hahn<br />

2:50 649. Deprotonation of N-alkylimidazole<br />

ligands: New reactivity patterns.<br />

J. Perez, L. Riera, M. A. Huertos<br />

3:10 650. Bimetallic carbon-halogen bond<br />

oxidative addition at Co(0). D. Zhu,<br />

P. H. Budzelaar<br />

3:30 Intermission<br />

3:35 651. Increasing the sensitivity of NMR<br />

spectroscopy: Iridium catalysts for polarisation<br />

transfer from para-hydrogen.<br />

M. J. Cowley, S. B. Duckett, G. Green<br />

3:55 652. Photochromic cyclopentadiene<br />

manganese tricarbonyl derivatives: Participation<br />

of imine group during linkage<br />

isomerization. T. J. Burkey, K. L. Mosley,<br />

C. E. Webster, K. R. Ruddick, P. P. Lubet,<br />

J. O. Johnson, E. J. Heilweil<br />

4:15 653. Role of Lewis acids in the reductive<br />

coupling of CO in Re and Mn cations:<br />

Intermolecular metal-free cleavage of dihydrogen<br />

and intramolecular facilitation<br />

of C-C bond formation. A. J. Miller,<br />

J. A. Labinger, J. E. Bercaw<br />

4:35 654. Catalytic, iron-mediated C-H<br />

bond functionalization chemistry.<br />

T. Betley, E. Hennessy, E. King,<br />

G. Edouard<br />

Section B<br />

Boston Convention & Exhibition Center<br />

Room 258C<br />

Organometallic Chemistry Catalysis<br />

N. Radu, Organizer<br />

A. Sadow, R. Waterman, Presiding<br />

1:30 655. Novel Chromium-based catalyst<br />

system for the highly selective trimerization<br />

of ethylene to 1-hexene. S. Peitz,<br />

N. Peulecke, B. R. Aluri, B. H. Müller,<br />

U. Rosenthal,A.Wöhl, W. Müller,<br />

M. H. Al-Hazmi, F. M. Mousa<br />

1:50 656. Synthesis, reactivity and mechanistic<br />

studies of Molybdenum pyrrolide<br />

alkylidene species supported by chiral<br />

bulky alkoxides. S. C. Marinescu,<br />

R. R. Schrock, P. Müller, J. H. Simpson,<br />

A. H. Hoveyda<br />

2:10 657. Mechanistic studies of ring-opening<br />

metathesis polymerization with molybdenum<br />

monoaryloxide monopyrrolide<br />

catalysts. L. Gerber, R. R. Schrock<br />

2:30 658. New catalysts for C-N bond formation<br />

involving hydroamination and related<br />

mechanistic investigations.<br />

A. D. Sadow<br />

2:50 659. Scope and mechanism of cis- and<br />

syndio-selective ring opening metathesis<br />

polymerization with molybdenum imido<br />

alkylidene complexes. M. M. Flook,<br />

R. R. Schrock<br />

3:10 660. Catalytic C–H bond amination and<br />

aziridination using organoazides from a<br />

ferrous dipyrromethene platform.<br />

E. T. Hennessy, T. Betley<br />

3:30 661. SiH bond activation reactions involving<br />

a coordinatively saturated zinc(II)<br />

center. D. Mukherjee, A. Ellern,<br />

A. D. Sadow<br />

3:50 662. Zirconium-mediated and -catalyzed<br />

P–C bond-forming reactions.<br />

A. J. Roering, S. E. Leshinski,<br />

R. Waterman<br />

4:10 663. Advances in phosphine dehydrocoupling<br />

and applications. M. Ghebreab,<br />

R. Waterman<br />

4:30 664. Indenyl Co(I) complexes: Synthesis,<br />

structure, and reactivity.<br />

F. Hung-Low, C. A. Bradley<br />

4:50 665. Synthesis and reactivity of iron<br />

pincer complexes. P. Bhattacharya,<br />

J. A. Krause, H. Guan<br />

5:10 666. Unusual activation of silanes resulting<br />

from � 3 -coordination to<br />

[PhBP3]RuH. M. C. Lipke, T. Tilley<br />

Section C<br />

Boston Convention & Exhibition Center<br />

Room 258B<br />

General Inorganic Chemistry<br />

B. Donovan-Merkert, Organizer<br />

C. Murillo, Presiding<br />

1:30 667. Matrix photochemistry of<br />

PdL 2(N 3)X derivatives. W. A. Thornley,<br />

T. E. Bitterwolf<br />

1:50 668. High valent transition metals featuring<br />

siloxide ligands. M. P. Marshak,<br />

D. G. Nocera<br />

2:10 669. Combined ligand �/metal � and ligand<br />

p�/metal-d� interactions indicated<br />

by magnetic and structural data.<br />

C. A. Murillo, G. M. Chiarella,<br />

D. Villagran, X. Wang<br />

2:30 670. Dioxygen activation by low valent<br />

chromium compounds. F. Dai,<br />

L. MacAdams, G. P. Yap, K. Theopold<br />

2:50 671. Synthesis and crystal structure of<br />

(benzo[1,2-c:3,4-c�:5,6-c�]trithiophene)2(7,7,8,8-tetracyano-p-quinodimethane)<br />

a possible 1D thermoelectric<br />

material. J. E. Schmidt, D. S. Dudis,<br />

A. V. Fratini<br />

3:10 672. Incorporation of main group elements<br />

into phosphorus-rich compounds<br />

via M[P 3Nb(ODipp) 3] platforms. A. Velian,<br />

C. C. Cummins<br />

3:30 673. Enhanced oxidative desulfurization<br />

of fuels using a film shear reactor.<br />

B. R. Fox, J. L. Male, D. R. Tyler<br />

3:50 674. Dimetal nitride chemistry and new<br />

insight into dirhodium catalyzed aminations.<br />

A. K. Long, J. F. Berry<br />

4:10 675. Luminescent rhenium(I) complexes<br />

incorporating a thiophene-functionalized<br />

bis(pyrazolyl) pyridine ligand.<br />

L. A. Lytwak, B. J. Holliday<br />

4:30 676. Comparing metal assisted thiolate<br />

disulfide exchange reactions (M�Au, Zn).<br />

G. S. Garusinghe,M.R.Bruce,<br />

A. E. Bruce<br />

4:50 677. Stopped flow ultra rapid IR studies<br />

of ClNO with metal complexes.<br />

M. L. Reback, T. E. Bitterwolf,<br />

P. R. Griffiths<br />

Photographing or recording<br />

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activities other than your own<br />

are prohibited at all official<br />

ACS events without written<br />

consent from ACS.

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