TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
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INOR <strong>TECHNICAL</strong> <strong>PROGRAM</strong><br />
9:30 613. Lanthanide-containing conducting<br />
metallopolymers for near-infrared lightemitting<br />
materials. X. Chen,Y.Yin,<br />
X. Yang, B. J. Holliday<br />
9:50 614. Nanostructured SiOC low dielectric<br />
film derived from inorganic polymer.<br />
Y. Kim, J. Kim, Y. Lee, W. Kwon, S. Kim,<br />
D. Choi<br />
10:10 Intermission<br />
10:30 615. Nanoscopic patterned materials<br />
with tunable dimensions via atomic layer<br />
deposition on block copolymers.<br />
Q. Peng, Y. Tseng, S. B. Darling,<br />
J. W. Elam<br />
10:50 616. Non-hydrolytic synthesis, characterization,<br />
and electronic structure of<br />
colloidal early transition metal oxide<br />
nanocrystals. S. W. Depner, K. R. Kort,<br />
C. Jaye, H. Zhang, D. A. Fischer,<br />
S. Banerjee<br />
11:10 617. Synthesis and characterization of<br />
amorphous pyrophosphates and their<br />
use in brushite bone cements. C. Slater,<br />
A. J. Wright, L. M. Grover, V. Burnell,<br />
D. Laurencin, J. A. Hriljac, M. E. Smith<br />
11:30 618. Hybrid polyoxometalates, from<br />
molecular catalysts to functional materials.<br />
M. Carraro, G. Modugno, A. Sartorel,<br />
M. Bonchio, G. Scorrano<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Growth and Design<br />
S. Wong, Organizer<br />
I. Hakem, K. Balkus, Presiding<br />
8:30 619. Large scale ZnO nanodendrites<br />
converted by an in-situ carbothermal<br />
method and their application as gas sensors.<br />
P. Shimpi,P.Gao<br />
8:50 620. Thermal behavior study of<br />
�-Fe 2 O 3 and �-FeOOH nanocapsules<br />
structures. Y. Kim, R. Yu, J. Pee, K. Kim<br />
9:10 621. Tuning the metal-insulator phase<br />
transition in VO 2 nanostructures.<br />
L. Whittaker, T. Wu, C. Jaye, D. Fischer,<br />
S. Ganapathy, S. Banerjee<br />
9:30 622. Nanostructured vanadium oxides<br />
by chemical vapor transport and hydrothermal<br />
methods. J. M. Velazquez,<br />
C. Jaye, D. A. Fischer, S. Banerjee<br />
9:50 623. Vanadium oxide nanotube films<br />
prepared via pulsed laser ablation.<br />
K. Balkus, S. D. Perera, J. Bonso,<br />
J. Ferraris<br />
10:20 Intermission<br />
10:40 624. Experimental and theoretical<br />
evaluation of the distribution of functionality<br />
of surface modified nanoparticles.<br />
I. F. Hakem, J. Walker, A. Leech,<br />
J. Johnson, S. Donahue,<br />
M. R. Bockstaller<br />
11:10 625. Nanoclusters of dicyanocuprate<br />
(I) ions doped in different alkali halides.<br />
X. Li, D. A. Welch, F. Baril-Robert,<br />
H. H. Patterson<br />
11:30 626. Efficient assemby of photochromic<br />
spiropyran molecules on zeolite<br />
nanostructures. K. Dubois, E. Garcia,<br />
S. Bent, G. Li<br />
11:50 627. Controlling ice formation on<br />
nanostructured superhydrophobic surfaces.<br />
L. Mishchenko,B.Hatton,<br />
J. Taylor, V. Bahadur, T. Krupenkin,<br />
J. Aizenberg<br />
12:10 628. Large-scale soft colloidal template<br />
synthesis of 1.4 nm-thick CdSe<br />
nanosheets. J. Son, T. Hyeon<br />
70–TECH<br />
‡ Cooperative Cosponsorship<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Ligand Design and Metal Behavior<br />
L. Doerrer, S. Koch, Organizers<br />
M. Millar, Organizer, Presiding<br />
9:00 629. Coordination chemistry of bidentate<br />
and tridentate N-aryl-substituted imino-N-heterocyclic<br />
carbene ligands.<br />
G. G. Lavoie, S. Dastgir, A. C. Badaj,<br />
T. G. Larocque<br />
9:30 630. Ligands which provide hydrogen<br />
bonds near and far from the metal center.<br />
E. T. Papish, M. Kumar, I. Nieto,<br />
S. W. Shim, S. N. Oseback, N. A. Dixon,<br />
M. Zeller<br />
10:00 631. Ligands designed for mimicking<br />
the diiron centers of bacterial monooxygenases.<br />
L. Do, Y. Li, S. J. Lippard<br />
10:40 Intermission<br />
10:50 632. Fluorinated ligands vs. fluorine<br />
as a ligand. L. H. Doerrer<br />
11:20 633. Designing ligands to enforce<br />
multielectron excited state chemistry.<br />
D. G. Nocera<br />
12:00 634. On the use of various thiolate ligands<br />
to replicate the chemistry of metalcysteine<br />
centers in nature. M. Millar<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Lanthanide and Actinide Chemistry<br />
B. Donovan-Merkert, A. De Bettencourt<br />
Dias, Organizers<br />
S. Bart, Presiding<br />
9:00 635. Interaction between CMPO and<br />
HDEHP in combined TRUEX-TALSPEAK<br />
extraction process. P. Tkac,<br />
G. F. Vandegrift, G. Lumetta, A. Gelis<br />
9:20 636. Placement of lanthanide and actinide<br />
elements in the Periodic Table.<br />
G. Katz<br />
9:40 637. Metal-loaded liquid scintillator for<br />
neutrino experiment. S. Hans,M.Yeh,<br />
R. Hahn, L. Hu<br />
10:00 638. Synthesis and reactivity of uranium<br />
compounds containing redox-active<br />
�-diimine ligands. S. J. Kraft,<br />
P. E. Fanwick, S. C. Bart<br />
10:20 639. Encapsulation of the uranyl dication.<br />
O. B. Berryman, S. Beer, D. Ajami,<br />
J. Rebek Jr.<br />
10:40 Intermission<br />
10:50 640. Organometallic chemistry of lowvalent<br />
uranium complexes with hydrotris(pyrazolyl)borate<br />
ligands. S. C. Bart,<br />
E. M. Matson, P. E. Fanwick<br />
11:10 641. Transformation and curvature in<br />
uranyl diphosphonate system: Synthesis<br />
and structural characterization from single<br />
X-ray crystallography. P. O. Adelani,<br />
T. E. Albrecht-Schmitt<br />
11:30 642. Controllable optical properties of<br />
luminescent core-shell rare-earth ion<br />
doped nanoparticles. J. Dorman,<br />
J. P. Chang<br />
11:50 643. Novel lanthanide complexes as<br />
potential photodynamic therapeutic<br />
agents. S. Gangula, A. Blinder, P. K. Fu<br />
12:10 644. Strong ytterbium (III)-induced<br />
near-infrared emission by a BODIPYmodified<br />
bidentate ligand. H. He,<br />
Y. Zhong, A. Sykes<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Analytical Science Sponsored by ANYL,<br />
Cosponsored by INOR<br />
WEDNESDAY AFTERNOON<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Organometallic Chemistry<br />
Synthesis and Characterization<br />
N. Radu, Organizer<br />
T. Betley, Presiding<br />
1:30 645. Photochemical reaction of 1-ferrocenyl-4-phenyl-1,3-butadiyne<br />
and<br />
Fe(CO) 5 in presence of CS 2 and S 8-powder.<br />
R. S. Ji, P. Mathur<br />
1:50 646. Metal complexes containing redox<br />
noninnocent aryldithiolate N-heterocyclic<br />
carbene ligands. B. Pan,C.M.Thomas<br />
2:10 647. Lithium dimethylcuprate and thiocarbonyl<br />
compounds: Observation, characterization<br />
and reactions of pi complexes.<br />
A. A. Thomas, Y. Moazami,<br />
J. D. Richter, S. H. Bertz, M. D. Murphy,<br />
C. A. Ogle<br />
2:30 648. Low energy solar neutrino spectrometer<br />
(LES). L. Hu, S. Rountree,<br />
R. Raghavan, S. Hans, M. Yeh,<br />
R. L. Hahn<br />
2:50 649. Deprotonation of N-alkylimidazole<br />
ligands: New reactivity patterns.<br />
J. Perez, L. Riera, M. A. Huertos<br />
3:10 650. Bimetallic carbon-halogen bond<br />
oxidative addition at Co(0). D. Zhu,<br />
P. H. Budzelaar<br />
3:30 Intermission<br />
3:35 651. Increasing the sensitivity of NMR<br />
spectroscopy: Iridium catalysts for polarisation<br />
transfer from para-hydrogen.<br />
M. J. Cowley, S. B. Duckett, G. Green<br />
3:55 652. Photochromic cyclopentadiene<br />
manganese tricarbonyl derivatives: Participation<br />
of imine group during linkage<br />
isomerization. T. J. Burkey, K. L. Mosley,<br />
C. E. Webster, K. R. Ruddick, P. P. Lubet,<br />
J. O. Johnson, E. J. Heilweil<br />
4:15 653. Role of Lewis acids in the reductive<br />
coupling of CO in Re and Mn cations:<br />
Intermolecular metal-free cleavage of dihydrogen<br />
and intramolecular facilitation<br />
of C-C bond formation. A. J. Miller,<br />
J. A. Labinger, J. E. Bercaw<br />
4:35 654. Catalytic, iron-mediated C-H<br />
bond functionalization chemistry.<br />
T. Betley, E. Hennessy, E. King,<br />
G. Edouard<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
Organometallic Chemistry Catalysis<br />
N. Radu, Organizer<br />
A. Sadow, R. Waterman, Presiding<br />
1:30 655. Novel Chromium-based catalyst<br />
system for the highly selective trimerization<br />
of ethylene to 1-hexene. S. Peitz,<br />
N. Peulecke, B. R. Aluri, B. H. Müller,<br />
U. Rosenthal,A.Wöhl, W. Müller,<br />
M. H. Al-Hazmi, F. M. Mousa<br />
1:50 656. Synthesis, reactivity and mechanistic<br />
studies of Molybdenum pyrrolide<br />
alkylidene species supported by chiral<br />
bulky alkoxides. S. C. Marinescu,<br />
R. R. Schrock, P. Müller, J. H. Simpson,<br />
A. H. Hoveyda<br />
2:10 657. Mechanistic studies of ring-opening<br />
metathesis polymerization with molybdenum<br />
monoaryloxide monopyrrolide<br />
catalysts. L. Gerber, R. R. Schrock<br />
2:30 658. New catalysts for C-N bond formation<br />
involving hydroamination and related<br />
mechanistic investigations.<br />
A. D. Sadow<br />
2:50 659. Scope and mechanism of cis- and<br />
syndio-selective ring opening metathesis<br />
polymerization with molybdenum imido<br />
alkylidene complexes. M. M. Flook,<br />
R. R. Schrock<br />
3:10 660. Catalytic C–H bond amination and<br />
aziridination using organoazides from a<br />
ferrous dipyrromethene platform.<br />
E. T. Hennessy, T. Betley<br />
3:30 661. SiH bond activation reactions involving<br />
a coordinatively saturated zinc(II)<br />
center. D. Mukherjee, A. Ellern,<br />
A. D. Sadow<br />
3:50 662. Zirconium-mediated and -catalyzed<br />
P–C bond-forming reactions.<br />
A. J. Roering, S. E. Leshinski,<br />
R. Waterman<br />
4:10 663. Advances in phosphine dehydrocoupling<br />
and applications. M. Ghebreab,<br />
R. Waterman<br />
4:30 664. Indenyl Co(I) complexes: Synthesis,<br />
structure, and reactivity.<br />
F. Hung-Low, C. A. Bradley<br />
4:50 665. Synthesis and reactivity of iron<br />
pincer complexes. P. Bhattacharya,<br />
J. A. Krause, H. Guan<br />
5:10 666. Unusual activation of silanes resulting<br />
from � 3 -coordination to<br />
[PhBP3]RuH. M. C. Lipke, T. Tilley<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, Organizer<br />
C. Murillo, Presiding<br />
1:30 667. Matrix photochemistry of<br />
PdL 2(N 3)X derivatives. W. A. Thornley,<br />
T. E. Bitterwolf<br />
1:50 668. High valent transition metals featuring<br />
siloxide ligands. M. P. Marshak,<br />
D. G. Nocera<br />
2:10 669. Combined ligand �/metal � and ligand<br />
p�/metal-d� interactions indicated<br />
by magnetic and structural data.<br />
C. A. Murillo, G. M. Chiarella,<br />
D. Villagran, X. Wang<br />
2:30 670. Dioxygen activation by low valent<br />
chromium compounds. F. Dai,<br />
L. MacAdams, G. P. Yap, K. Theopold<br />
2:50 671. Synthesis and crystal structure of<br />
(benzo[1,2-c:3,4-c�:5,6-c�]trithiophene)2(7,7,8,8-tetracyano-p-quinodimethane)<br />
a possible 1D thermoelectric<br />
material. J. E. Schmidt, D. S. Dudis,<br />
A. V. Fratini<br />
3:10 672. Incorporation of main group elements<br />
into phosphorus-rich compounds<br />
via M[P 3Nb(ODipp) 3] platforms. A. Velian,<br />
C. C. Cummins<br />
3:30 673. Enhanced oxidative desulfurization<br />
of fuels using a film shear reactor.<br />
B. R. Fox, J. L. Male, D. R. Tyler<br />
3:50 674. Dimetal nitride chemistry and new<br />
insight into dirhodium catalyzed aminations.<br />
A. K. Long, J. F. Berry<br />
4:10 675. Luminescent rhenium(I) complexes<br />
incorporating a thiophene-functionalized<br />
bis(pyrazolyl) pyridine ligand.<br />
L. A. Lytwak, B. J. Holliday<br />
4:30 676. Comparing metal assisted thiolate<br />
disulfide exchange reactions (M�Au, Zn).<br />
G. S. Garusinghe,M.R.Bruce,<br />
A. E. Bruce<br />
4:50 677. Stopped flow ultra rapid IR studies<br />
of ClNO with metal complexes.<br />
M. L. Reback, T. E. Bitterwolf,<br />
P. R. Griffiths<br />
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