TECHNICAL PROGRAM - American Chemical Society Publications

ORGN TECHNICAL PROGRAM
3:20 891. Control vs. chaos in the assembly
of folding and DNA binding molecules.
B. L. Iverson
3:40 892. Synthesis of shell cross-linked micelles
(SCMs) with Co-salen functionalized
core. Y. Liu,M.Weck
4:00 893. Light controlled guest binding in a
molecular cavitand. O. B. Berryman,
A. C. Sather, J. Rebek Jr.
4:20 894. Odd-even effects on charge transport
across n-alkanethiolate SAMs on
metal/SAM/oxide/EGaIn junction.
M. T. Mwangi, W. Reus, C. Nijhuis,
C. Kim, J. Barber, M. D. Schulz,
G. M. Whitesides
4:40 895. Multicomponent capsular assemblies
of calix[4]resorcinarene: From hexamers
to dimers. O. O. Ugono,
K. T. Holman
Section F
Boston Convention & Exhibition Center
Room 204B
Metal-Mediated Reactions and Syntheses
S. Sieburth, Organizer
A. Wenzel, Presiding
1:00 896. Development of new palladium
precatalysts and their application to
cross-coupling reactions. Y. Zhang,
S. L. Buchwald, T. Kinzel
1:20 897. Visible light photoredox catalysis:
Applications in synthetic methodology.
J. W. Tucker, J. M. Narayanam,
J. D. Nguyen, S. R. Corey
1:40 898. Metal-catalyzed carbonylative cyclization
of unactivated alkyl halides with
alkenes. E. J. Alexanian
2:00 899. Pd(II) mediated disubstitution of
alkenes by carbon and heteroatom nucleophiles.
B. S. Matsuura, A. Condie,
P. Fink, C. R. Stephenson
2:20 900. Electron-transfer photoredox catalysis:
Development of a phosphine-free
halogenation of alcohols. C. Dai,
J. M. Narayanam, C. R. Stephenson
2:40 901. Development of catalysts for Pdcatalyzed
C–N cross-coupling reactions.
B. P. Fors, S. L. Buchwald
3:00 902. Intermolecular Rh(II)-catalyzed reactions
of �-diazolactones and �-diazolactams:
Remarkable selectivity over tertiary
C-H bond migration. A. DeAngelis,
J. M. Fox
3:20 903. Nickel-catalyzed reductive coupling
of organohalides to electron-deficient
olefins forming 1,4-conjugate addition
products. R. Shrestha,D.J.Weix
3:40 904. Remarkable effect of sulfate additives
on the palladium-catalyzed cyanation
of aryl chlorides. M. Shevlin
4:00 905. Ylide chemistry via Co(III)Corroles:
Axial ligand effects of epoxidation and
N-H insertion reactions with diverse
diazo-compounds. C. Kim, P. X. Zhang,
C. Ludwin
4:20 906. Epoxidation of olefins using chiral
salen vanadium catalysts. J. A. Miranda,
E. J. Martin
Section G
Boston Convention & Exhibition Center
Room 207
Material, Devices and Switches
96–TECH
S. Sieburth, Organizer
S. Phillips, Presiding
1:00 907. Preparation of polymers conjugated
with �-extended quinone: Optical
and redox properties of the polymers.
E. Yoshikawa, T. M. Swager
‡ Cooperative Cosponsorship
1:20 908. Redox-driven structural folding
and unfolding: Electronic communication
between TTF units anchored onto a C 2symmtric
aryleneethynylene scaffold.
J. Jung, W. Liu, D. Lee
1:40 909. Conjugated polymers that respond
to oxidation with increased emission.
E. L. Dane, T. M. Swager
2:00 910. Role of metal ions and counterions
in the switching behavior of spiropyrans.
S. Giordani, M. Natali, L. Soldi,
C. Aakeroy, J. Desper
2:20 911. Detection of ethylene gas with a
conjugated polymer/copper composite.
B. Esser, T. M. Swager
2:40 912. Metal-induced switching of a hydrazone-based
rotary switch.
I. Aprahamain,X.Su
3:00 913. Polymer electrolyte based room
temperature oxygen microsensors for
aerospace applications. J. C. Xu,
G. W. Hunter, C. Liu
3:20 914. Electronic restoration of damaged
lithium ion batteries. S. A. Odom,
Z. Zhang, W. Weng, S. Kang,
N. R. Sottos, K. Amine, J. S. Moore
3:40 915. Microvascular composite materials
using sacrificial fibers.
A. P. Esser-Kahn, H. Dong, P. Pthakre,
B. Kozola, M. Cale, J. Patrick, S. White,
N. Sottos, J. S. Moore
4:00 916. Multistate [3]catenanes utilizing
highly stable TTF radical dimers.
A. Coskun, J. M. Spruell, D. C. Friedman,
G. Barin, J. Stoddart
4:20 917. Functional materials derived from
renewable sources. R. A. Smaldone,
J. J. Gassensmith, R. S. Forgan,
O. M. Yaghi, J. F. Stoddart
4:40 918. Design and synthesis of rigid 3D
hydrophilic structures for improved properties
of conjugated polymers in water
and postpolymerization strategies for
sensing of proteins and influenza.
B. VanVeller, T. M. Swager
5:00 919. Tuning optical and electronic
properties of arene-based organic semiconductors
via perfluoroalkylation.
H. Sun, M. Billion
Section A
Boston Convention & Exhibition Center
Ballroom East
Technical Achievements in Organic
Chemistry Award Symposium
J. Cohen, C. Welch, Organizers, Presiding
2:00 Introductory Remarks
2:05 920. Characterization of drug-eluting
coronary stents by vibrational spectroscopy
and multivariate analysis.
M. F. Chisholm
2:30 921. Isoindolinones as glucokinase activators.
R. F. Kester, S. J. Berthel,
K. R. Guertin, J. Tengi, L. Orzechowski,
L. Qi, J. Grimsby
2:55 922. Development of an asymmetric alkylation
towards an 11�-HSD1 inhibitor.
C. F. Bernard, G. A. Moniz, M. J. Frizzle,
L. M. Brown, C. D. Papageorgiou,
J. S. Tedrow, E. A. Bercot, S. Caille,
S. Cui, S. Wang, M. J. Martinelli,
M. M. Faul, R. D. Larsen, K. B. Hansen
3:20 923. Automated Chemistry: The development
and use of low-cost automated
chemical workstations for performing organic
synthesis, sample preparation, material
testing, and improving productivity
and safety of laboratory operations.
R. Shumate
3:45 924. Synthetic highlights: Examples
from early lead to clinical candidates in
oncology and neuroscience therapeutic
areas. N. Patel
4:10 925. Optimization of oligonucleotide
synthesis at Merck. E. Vazquez
4:35 926. Modifications on the nucleotide
sugar: Manipulation of GPCR activity.
S. R. Shaver
WEDNESDAY EVENING
Section A
Boston Convention & Exhibition Center
Ballroom
Chemistry for Preventing & Combating
Disease, New Reactions & Methodology
and Total Synthesis of Complex Molecules
A. Abdel-Magid, Organizer
7:00–10:00
927. Synthesis of epi-galiellalactone analogs.
R. Gidlof, M. Johansson, O. Sterner
928. Toward the total synthesis of the transtaganolides/basiliolides.
R. Larsson,
O. Sterner, M. Johansson
929. Gentamicin component separation.
J. Grote, R. Himmelsbach, D. Johnson
930. Syntheses of dioxa-bicyclo[3.2.1]
octane-2,3,4-triol derivative SGLT2 inhibitors.
C. Préville, V. Mascitti
931. Enamide-ene metathesis for constructing
chiral 2-cyclopropylheterocycles: Indole,
quinoline, benzofuran and
chromene. T. Kobayashi,M.Arisawa,
S. Shuto
932. Tuneable nanotools for bioapplications:
Soft organic nanodots as an eco-friendly
alternative to quantum dots. C. Rouxel,
O. Mongin, J. Vabre, Y. Mir, Y. Wei,
A. Pla-Quintana, J. Majoral, A. Caminade,
M. Blanchard-Desce
933. Discovery of antibacterial virulence inhibitors
targeted at Type III protein secretion.
L. K. Tsou, J. Yount, P. Dossa,
H. C. Hang
934. Synthesis of estrogen receptor (ER) antagonist
derivatives for breast cancer.
K. Dao, A. Kozhushuyan, J. A. Hendricks,
H. Pham, R. N. Hanson
935. Towards B vitamin targeted light-activated
cancer drug conjugates.
K. Dhananjay, R. J. Fradette,F.G.West
936. Development of SHIP activators: Potentially
selective cancer therapy.
L. G. Meimetis, M. Nodwell, C. Wang,
L. Yang, A. L. Mui, C. Ong, G. Krystal,
R. J. Andersen
937. Solution- and solid-phase synthesis of
potential anticancer HDAC inhibitors.
T. R. Blum, H. K. Shah, X. Zang,
A. R. Korn, D. M. Wholly, J. S. Miller
938. Controlling biofouling by a kosmotrope
approach for surfaces and materials.
D. Bandyopadhyay, P. Sejwal,
D. Prashar, Y. Y. Luk
939. Singlet oxygen delivery via a fiber opticbound
photosensitizer. M. Minnis,
A. Greer
940. Organic photonic nanoparticles for bioconjugation.
C. Cordovilla,T.M.Swager
941. Targeting Gp120’s binding sites.
C. I. Dogo-Isonagie,S.N.Lam,
C. A. Bewley
942. Encapsulation of neutral and charged
molecules into catanionic surfactant vesicles
for drug delivery applications.
L. H. Rader, J. Park, D. S. English,
F. Khachik, P. DeShong
943. MSN as controlled release devices and
diagnostic tools. P. DeShong,
M. T. Hurley, S. Galanie, D. S. English,
M. Zachariah, C. Wu, Z. Wang, E. Liu,
P. DeMuth
944. Investigation of structure and function
of thin films of nitric oxide synthase and
polyethylenimine formed using the layerby-layer
deposition method.
M. N. Gunasekera, M. Bayachou
945. Targeting IspC in non-mammalian isoprenoid
biosynthesis. D. J. Meyers,
C. L. Freel Meyers
946. Chemogenomic analysis of adipogenesis
using functional proteomics. W. Li,
J. Pawlak, E. Dominguez, E. Saez,
B. Cravatt
947. Inhibition of the serine protease chymase
by silanediols. Y. Bo,C.Cao,
S. M. Sieburth
948. Short, asymmetric synthesis of
silanediol protease inhibitors.
H. Q. Duong, S. Singh, Y. Bo,
S. M. Sieburth
949. Regioselective, iron-catalyzed allylic
sulfonation of allylic carbonates.
M. Jegelka, B. J. Plietker
950. New N-heterocyclic carbene-derived alkylidene
imidazolines. C. E. Knappke,
A. Jacobi von Wangelin, A. J. Arduengo,
III
951. Synthesis of non-racemic enaminones
via 6-exo-dig ketene cyclization. H. Seki,
G. I. Georg
952. Synthesis of vinyl sulfones with aldehyde
and phenylsulfonylacetic acid using
benzyltrimethyl ammonium hydroxide as
base. R. Rengasamy,D.C.Forbes
953. Stereoselective synthesis of the tetracyclic
core of the codeine alkaloid using (-)shikimic
acid as the chiral source.
T. N. Dinh, A. Chen, C. L. Chai
954. Progress toward the synthesis of decahydroquinolines
(DHQs) from 2-alkenyltethered
oxazolium salts. S. A. Habay
955. Towards the total synthesis of leustroducsin
B. P. B. Cranwell,
K. L. Bridgwood, M. R. Huttl,
D. A. Salinger, S. Wittrock, S. V. Ley
956. Flow chemistry for natural product synthesis:
Towards the syntheses of spiragiens
A and B. C. F. Carter,H.Lange,
S. Newton, S. V. Ley
957. Total synthesis of novel analogs of dictyostatin.
E. G. Williams, I. Paterson
958. Electrophilic properties and NMR studies
of triphenylphosphine–trifluoromethanesulfonic
anhydride: An efficient dehydrating
reagent system for the conversion
of aldoximes into nitriles. Z. Moussa
959. Improved preparation of (S)-Z/E-N-(1-
(tert-butyldimethylsilyloxy)propan-2ylidene)-2-
methylpropane-2-sulfinamide
and analogs. X. Shi, H. Chang,
D. G. Walker, R. Chen, W. F. Kiesman
960. Spectroscopic analysis of the (HQ) 3C 60
compound. S. Ahn, J. Yoon, H. Lee,
B. Nam, B. Kim, G. Lee, D. Moon, H. Shin
961. Mild and highly chemoselective deprotection
of methoxymethyl (MOM) ethers
in combination with TMSOTf (TESOTf)–
2,2�-bipyridyl. T. Maegawa, O. Kubo,
K. Senami, Y. Minamitsuji, H. Fujioka
962. Efforts toward an enantiospecific synthesis
of the natural product pleurotin.
D. A. Siler, D. C. Ebner, E. J. Sorensen
963. Soft Lewis acid-catalyzed cycloisomerization
reactions. Z. Wang, Z. Wang
964. Synthesis of 3,5-di-tert-butyl-2-iodocyclopenta-2,4-dienone
via novel ring-contraction
iodination reaction and its application
for syntheses of various
ethynylene functionized cyclopentadienone
rings. X. Chen, T. C. Sandreczki,
X. Bai, J. R. Dias, C. Barnes
965. Synthetic applications of N–O tethered
intramolecular 1,7-C–H insertion reactions.
J. Wang,H.O.Sintim
966. Asymmetric total synthesis of (-)-doliculide:
An exceptionally potent cytotoxic
compound for HeLa cells. A. V. Madduri,
A. J. Minnaard
967. One-step synthesis of nanofibers of aniline
oligomers using benzoquinone oxidant.
S. P. Surwade, S. Agnihotra,
N. Manohar, S. K. Manohar
968. Polystyrene supported aluminum chloride
as an efficient and reusable catalyst
for one-pot preparation of �-aminophosphonates
via three component coupling
reaction of aldehydes, amines, and diethyl
phosphite. B. Tamami, K. Parang,
A. N. Shirazi
969. Esterification of aldehydes and alcohols
with pyridinium hydrobromide perbromide
in water. S. Sayama
970. Intramolecular photocyclization: Cyclopropanation
vs. epoxidation.
M. R. Buchner, K. Ruhland
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