TECHNICAL PROGRAM - American Chemical Society Publications

545. Developing novel nanoparticulated imaging
system using luminescence enhancement
of Eu(III) and Tb(III) by singlestrand
DNA. D. A. Corcoran,
D. L. Harms, P. K. Fu
546. MRI contrast enhancement using
Gd(III)-nanodiamond conjugates.
L. M. Manus, D. J. Mastarone, X. Zhang,
E. A. Waters, K. W. MacRenaris,
G. Parigi, C. Luchinat, D. Ho, T. J. Meade
547. Development of triphenoxymethane
based ligands for the liquid-liquid extraction
of lanthanides and actinides.
G. L. Guillet, P. Hillesheim, M. J. Scott
548. Computational and synthetic development
of ligands for the selective binding
of lanthanides and actinides. I. D. Hyatt,
C. A. Rienas, M. J. Scott
549. Synthesis and characterization of Gd 3�
conjugated-hyperbranched polyglycerols
for use as MR vascular imaging agents.
C. A. Barta, N. A. Rossi, S. Horte,
B. F. Lai, J. N. Kizhakkedathu
Section H
Boston Convention & Exhibition Center
Hall C
Inorganic Catalysts
B. Donovan-Merkert, Organizer
7:00–9:00
550. Synthesis and reactivity of Ir III CCC-
NHC pincer complexes. K. M. Schultz,
W. Kaminsky, K. I. Goldberg, D. Heinekey
551. Methane to methanol: A DFT study of
the oxy-functionalization of metal alkyls.
T. R. Cundari, B. M. Prince, T. M. Figg
552. Production of poly(lactide) using aluminium
and zinc complexes.
O. Karroonnirun, D. J. Darensbourg
553. N-doped SiO 2/TiO 2 core/shell nanoparticles
as highly efficient visible light photocatalyst:
Application in decomposition
of water pollutant. C. Kim, J. Jang
554. Preparation and characterization of
supported binuclear copper complexes
on Cab-O-Sil and their catalytic activity.
S. A. Ranaweera, W. P. Henry,
M. D. Rowe, K. B. Walters, M. G. White,
J. M. Rodriguez
555. Asymmetric reaction rates in terpolymers
produced from CO 2 and epoxides.
R. R. Poland, D. J. Darensbourg
556. Novel metal nitride catalysts supported
on magnetic silica microspheres for click
reactions. S. Han, B. Lee, M. Yi, S. Chu,
J. Lee, H. Kwon, K. Lee, D. Kang, D. Chi,
N. Hur
557. Carbon dioxide reduction with biomimetic
molybdenum catalysts. A. Aron,
J. Seo, E. Kim
Section I
Boston Convention & Exhibition Center
Hall C
Organometallic Chemistry
Synthesis and Characterization
N. Radu, Organizer
7:00–9:00
558. Organometallic furan derivatives for solar
energy capture. N. C. Tice,
A. Z. Preston, C. A. Snyder
559. Preparation and structural characterization
of bimetallic Iron�Nickel carbido
cluster complexes. S. Saha,L.Zhu,
B. Captain
560. Synthesis and structure of gold and
platinum menthyl complexes.
A. A. Zuzek, S. C. Reynolds, J. A. Golen,
A. L. Rheingold, D. S. Glueck
561. Synthesis, structure, and spectroscopic
properties of 2,3-bis(diphenylphosphino-
)quinoxaline (dppQx) Cu(I) complexes.
M. F. Cain, S. C. Reynolds, D. S. Glueck,
J. A. Golen, A. L. Rheingold
562. Formation of group 4 metallacyclopentanes
from metallacyclopropenes: Investigation
of the reactions with ethylene by
in situ NMR and UV/vis spectroscopy.
T. Beweries, C. Fischer, S. Peitz,
V. V. Burlakov, P. Arndt, W. Baumann,
A. Spannenberg, D. Heller, U. Rosenthal
563. �-Coordinated chromium and manganese
DBCOT complexes. N. Bandara,
D. J. Beard, S. R. Gwaltney, W. P. Henry
564. Oxidative addition and cleavage of sp 3
C-F Bond by pincer iridium complexes.
J. Choi,A.S.Goldman
565. New PNP pincer ligand motifs as mechanistic
probes into metal-ligand cooperation
catalysis at ruthenium. E. Khaskin,
M. A. Iron, D. Milstein
566. Mononuclear guanidinato and amidinato
complexes of iridium(I) and rhodium(I).
M. R. Kelley,J.Rohde
567. Synthesis of new photochromic organometallics
based on a linkage isomerization.
K. L. Mosley, K. R. Ruddick,
J. O. Johnson, C. E. Webster,
T. J. Burkey
568. Investigation into the effects of halide
substitution on the structures and N-CH 3
oxidative addition reaction occurring in
[PN(Me)P]RhX complexes.
A. L. Fernandez, B. M. Foxman,
O. V. Ozerov
569. Reaction of O 2 with alkyl amide imide
Ta(�NSiMe 3)[N(SiMe 3) 2](CH 2Bu t ) 2.
mechanistic study of the formation of
Ta(�NSiMe 3)[N(SiMe 3) 2](OCH 2Bu t ) 2.
S. Chen, S. C. Hunter, X. Wang, Z. Xue
570. Direct synthesis of (eta6-aniline) manganese
tricarbonyl cation. W. Dai,S.Kim,
P. D. Robert, D. A. Sweigart
571. Synthesis, structures and reactivity of
some azaferrocene boron-Lewis Acid donor-acceptor
complexes. T. J. Brunker,
B. T. Roembke, A. L. Rheingold, J. Golen
572. Investigation of new imido ligands and
their application to olefin metathesis.
A. G. Lichtscheidl, R. R. Schrock
573. Synthesis and characterization of ruthenium-glycals
containing BINAP and 1,1�-
Bis(diphenylphosphino)ferrocene.
V. D. Reddy
574. Synthesis and characterization of oxygenous
ligands and their relevance to water
oxydation. R. Huacuja, O. V. Ozerov,
D. Graham, B. M. Foxman, C. Chen
575. Withdrawn
WEDNESDAY MORNING
Section A
Boston Convention & Exhibition Center
Room 258A
Organometallic Chemistry
Catalysis
N. Radu, Organizer
A. Wenzel, J. Soper, Presiding
8:30 576. Ruthenium metallacycles derived
from 14- and 16-electron complexes:
New methods for metallacycle preparation,
and the insights gained from the
study of these metathesis intermediates.
A. G. Wenzel, R. H. Grubbs, G. Blake
8:50 577. Influence of electronically and
sterically tunable olefin-ligands on the
properties of group 10 d 10 metal-complexes
and correlation with reactivity.
M. R. Buchner, K. Ruhland
9:10 578. Platinum and nickel metal complexes
containing bulky tin ligands.
V. Yempally, L. Zhu, D. Isrow, B. Captain
9:30 579. Palladium alkyl complexes with
chelating N-heterocyclic carbene-sulfonate
ligand. X. Zhou,R.F.Jordan
9:50 580. Enhanced phosphorescence in
cyclometalated Pt(II) complexes facilitated
by triarylboron. Z. M. Hudson,
C. Sun, H. Amarne, S. Wang
10:10 Intermission
10:15 581. Gilded organometallics: Recent
developments. T. G. Gray, D. V. Partyka,
L. Gao, T. J. Robilotto, N. Deligonul
10:35 582. Novel bis(2-pyridyl)borato platinum(II)
complexes for alkane C-H bond
functionalization. S. Pal, A. N. Vedernikov
10:55 583. Luminescent Au(I)/Cu(I) alkynyl
clusters of ethynyl steroids and related aliphatic
acetylides. G. Manbeck,
W. Brennessel, R. Stockland,
R. Eisenberg
11:15 584. Redox-active ligand-mediated
coupling reactions at square planar manganese,
iron and cobalt centers.
J. D. Soper
11:35 585. Paramagnetic multinuclear complexes
bridged by alkynyl-type ligands.
M. P. Shores, W. A. Hoffert, B. S. Newell,
A. K. Rappe
11:55 586. C-H and C-CN bond activation
of acetonitrile with [Cp*Rh(PMe 3)]: An experimental
and theoretical investigation.
M. E. Evans, T. Li, W. D. Jones
Section B
Boston Convention & Exhibition Center
Room 258C
Organometallic Chemistry
Synthesis and Characterization
N. Radu, Organizer
L. Mirica, Presiding
8:30 587. Oxidative addition and reductive
elimination of C-H bonds of aryl halides
by a pincer-ligated iridium complex.
D. A. Laviska,D.Y.Wang,
K. Krogh-Jespersen, A. S. Goldman
8:50 588. Complexes of pincer ligands with
a central silylene donor. O. V. Ozerov,
W. Gu, J. R. Walensky
9:10 589. Activation of NH bonds by ruthenium
via metal-ligand cooperation.
E. Khaskin, M. A. Iron, L. J. Shimon,
D. Milstein
9:30 590. Four-coordinate Ru(II) amdio
PNP-pincer complexes. B. Askevold,
J. Meiners, M. Khusniyarov,
E. Herdtweck, S. Schneider
9:50 591. Studies of oxygenous ligands and
their relevance to transiton metal-catalyzed
water oxidation. R. Huacuja,
O. Ozerov, D. Graham, B. Foxman,
C. Chen
10:10 592. Effect of mono- and dianionic ligands
on the reactivity of monoalkylplatinum(II)
complexes toward O 2 in water.
A. Sberegaeva, A. Vedernikov
10:30 593. Reactivity of Pt and Rh hydrocarbyl
complexes with oxidants. J. R. Webb,
T. Gunnoe
10:50 Intermission
10:55 594. O-Ligated monoaryl palladium(IV)
complexes: Experimental and
computational study of direct C(sp 2 )-O
reductive elimination from Pd IV center.
A. N. Vedernikov,W.Oloo
11:15 595. Mononuclear alkyl and aryl Pd(III)
complexes and their reactivity in C-C and
C-X bond formation. L. M. Mirica,
J. R. Khusnutdinova
11:35 596. Synthesis, characterization and
electrochemical studies of Pd(III) complexes
stabilized by polydentate N-donor
ligands. J. R. Khusnutdinova,
L. M. Mirica
11:55 597. Chemistry and electrochemistry
of fluorinated rhodium acyl diphosphine
complexes, Rh(COR)(P-P)X 2.
B. D. Panthi, S. L. Gipson, A. Franken
Section D
Boston Convention & Exhibition Center
Room 259A/B
Coordination Chemistry
Synthesis
D. Crans, Organizer
J. Rohde, Presiding
8:30 598. Synthesis, spectroscopic and
electrochemical characterizations, density
functional theory calculations, and
activity screening of tridentate SNS zinc
pincer complexes. J. R. Miecznikowski,
W. Lo, M. A. Lynn, N. F. Kloczko,
B. E. O’Loughlin, A. P. DiMarzio,
L. C. Keilich, K. M. Foley
8:50 599. Mixed-valence models for [NiFe]
hydrogenase: Synthesis and reactivity.
D. Schilter, B. E. Barton, M. J. Nilges,
T. B. Rauchfuss
9:10 600. Family of new Mn/Ln (Ln � lanthanide)
single-molecule magnets with
record magnetization reversal barriers for
3d-4f SMMs. C. Papatriantafyllopoulou,
K. A. Abboud, W. Wernsdorfer,
G. Christou
9:30 601. Pseudo-tetrahedral metal-oxo
complexes supported by bulky alkoxides.
M. B. Chambers, S. Groysman,
D. G. Nocera
9:50 602. Synthesis, structure, and spectroscopy
of an iron(I)-sulfide complex.
M. M. Clark, B. D. Stubbert,
W. W. Brennessel, E. Bill, P. L. Holland
10:10 603. Synthesis, electrochemistry, and
magnetic properties of a binuclear bis(�-
OMe) Co(II)Co(III) mixed-valent complex.
J. Luo, L. M. Mirica
10:30 604. Binucleating ligands: Control of
the M-M distance in transition metal
complexes. F. Tang, L. Mirica
10:50 605. New aspects of chirality and molecular
sensing in metallocorrole chemistry.
O. A. Egorova, O. G. Tsay, K. Kim,
D. G. Churchill
11:10 606. Dialkyldiarylguanidinato(1–) ligands
and their iridium(I), iridium(III) and
iridium(IV) complexes. J. Rohde, W. Lee,
M. R. Kelley
11:30 607. Outer vs. inner-sphere redox
chemistry of 3d transition metal tris(pyrrolide)ethane
complexes. G. T. Sazama,
T. A. Betley
11:50 608. Dipyrromethene supported lowcoordinate
high-spin iron complexes and
their reactivity as platforms for C-H functionalization
via oxidative group transfer.
E. R. King, T. A. Betley
12:10 609. Rational design and synthesis of
polynuclear clusters to control M-M interactions.
A. R. Fout,T.A.Betley
Section F
Boston Convention & Exhibition Center
Room 257B
Chemistry of Materials
Polymer-related Research
D. Nelson, Organizer
J. Burgess, N. Kariuki, Presiding
8:30 610. Palladium alloys for oxygen reduction
in polymer electrolyte fuel cells.
N. N. Kariuki, X. Xiaoping, S. Niyogi,
D. J. Myers, T. Hofmann, Y. Zhang,
C. Heske, W. A. Goddard, III,, B. Merinov,
T. Yu
8:50 611. N-benzylazole and hydroxypyridine
substituted polyphosphazenes to be
used as proton exchange membranes in
fuel cells. S. K. Ekanayake, S. Moolsin,
M. J. Panzner, C. A. Tessier*,
W. J. Youngs*
9:10 612. Polymer microblades in srtificial
muscles: Toward bio-inspired adaptive
optics and self-sustaining propulsion.
P. Kim, J. M. Epstein, L. D. Zarzar,
M. Aizenberg, J. Aizenberg
The official technical program
for the 240th National Meeting
is available at:
www.acs.org/boston2010
INOR
TECH–69