TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
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Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Coordination Chemistry<br />
Characterization and Applications<br />
D. Crans, Organizer<br />
C. Lu, Presiding<br />
1:30 678. Controlling the polymerization of<br />
2,6-hexadiyne-diole in 1D metal-organic<br />
frameworks (MOFs) like [Al(OH)(terephthalate)]<br />
n: Structural investigations and<br />
possible properties. M. Meilikhov,<br />
K. Yusenko, R. A. Fischer<br />
1:50 679. Reactivity of early/late heterobimetallic<br />
complexes featuring metal-metal<br />
multiple bonds: Small molecule activation<br />
and catalytic applications.<br />
C. M. Thomas,G.T.Rowe,<br />
B. P. Greenwood, J. W. Napoline,<br />
W. Zhou, D. J. Graham, B. M. Foxman<br />
2:10 680. Orotate complexes of cobalt: Solid-state<br />
phase transition and metalloligand<br />
behavior toward silver and thallium.<br />
L. R. Falvello,M.Tomás, G. Martínez,<br />
N. Mushale<br />
2:30 681. Double bond between metals in<br />
the H 2Os 3(CO) 10 and H 2Ru 3(CO) 10 clusters?<br />
R. J. Alvarez-Mendez,<br />
O. Reyes-Lopez, M. J. Rosales-Hoz,<br />
A. Vela<br />
2:50 682. Synthesis, reactivity, and photochemistry<br />
of heterobimetallic rhodiumgold<br />
halide and hydride complexes.<br />
T. S. Teets, M. P. Neumann,<br />
D. G. Nocera<br />
3:10 683. Pseudorotaxanes as ligands for<br />
the construction of metal-organic molecular<br />
devices. G. Mezei, I. R. Fernando,<br />
S. Bairu, R. Guda, C. J. Ziegler<br />
3:30 684. Using molybdenum tetracarbonyl<br />
complexes to investigate photoinduced<br />
ligand field switching in photochromic<br />
spirooxazine ligands. M. M. Paquette,<br />
B. O. Patrick, N. L. Frank<br />
3:50 685. Withdrawn<br />
4:10 686. Copolymerizable ligands, and<br />
their incorporation in polymer based<br />
Cu 2� sensors. J. Massing,<br />
N. Bencivenga, J. Du, R. Ding, S. Yao,<br />
R. Planalp, R. Seitz, J. Reddel<br />
4:30 687. Reactivity of pseudotetrahedral<br />
nickel(II) arylthiolate complexes.<br />
M. Jensen, S. Chattopadhyay, T. Deb,<br />
V. G. Young, Jr.<br />
4:50 688. Characterization of high-spin triiron<br />
complexes with variable metal-metal<br />
interaction. E. V. Eames, T. A. Betley,<br />
Q. Zhao<br />
5:10 689. Reaction mechanism in the synthesis<br />
of (PNP)Rh�O using N2O.<br />
J. G. Andino,K.G.Caulton<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Inorganic Chemistry<br />
M. Millar, S. Koch, Organizers<br />
J. Caradonna, L. Doerrer, Presiding<br />
1:30 690. Discrete Cu(I) and dioxygen reactivity<br />
without N-donor ligands. J. S. Lum,<br />
L. H. Doerrer<br />
1:50 691. Fluorinated cobalt alkoxide complexes.<br />
S. A. Cantalupo, L. H. Doerrer<br />
2:10 692. Preparation and characterization<br />
of a reactive synthetic model complex to<br />
mimic the chemistry of TauD.<br />
P. C. Tarves, P. J. Cappillino,<br />
J. P. Caradonna<br />
2:30 693. Density functional theory (DFT)<br />
study of a series of Fe II/III nonheme iron<br />
oxygenase model compounds.<br />
J. S. McNally, P. J. Cappillino, F. Wang,<br />
J. P. Caradonna<br />
2:50 694. Reactivity studies of a functional<br />
non-heme iron enzyme model complex<br />
using stopped-flow UV/vis spectroscopy.<br />
L. C. Gregor,G.T.Rowe,<br />
E. V. Rybak-Akimova, J. P. Caradonna<br />
3:10 695. Studies toward understanding the<br />
mechanism of allosteric activation in phenylalanine<br />
hydroxylase. S. R. Soltau,<br />
G. Anarat, R. Napoleon, D. Kozakov,<br />
S. Vajda, J. P. Caradonna<br />
3:30 696. Investigation into the kinetic<br />
mechanisms and characterization of the<br />
active sites of truncated and full-length<br />
phenylalanine hydroxylases.<br />
B. J. Salsbery, G. Anarat,<br />
J. P. Caradonna<br />
3:50 697. Differential studies of the kinetics,<br />
mechanisms, and active site structures of<br />
truncated and full length phenylalanine<br />
hydroxylase. J. P. Caradonna<br />
4:10 698. Membrane permeable and impermeable<br />
sensors for the visualization and<br />
quantification of mobile zinc.<br />
D. Buccella,S.J.Lippard<br />
4:30 699. New synthetic platforms that<br />
mimic the structure and function of diiron<br />
monooxygenases. L. H. Do,S.J.Lippard<br />
4:50 700. Dioxygen activation in T201 variants<br />
of toluene/o-xylene monooxygenase<br />
hydroxylase from Pseudomonas sp. OX1.<br />
W. Song,S.J.Lippard<br />
5:10 701. Mechanistic studies of dioxygen<br />
activation in soluble methane monooxygenase.<br />
C. E. Tinberg,S.J.Lippard<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Chemistry of Materials<br />
Metal Organic Frameworks and Porous<br />
Surfaces<br />
D. Nelson, Organizer<br />
D. Knight, K. Chapman, Presiding<br />
1:30 702. Exceptionally high acetylene uptake<br />
in a microporous metal-organic<br />
framework with open metal sites.<br />
S. Xiang, W. Zhou, Y. Liu, B. Chen<br />
1:50 703. Novel monovalent metal organophosphates.<br />
T. L. Kinnibrugh,<br />
N. Jimenez Garcia, A. Clearfield<br />
2:10 704. Effects of crystal structure and<br />
linker on MOF luminescent properties.<br />
S. T. Meek, P. L. Feng, J. J. Perry,<br />
P. Doty, M. D. Allendorf<br />
2:30 705. Pressure-induced pore modification<br />
and amorphization in a metal-organic<br />
framework. K. W. Chapman,<br />
G. J. Halder, P. J. Chupas<br />
2:50 706. Metals supported on covalent organic<br />
frameworks as heterogeneous catalysts.<br />
C. E. Chan-Thaw, M. Bojdys,<br />
P. Katekomol, K. Kailasam, R. Palkovits,<br />
F. Schüth, A. Villa, L. Prati, A. Thomas<br />
3:10 Intermission<br />
3:30 707. Novel hydrogen storage materials<br />
obtained via the stabilization of aluminum<br />
borohydride. D. A. Knight, R. Zidan,<br />
R. Lascola, T. Motyka,<br />
P. Simvasubramanian, R. Mohtadi<br />
3:50 708. Chemistry of trimethylaluminium:<br />
A spontaneous route to thermally stable<br />
3D crystalline macroporous alumina<br />
foams with a hierarchy of pore sizes.<br />
B. Su, Y. Li, X. Yang<br />
4:10 709. Dry water: Can we still make<br />
waves? B. O. Carter, J. V. Weaver,<br />
D. J. Adams, A. I. Cooper, W. Wang,<br />
D. G. Spiller<br />
4:30 710. ZnO nanostructures with outstanding<br />
gas sensing performance.<br />
D. Bekermann, D. Barreca, E. Comini,<br />
A. Gasparotto, C. Maccato, R. A. Fischer,<br />
A. Devi<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Biology<br />
S. Wong, Organizer<br />
S. Pascu, Presiding<br />
1:30 711. Nanotubes as radiopharmaceuticals<br />
for cancer imaging and therapy.<br />
Y. Mackeyev, J. Sims-Mourtada,<br />
L. Wilson, I. Tworowska<br />
1:50 712. Synthesis, characterization, and<br />
computed tomography imaging of a tantalum<br />
oxide nanoparticle imaging agent.<br />
P. J. Bonitatibus Jr, A. S. Torres,<br />
G. D. Goddard, P. F. FitzGerald,<br />
A. M. Kulkarni<br />
2:10 713. Synthetic extracellular matrices<br />
and nanostructures for biomedical applications.<br />
W. Suh, G. Stucky, M. Tirrell<br />
2:30 714. Production of zeolite including microfluidic<br />
channels: Applications in biosensors.<br />
S. K. Kirdeciler,<br />
B. Ozansoy Kasap, B. Akata, S. Öztürk<br />
2:50 715. Design, synthesis, and characterization<br />
of functional carbon nanomaterials<br />
for bioimaging applications: Toward<br />
healthcare for the modern age.<br />
S. I. Pascu<br />
3:20 Intermission<br />
3:30 716. Novel approach to nanoscale materials<br />
assembly using bioengineered spider<br />
silk fusion proteins and chemically<br />
generated fusion proteins- application to<br />
the synthesis of a range of nanosized<br />
metal and oxide particles. C. C. Perry,<br />
O. Deschaume, H. A. Currie, D. L. Kaplan,<br />
E. Boix-Lopez, L. Canabady-Rochelle,<br />
D. J. Belton<br />
4:00 717. DNA-mediated assembly of<br />
nanocubes. F. Lu, Y. Zhang,<br />
D. van der Lelie, O. Gang<br />
4:20 718. Dephosphorylation of biologically<br />
relevant molecules by cerium oxide nanoparticles<br />
(CNP). M. H. Kuchma, J. Colon,<br />
B. Alvarado, C. H. Baker, A. Teblum,<br />
A. Masonov<br />
4:40 719. Design of intracellular pH sensitive<br />
nanovalve on mesoporous silica nanoparticle.<br />
M. Xue,H.Meng,T.Xia,<br />
Y. Zhao, J. F. Stoddart, A. E. Nel,<br />
J. I. Zink<br />
5:00 720. Noninvasive release of drugs by<br />
magnetic actuation of mechanized nanoparticles.<br />
C. R. Thomas, D. P. Ferris,<br />
J. Lee, J. Cheon, J. I. Zink<br />
5:20 721. Effect of surface chemistry on uptake,<br />
distribution and excretion of nanomaterials<br />
by Japanese medaka. Z. Zhu,<br />
R. Carboni, M. Quercio, B. Yan,<br />
O. R. Miranda, K. F. Arcaro, R. W. Vachet,<br />
V. M. Rotello<br />
A Half-Century at the Crossroads of<br />
Chemistry: Symposium in Honor of Royce<br />
Murrays 50 Years at Carolina<br />
Materials Chemistry & Nanoscience<br />
Sponsored by ANYL, Cosponsored by INOR<br />
WEDNESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Bioinorganic Chemistry<br />
M. Millar, Organizer<br />
7:00–9:00<br />
722. High yield flash-quench method to<br />
probe long-range electron transfer. P. Lin<br />
723. Bioinspired small molecule activation<br />
with monofunctionalized aminopyridine<br />
macrocyclic complexes of iron.<br />
T. Palluccio, V. Organo, W. Ye,<br />
E. Rybak-Akimova<br />
724. Interface probing with 2,6-pyridinedicarboxylic<br />
acid: CTAB micelles and reverse<br />
micelles. E. Gaidamauskas,<br />
D. Cleaver, P. B. Chatterjee, D. C. Crans<br />
725. Aromatic hydroxylation at nonheme iron<br />
model complexes: Kinetics and insights<br />
into the nature of the active species.<br />
O. Makhlynets, P. Das, L. Que Jr.,<br />
E. Rybak-Akimova<br />
726. Role of the [Fe-S] protein YfaE in the<br />
biosynthesis of the diferric-tyrosyl radical<br />
cofactor of class Ia ribonucleotide reductase.<br />
C. Shih, C. Wu, W. Jiang, C. Krebs,<br />
J. Stubbe<br />
727. Development of heme fusion tags for<br />
protein affinity purification, for protein<br />
quantitation, and for monitoring protein<br />
folding. W. B. Asher,T.D.Krauss,<br />
K. L. Bren<br />
728. Kinetic studies of formation and reactivity<br />
of peroxo- and Fe III Fe IV intermediates<br />
with tris-picolylamine ligands. X. Sun,<br />
S. V. Kryatov, E. V. Rybak-Akimova<br />
729. Spectroscopic and computational investigations<br />
into the mechanism of oxalate<br />
decarboxylase. A. M. Glass,<br />
T. A. Jackson<br />
730. Immobilization of Cellobiase enzyme in<br />
mesoporous silica and its application in<br />
saccharification of biomass. S. Das,<br />
D. Berke-Schlessel, Y. Wei<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
General Inorganic Chemistry<br />
B. Donovan-Merkert, M. Millar, Organizers<br />
7:00–9:00<br />
731. Self-assembled monolayers of heteroleptic<br />
ruthenium complexes incorporating<br />
redox-active ligand architectures.<br />
J. P. Harney, D. A. Walsh, J. Rochford<br />
732. Kinetic studies of labile olefins of platinum(II)<br />
complexes. J. A. Dudziak,<br />
J. D. Atwood<br />
733. Electronic perturbations of iron dipyrromethene<br />
complexes by variations in the<br />
ligand periphery. A. B. Scharf,<br />
T. A. Betley<br />
734. Oxidation of alcohols by a tetra-ruthenium<br />
polyoxometalate complex: Kinetics<br />
and mechanism. G. Zhu,C.Besson,<br />
Y. V. Geletii, P. Zhuk, D. G. Musaev,<br />
C. L. Hill<br />
735. Elctron transfer in [Ru(bpy) 2(5,5�dabpy-(phe-A)<br />
2)] 2� dyad. I. Hsu<br />
736. Synthesis, characterization, and metalation<br />
of phthalocyanine analogs with<br />
phenol and resorcinol units. R. S. Costa,<br />
C. J. Ziegler<br />
737. Contrasting magnetic dimensionality<br />
and other properties of nickel dibromide<br />
dihydrate and monohydrate.<br />
G. C. DeFotis,A.S.Hampton,<br />
J. M. Pothen, C. M. Davis, C. L. DeSanto<br />
738. Contrasting magnetic dimensionality<br />
and other properties of manganese dibromide<br />
dihydrate and monohydrate.<br />
G. C. DeFotis,A.S.Hampton,<br />
J. M. Pothen<br />
739. Detection via coumarin-based sensors<br />
for sensing metal ions and nerve gas<br />
agents. E. Sinn,F.A.Abebe<br />
740. Land-use and land cover effects on<br />
stream physical and chemical parameters<br />
of the Neponset River Watershed.<br />
N. D. Henderson, A. D. Christian,<br />
R. E. Hannigan<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–71