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TECHNICAL PROGRAM - American Chemical Society Publications

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Section D<br />

Boston Convention & Exhibition Center<br />

Room 259A/B<br />

Coordination Chemistry<br />

Characterization and Applications<br />

D. Crans, Organizer<br />

C. Lu, Presiding<br />

1:30 678. Controlling the polymerization of<br />

2,6-hexadiyne-diole in 1D metal-organic<br />

frameworks (MOFs) like [Al(OH)(terephthalate)]<br />

n: Structural investigations and<br />

possible properties. M. Meilikhov,<br />

K. Yusenko, R. A. Fischer<br />

1:50 679. Reactivity of early/late heterobimetallic<br />

complexes featuring metal-metal<br />

multiple bonds: Small molecule activation<br />

and catalytic applications.<br />

C. M. Thomas,G.T.Rowe,<br />

B. P. Greenwood, J. W. Napoline,<br />

W. Zhou, D. J. Graham, B. M. Foxman<br />

2:10 680. Orotate complexes of cobalt: Solid-state<br />

phase transition and metalloligand<br />

behavior toward silver and thallium.<br />

L. R. Falvello,M.Tomás, G. Martínez,<br />

N. Mushale<br />

2:30 681. Double bond between metals in<br />

the H 2Os 3(CO) 10 and H 2Ru 3(CO) 10 clusters?<br />

R. J. Alvarez-Mendez,<br />

O. Reyes-Lopez, M. J. Rosales-Hoz,<br />

A. Vela<br />

2:50 682. Synthesis, reactivity, and photochemistry<br />

of heterobimetallic rhodiumgold<br />

halide and hydride complexes.<br />

T. S. Teets, M. P. Neumann,<br />

D. G. Nocera<br />

3:10 683. Pseudorotaxanes as ligands for<br />

the construction of metal-organic molecular<br />

devices. G. Mezei, I. R. Fernando,<br />

S. Bairu, R. Guda, C. J. Ziegler<br />

3:30 684. Using molybdenum tetracarbonyl<br />

complexes to investigate photoinduced<br />

ligand field switching in photochromic<br />

spirooxazine ligands. M. M. Paquette,<br />

B. O. Patrick, N. L. Frank<br />

3:50 685. Withdrawn<br />

4:10 686. Copolymerizable ligands, and<br />

their incorporation in polymer based<br />

Cu 2� sensors. J. Massing,<br />

N. Bencivenga, J. Du, R. Ding, S. Yao,<br />

R. Planalp, R. Seitz, J. Reddel<br />

4:30 687. Reactivity of pseudotetrahedral<br />

nickel(II) arylthiolate complexes.<br />

M. Jensen, S. Chattopadhyay, T. Deb,<br />

V. G. Young, Jr.<br />

4:50 688. Characterization of high-spin triiron<br />

complexes with variable metal-metal<br />

interaction. E. V. Eames, T. A. Betley,<br />

Q. Zhao<br />

5:10 689. Reaction mechanism in the synthesis<br />

of (PNP)Rh�O using N2O.<br />

J. G. Andino,K.G.Caulton<br />

Section E<br />

Boston Convention & Exhibition Center<br />

Room 257A<br />

Inorganic Chemistry<br />

M. Millar, S. Koch, Organizers<br />

J. Caradonna, L. Doerrer, Presiding<br />

1:30 690. Discrete Cu(I) and dioxygen reactivity<br />

without N-donor ligands. J. S. Lum,<br />

L. H. Doerrer<br />

1:50 691. Fluorinated cobalt alkoxide complexes.<br />

S. A. Cantalupo, L. H. Doerrer<br />

2:10 692. Preparation and characterization<br />

of a reactive synthetic model complex to<br />

mimic the chemistry of TauD.<br />

P. C. Tarves, P. J. Cappillino,<br />

J. P. Caradonna<br />

2:30 693. Density functional theory (DFT)<br />

study of a series of Fe II/III nonheme iron<br />

oxygenase model compounds.<br />

J. S. McNally, P. J. Cappillino, F. Wang,<br />

J. P. Caradonna<br />

2:50 694. Reactivity studies of a functional<br />

non-heme iron enzyme model complex<br />

using stopped-flow UV/vis spectroscopy.<br />

L. C. Gregor,G.T.Rowe,<br />

E. V. Rybak-Akimova, J. P. Caradonna<br />

3:10 695. Studies toward understanding the<br />

mechanism of allosteric activation in phenylalanine<br />

hydroxylase. S. R. Soltau,<br />

G. Anarat, R. Napoleon, D. Kozakov,<br />

S. Vajda, J. P. Caradonna<br />

3:30 696. Investigation into the kinetic<br />

mechanisms and characterization of the<br />

active sites of truncated and full-length<br />

phenylalanine hydroxylases.<br />

B. J. Salsbery, G. Anarat,<br />

J. P. Caradonna<br />

3:50 697. Differential studies of the kinetics,<br />

mechanisms, and active site structures of<br />

truncated and full length phenylalanine<br />

hydroxylase. J. P. Caradonna<br />

4:10 698. Membrane permeable and impermeable<br />

sensors for the visualization and<br />

quantification of mobile zinc.<br />

D. Buccella,S.J.Lippard<br />

4:30 699. New synthetic platforms that<br />

mimic the structure and function of diiron<br />

monooxygenases. L. H. Do,S.J.Lippard<br />

4:50 700. Dioxygen activation in T201 variants<br />

of toluene/o-xylene monooxygenase<br />

hydroxylase from Pseudomonas sp. OX1.<br />

W. Song,S.J.Lippard<br />

5:10 701. Mechanistic studies of dioxygen<br />

activation in soluble methane monooxygenase.<br />

C. E. Tinberg,S.J.Lippard<br />

Section F<br />

Boston Convention & Exhibition Center<br />

Room 257B<br />

Chemistry of Materials<br />

Metal Organic Frameworks and Porous<br />

Surfaces<br />

D. Nelson, Organizer<br />

D. Knight, K. Chapman, Presiding<br />

1:30 702. Exceptionally high acetylene uptake<br />

in a microporous metal-organic<br />

framework with open metal sites.<br />

S. Xiang, W. Zhou, Y. Liu, B. Chen<br />

1:50 703. Novel monovalent metal organophosphates.<br />

T. L. Kinnibrugh,<br />

N. Jimenez Garcia, A. Clearfield<br />

2:10 704. Effects of crystal structure and<br />

linker on MOF luminescent properties.<br />

S. T. Meek, P. L. Feng, J. J. Perry,<br />

P. Doty, M. D. Allendorf<br />

2:30 705. Pressure-induced pore modification<br />

and amorphization in a metal-organic<br />

framework. K. W. Chapman,<br />

G. J. Halder, P. J. Chupas<br />

2:50 706. Metals supported on covalent organic<br />

frameworks as heterogeneous catalysts.<br />

C. E. Chan-Thaw, M. Bojdys,<br />

P. Katekomol, K. Kailasam, R. Palkovits,<br />

F. Schüth, A. Villa, L. Prati, A. Thomas<br />

3:10 Intermission<br />

3:30 707. Novel hydrogen storage materials<br />

obtained via the stabilization of aluminum<br />

borohydride. D. A. Knight, R. Zidan,<br />

R. Lascola, T. Motyka,<br />

P. Simvasubramanian, R. Mohtadi<br />

3:50 708. Chemistry of trimethylaluminium:<br />

A spontaneous route to thermally stable<br />

3D crystalline macroporous alumina<br />

foams with a hierarchy of pore sizes.<br />

B. Su, Y. Li, X. Yang<br />

4:10 709. Dry water: Can we still make<br />

waves? B. O. Carter, J. V. Weaver,<br />

D. J. Adams, A. I. Cooper, W. Wang,<br />

D. G. Spiller<br />

4:30 710. ZnO nanostructures with outstanding<br />

gas sensing performance.<br />

D. Bekermann, D. Barreca, E. Comini,<br />

A. Gasparotto, C. Maccato, R. A. Fischer,<br />

A. Devi<br />

Section G<br />

Boston Convention & Exhibition Center<br />

Room 256<br />

Nanoscience<br />

Biology<br />

S. Wong, Organizer<br />

S. Pascu, Presiding<br />

1:30 711. Nanotubes as radiopharmaceuticals<br />

for cancer imaging and therapy.<br />

Y. Mackeyev, J. Sims-Mourtada,<br />

L. Wilson, I. Tworowska<br />

1:50 712. Synthesis, characterization, and<br />

computed tomography imaging of a tantalum<br />

oxide nanoparticle imaging agent.<br />

P. J. Bonitatibus Jr, A. S. Torres,<br />

G. D. Goddard, P. F. FitzGerald,<br />

A. M. Kulkarni<br />

2:10 713. Synthetic extracellular matrices<br />

and nanostructures for biomedical applications.<br />

W. Suh, G. Stucky, M. Tirrell<br />

2:30 714. Production of zeolite including microfluidic<br />

channels: Applications in biosensors.<br />

S. K. Kirdeciler,<br />

B. Ozansoy Kasap, B. Akata, S. Öztürk<br />

2:50 715. Design, synthesis, and characterization<br />

of functional carbon nanomaterials<br />

for bioimaging applications: Toward<br />

healthcare for the modern age.<br />

S. I. Pascu<br />

3:20 Intermission<br />

3:30 716. Novel approach to nanoscale materials<br />

assembly using bioengineered spider<br />

silk fusion proteins and chemically<br />

generated fusion proteins- application to<br />

the synthesis of a range of nanosized<br />

metal and oxide particles. C. C. Perry,<br />

O. Deschaume, H. A. Currie, D. L. Kaplan,<br />

E. Boix-Lopez, L. Canabady-Rochelle,<br />

D. J. Belton<br />

4:00 717. DNA-mediated assembly of<br />

nanocubes. F. Lu, Y. Zhang,<br />

D. van der Lelie, O. Gang<br />

4:20 718. Dephosphorylation of biologically<br />

relevant molecules by cerium oxide nanoparticles<br />

(CNP). M. H. Kuchma, J. Colon,<br />

B. Alvarado, C. H. Baker, A. Teblum,<br />

A. Masonov<br />

4:40 719. Design of intracellular pH sensitive<br />

nanovalve on mesoporous silica nanoparticle.<br />

M. Xue,H.Meng,T.Xia,<br />

Y. Zhao, J. F. Stoddart, A. E. Nel,<br />

J. I. Zink<br />

5:00 720. Noninvasive release of drugs by<br />

magnetic actuation of mechanized nanoparticles.<br />

C. R. Thomas, D. P. Ferris,<br />

J. Lee, J. Cheon, J. I. Zink<br />

5:20 721. Effect of surface chemistry on uptake,<br />

distribution and excretion of nanomaterials<br />

by Japanese medaka. Z. Zhu,<br />

R. Carboni, M. Quercio, B. Yan,<br />

O. R. Miranda, K. F. Arcaro, R. W. Vachet,<br />

V. M. Rotello<br />

A Half-Century at the Crossroads of<br />

Chemistry: Symposium in Honor of Royce<br />

Murrays 50 Years at Carolina<br />

Materials Chemistry & Nanoscience<br />

Sponsored by ANYL, Cosponsored by INOR<br />

WEDNESDAY EVENING<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Hall C<br />

Bioinorganic Chemistry<br />

M. Millar, Organizer<br />

7:00–9:00<br />

722. High yield flash-quench method to<br />

probe long-range electron transfer. P. Lin<br />

723. Bioinspired small molecule activation<br />

with monofunctionalized aminopyridine<br />

macrocyclic complexes of iron.<br />

T. Palluccio, V. Organo, W. Ye,<br />

E. Rybak-Akimova<br />

724. Interface probing with 2,6-pyridinedicarboxylic<br />

acid: CTAB micelles and reverse<br />

micelles. E. Gaidamauskas,<br />

D. Cleaver, P. B. Chatterjee, D. C. Crans<br />

725. Aromatic hydroxylation at nonheme iron<br />

model complexes: Kinetics and insights<br />

into the nature of the active species.<br />

O. Makhlynets, P. Das, L. Que Jr.,<br />

E. Rybak-Akimova<br />

726. Role of the [Fe-S] protein YfaE in the<br />

biosynthesis of the diferric-tyrosyl radical<br />

cofactor of class Ia ribonucleotide reductase.<br />

C. Shih, C. Wu, W. Jiang, C. Krebs,<br />

J. Stubbe<br />

727. Development of heme fusion tags for<br />

protein affinity purification, for protein<br />

quantitation, and for monitoring protein<br />

folding. W. B. Asher,T.D.Krauss,<br />

K. L. Bren<br />

728. Kinetic studies of formation and reactivity<br />

of peroxo- and Fe III Fe IV intermediates<br />

with tris-picolylamine ligands. X. Sun,<br />

S. V. Kryatov, E. V. Rybak-Akimova<br />

729. Spectroscopic and computational investigations<br />

into the mechanism of oxalate<br />

decarboxylase. A. M. Glass,<br />

T. A. Jackson<br />

730. Immobilization of Cellobiase enzyme in<br />

mesoporous silica and its application in<br />

saccharification of biomass. S. Das,<br />

D. Berke-Schlessel, Y. Wei<br />

Section B<br />

Boston Convention & Exhibition Center<br />

Hall C<br />

General Inorganic Chemistry<br />

B. Donovan-Merkert, M. Millar, Organizers<br />

7:00–9:00<br />

731. Self-assembled monolayers of heteroleptic<br />

ruthenium complexes incorporating<br />

redox-active ligand architectures.<br />

J. P. Harney, D. A. Walsh, J. Rochford<br />

732. Kinetic studies of labile olefins of platinum(II)<br />

complexes. J. A. Dudziak,<br />

J. D. Atwood<br />

733. Electronic perturbations of iron dipyrromethene<br />

complexes by variations in the<br />

ligand periphery. A. B. Scharf,<br />

T. A. Betley<br />

734. Oxidation of alcohols by a tetra-ruthenium<br />

polyoxometalate complex: Kinetics<br />

and mechanism. G. Zhu,C.Besson,<br />

Y. V. Geletii, P. Zhuk, D. G. Musaev,<br />

C. L. Hill<br />

735. Elctron transfer in [Ru(bpy) 2(5,5�dabpy-(phe-A)<br />

2)] 2� dyad. I. Hsu<br />

736. Synthesis, characterization, and metalation<br />

of phthalocyanine analogs with<br />

phenol and resorcinol units. R. S. Costa,<br />

C. J. Ziegler<br />

737. Contrasting magnetic dimensionality<br />

and other properties of nickel dibromide<br />

dihydrate and monohydrate.<br />

G. C. DeFotis,A.S.Hampton,<br />

J. M. Pothen, C. M. Davis, C. L. DeSanto<br />

738. Contrasting magnetic dimensionality<br />

and other properties of manganese dibromide<br />

dihydrate and monohydrate.<br />

G. C. DeFotis,A.S.Hampton,<br />

J. M. Pothen<br />

739. Detection via coumarin-based sensors<br />

for sensing metal ions and nerve gas<br />

agents. E. Sinn,F.A.Abebe<br />

740. Land-use and land cover effects on<br />

stream physical and chemical parameters<br />

of the Neponset River Watershed.<br />

N. D. Henderson, A. D. Christian,<br />

R. E. Hannigan<br />

The official technical program<br />

for the 240th National Meeting<br />

is available at:<br />

www.acs.org/boston2010<br />

INOR<br />

TECH–71

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