TECHNICAL PROGRAM - American Chemical Society Publications

ORGN TECHNICAL PROGRAM
270. Design, synthesis, and topochemical
polymerization of diacetylene macrocyclic
systems. T. Hsu, F. W. Fowler,
J. W. Lauher
271. Probing early events in peptide self-assembly
with nonnatural amino acids.
T. M. Doran, A. J. Kamens, N. K. Byrnes,
B. L. Nilsson
272. Withdrawn
273. Exploring the effect of linker topology
on the binding affinity of donor acceptor
hetero-duplexes. S. A. Samuel,
B. Iverson
274. Thermal reaction of a columnar assembled
diacetylene macrocycle. Y. Xu,
L. S. Shimizu
275. Dan-Ndi liquid crystals: Tunable mesophases
and potential photovoltaic applications.
P. M. Alvey, B. Iverson
276. Concentric cyclic assembly of watersoluble
aedamers. C. R. Martinez,
B. L. Iverson
277. 3-Halodiazirinyl anion: A complex of
diazirinylidene and halide ion. T. Martinu,
E. Hanzlova
278. Dynamics of spin-labels in solvent inclusions
in potassium hydrogen phtalate
and phtalic acid single crystals.
L. Ryzhkov
279. Asymmetric Diels-Alder reaction using
benzoin as a photoremovable chiral auxiliary.
V. B. Kammath,P.Sˇ ebej,
T. Slanina, P. Klán
280. Study of 1-naphthyl N-methylcarbamate
� OH radical gas-phase reaction:
Mechanism, kinetics, and branching ratios.
C. Zavala-Oseguera, A. Galano,
G. Merino
281. Computational studies on the structure
and photophysical properties of photochromic
oligothienoacene derivatives.
W. Lam,C.Ko,V.Yam
282. Changing reaction mechanisms with
force. T. J. Kucharski, Q. Yang, Y. Tian,
N. C. Rubin, R. Boulatov
283. p-Hydroxyphenacyl as a photoremovable
protecting group for amines and
amino acids. I. Bownik, J. Literák,
R. S. Givens, P. Klán
284. Slow rearrangement of a sterically hindered
nitrocyclohexadienone and the absence
of phenol oxidation by NO.
S. J. Peters, M. E. Kassabaum,
T. M. Blood
285. Dynamics of 1,3-dipolar cycloadditions
and carbene cycloadditions. L. Xu,
D. E. Charles, K. N. Houk, R. A. Moss
286. Planar and nearly planar trialkylamines.
D. S. Makhanu,A.N.Alsobrook,
A. D. Nelson, T. E. Albrecht-Schmitt,
P. D. Livant
287. Symmetry of N-X-N halogen bonds in
solution. A. C. Carlsson, M. Erdelyi
288. New carbazole, indole, and diphenylamine
based emissive compounds:
Synthesis, photophysical properties, and
formation of nanoparticles. K. Panthi,
T. H. Kinstle
289. Mechanistic insights into the copper(II)promoted
aminooxygenation of alkenes.
M. C. Paderes, J. B. Keister,
S. R. Chemler
290. Elucidating the relative importance of
various photochemically produced reactive
intermediates in the photodegradation
of endocrine-disrupting pollutants.
K. E. Daumit,C.M.Whidbey,
C. N. Goodwin, J. L. Gray, D. E. Latch
291. Using the photo-Fries reaction as a
photochemical probe to quantify the cage
effects of ionic liquids. A. Zablowsky,
A. E. Keirstead
292. N-(�-Aminoalkyl)tetrazoles: Synthesis
and NMR study of the tautomeric equilibria.
B. M. El-Gendy, B. Draghici, C. Hall,
P. J. Steel
293. Experimental and computational investigations
of the thermochemical decomposition
of aryl ether lignin model compounds.
M. K. Kidder, A. Beste,
A. Buchanan
88–TECH
‡ Cooperative Cosponsorship
294. Molecular torsion balance for evaluation
of halogen bonding in polar and nonpolar
solvents. S. K. Keyser, C. S. Wilcox
295. Mechanism for the fragmentation of
aryltrialkylstannane cation radicals.
P. Luo, J. P. Dinnocenzo
296. Bottom-up synthesis of graphene nanoribbons.
J. Kintigh, G. P. Miller
297. X-ray crystal structures of organothiosubstituted
pentacenes. J. B. Briggs,
I. Kaur, G. P. Miller
298. Synthesis and study of substituted starphenes.
R. P. Kopreski, G. P. Miller
299. Intramolecular enyne-pyridone photocycloaddition.
S. Kulyk, S. M. Sieburth
300. Synthesis of unusual bicyclic amino
acid from D-Glucose and its use in the
synthesis of natural product analogs.
N. Goyal,G.Wang
301. Efficient ligand-free copper catalyzed
N-arylation of sulfonamides.
T. Yong-Chua,F.Yong
302. Manganese-catalyzed cross-coupling
reactions of nitrogen nucleophiles with
aryl halides in water. Y. Teo, F. Yong,
C. Poh, Y. Yan, G. Chua
303. Highly enantioselective 1,3-dipolar addition
of azomethine ylide with unsaturated
ketones, esters, and amides.
K. Shimizu, K. Ogata, S. Fukuzawa
MONDAY MORNING
Section B
Boston Convention & Exhibition Center
Room 205A/B
Robert Burns Woodward Memorial
Symposium
R. Williams, W. Greenlee, Organizers
L. T. Scott, Organizer, Presiding
8:00 Introductory Remarks by Roald Hoffmann
8:10 304. Natural product synthesis.
Y. Kishi
9:10 305. Topics in discovery and process
chemistry from pharmaceutical and crop
protection R&D. P. N. Confalone
10:00 Intermission
10:20 306. Design of bifunctional allylboron
reagents via allene hydroboration reactions
and applications to the synthesis of
natural products. W. R. Roush
11:10 307. Synthetic studies on selective
phosphatidylinositol 3-kinase inhibitors.
P. A. Jacobi, E. Onyango, T. Konekamp
Section C
Boston Convention & Exhibition Center
Room 206A
New Reactions and Methodology
S. Sieburth, Organizer
C. Stephenson, Presiding
8:00 308. Concise approach to the synthesis
of vinigrol using electrocyclic cyclization.
D. Wang,W.E.Crowe
8:20 309. Novel cascade ether synthesis
through the [3,3] sigmatropic rearrangement
of N-allylhydrazones. K. E. Lutz,
R. J. Thomson, D. A. Mundal
8:40 310. Discovery of silver-N-heterocylic
carbenes as novel promoters for O-glycosidation
reactions. I. J. Talisman,
V. Kumar, S. V. Malhotra
9:00 311. Electron transfer-initiated Diels-Alder
cycloadditions of 2�-hydroxychalcones.
H. Cong, J. A. Porco
9:20 312. Highly efficient, three-component,
one-pot, microwave-assisted synthesis
of 2,3-disubstituted benzofurans under
Sonogashira conditions. N. A. Markina,
Y. Chen, R. C. Larock
9:40 313. Copper-catalyzed [4�1] cycloaddition
of 1,3-dienes and nitrene precursors.
J. Zhou
10:00 314. Synthesis of amines, aldehydes,
and imines: Exceeding chemoselectivity
in secondary amide reductions.
G. Pelletier, W. S. Bechara,
A. B. Charette
10:20 315. Bayer-Villiger oxidation of 2-acylcyclic
ketones: A novel approach for the
synthesis of acyl substituted alpha-hydroxy
and alpha-beta unsaturated long
chain acids. V. R. Neelagiri
10:40 316. Boronic acid catalysis for mild
and selective cycloadditions of unsaturated
carboxylic acids. H. Zheng,
O. Marion, D. G. Hall
11:00 317. Sequenced Brook and Ireland-
Claisen rearrangements of allylic silyl
glyoxylates. D. C. Schmitt,J.S.Johnson
11:20 318. Novel expedient synthesis of
18 O-labelled allyl alcohol. S. Purser,
G. J. Owen-Smith, G. C. Lloyd-Jones
11:40 319. Electrophilic aromatic selenylation.
S. Knapp,M.Abdo
Section D
Boston Convention & Exhibition Center
Room 203
Biologically-Related Molecules &
Processes
S. Sieburth, Organizer
C. Meyers, Presiding
8:00 320. Chemistry of thyroxine and dissociation
of arylglyoxylic acids. R. Reddy
8:20 321. Chemical communication within
and between species. M. M. Meijler
8:40 322. Natural product isolation from
some marine-derived fungi.
D. K. Fearon, P. B. Reese
9:00 323. Simple synthesis, anti-breast cancer
activity of novel coumarin-based sulfonamides:
A coumestrol derivative and
related molecules. G. Zeng,W.Mao,
H. Zeng, T. Wang, Z. Zhu, S. Liu
9:20 324. Molecular imaging approaches to
understanding hydrogen peroxide biology
in stress and development.
B. C. Dickinson,C.J.Chang
9:40 325. Synthetic scale-up and process
optimization of glyceollin I, a novel natural
product that displays interesting anticancer
activity. A. Luniwal, M. El-Dakdouki,
L. Fang, R. Khuspe, J. Liu, M. Reese,
P. W. Erhardt
10:00 326. Fungal biotransformation of
Ferutinin and Tschimganin to afford bioactive
products. A. Azarpira,
M. I. Choudhary, S. A. Sattar, A. Rahman
10:20 327. Synthesis of affinity tags for the
proteomic profiling of cysteine sulfenic
acids and S-nitrosothiols. E. Bechtold,
J. Qian, K. J. Nelson, L. B. Poole,
C. M. Furdui, S. B. King
10:40 328. Mutasynthesis of novel thiopeptide
natural product antibiotics.
M. G. Acker, A. A. Bowers, A. Koglin,
C. T. Walsh
11:00 329. Development of fluorescent substrates
for vesicular monoamine transporter
2 (VMAT2) and their application in
high throughput screening of VMAT2 inhibitors.
G. Hu,D.Sames
11:20 330. Synthesis and screening of PI3K
inhibitor prodrugs for prostate cancer
treatment. T. A. Pinder, M. Welker,
G. Kulik
11:40 331. Diversity-oriented synthesis of
macrocyclic peptidomimetic scaffolds.
A. Isidro-Llobet, P. Bello, T. Murillo,
D. R. Spring
12:00 332. Synthesis of vitamin D analogs
as ligands for mutant human vitamin D receptor
(Arg274Leu). S. Honzawa,
N. Takahashi, A. Yamashita, T. Sugiura,
M. A. Arai, S. Kato, M. Kurihara,
A. Kittaka
Section E
Boston Convention & Exhibition Center
Room 204A
Total Synthesis of Complex Molecules
S. Sieburth, Organizer
A. Doyle, Presiding
8:00 333. Concise racemic and asymmetric
total synthesese of strychnos alkaloids:
Akuammicine, strychnine. G. Sirasani,
T. Paul, R. B. Andrade
8:20 334. Progress towards total synthesis
of Ammocidin D. S. T. Chau,J.A.Teske,
Q. Liu, G. A. Sulikowski
8:40 335. Progress towards the total synthesis
of Pectenotoxin 4. R. Sharma,
L. J. Williams
9:00 336. Efficient total synthesis of (-)-1
(10),5-germacradien-4-ol from Pinus strobus.
J. J. Kiddle, J. M. Smith,
A. M. Vermeersch, T. Lim
9:20 337. Convergent synthesis of the natural
product DC-45-A2, the parent aglycone
of the trioxacarcins. N. Hill,
J. Svenda, A. G. Myers
9:40 338. Six-step synthesis of strychnine.
D. B. Martin, C. D. Vanderwal
10:00 339. Total synthesis of (�)-nakadomarin
A. P. Jakubec,
D. M. Cockfield, D. J. Dixon
10:20 340. Studies toward the synthesis of
sanggenol-type natural products.
Y. Xiong,J.A.Porco
10:40 341. Concise total syntheses of Lycopodium
and Aspidosperma alkaloids.
S. P. Waters,X.Cheng
11:00 342. Studies directed toward the total
synthesis of isatisine A. J. Lee,
J. S. Panek
11:20 343. Synthetic access to members of
the Aeruginosin family of natural products
relying upon a novel oxabicyclic building
block. C. S. Schindler, E. M. Carreira
11:40 344. Synthesis and biological evaluation
of the macrolide 4,8,10-tridesmethyl
cethromycin, an effort towards overcoming
antibiotic resistance. B. S. Wagh,
V. Velvadapu, T. Paul, R. B. Andrade
Section F
Boston Convention & Exhibition Center
Room 204B
Asymmetric Reactions and Syntheses
S. Sieburth, Organizer
D. Coltart, Presiding
8:00 345. Novel camphor-based amino alcohols
and diols for selected asymmetric
synthesis. O. B. Olubanwo,J.A.Golen,
V. Nevalainen
8:20 346. Computationally inspired diastereo-
and enantioselective rhodium-catalyzed
Pauson-Khand reaction at room
temperature. P. Ricci, P. Evans, M. Baik
8:40 347. Enantioenriched allenylsilanes as
building blocks for stereocontrol in organic
synthesis. R. A. Brawn,J.S.Panek
9:00 348. Design and synthesis of cobalt(II)
porphyrin catalysts for stereoselective intro-molecular
cyclopropanation. X. Xu,
H. Lu, R. Joshua, P. Zhang
9:20 349. Asymmetric total synthesis of (�)clusianone
via N-amino cyclic carbamate
hydrazones. M. R. Garnsey,D.Lim,
J. Yost, D. M. Coltart
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