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TECHNICAL PROGRAM - American Chemical Society Publications

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TUESDAY AFTERNOON<br />

Section B<br />

Boston Convention & Exhibition Center<br />

Room 258C<br />

ExxonMobil Solid State Chemistry Faculty<br />

Fellow Award<br />

Symposium in Honor of Sarbajit Banerjee<br />

S. Brock, Organizer, Presiding<br />

1:30 Introductory Remarks<br />

1:40 414. Understanding the influence of finite<br />

size on the phase transitions and<br />

phase stabilities of early transition metal<br />

oxides. S. Banerjee, L. Whittaker,<br />

C. J. Patridge, S. W. Depner,<br />

J. M. Velazquez, K. R. Kort<br />

2:10 415. Nanomaterials for energy storage.<br />

M. Whittingham<br />

2:40 416. <strong>Chemical</strong> strategies in nanoscience.<br />

S. S. Wong<br />

3:10 Intermission<br />

3:25 417. Using local structural probes to<br />

understand and optimize the functioning<br />

of lithium ion battery materials. B. Key,<br />

R. Bhattacharyya, N. Trease, C. P. Grey<br />

3:55 418. Nanomaterials composed of<br />

nanocomponents: Nanoparticle supercrystals<br />

and hybrids. I. P. Herman<br />

4:25 419. Discovery and characterization of<br />

novel materials for electrical energy generation<br />

and storage: Fuel cells, batteries<br />

and super-caps. H. D. Abruña<br />

4:55 Concluding Remarks<br />

Section C<br />

Boston Convention & Exhibition Center<br />

Room 258B<br />

Ligand Design and Metal Behavior<br />

M. Millar, S. Koch, Organizers<br />

L. Doerrer, Organizer, Presiding<br />

1:30 420. Monobridged, binuclear metallacycles<br />

supported by third generation<br />

bis(1-pyrazolyl)methane ligands: Unusual<br />

magnetic properties. D. L. Reger,<br />

E. A. Foley, R. P. Watson, A. E. Pascui,<br />

M. D. Smith<br />

2:00 421. Design of phosphine ligands for<br />

electrocatalytic carbon dioxide reduction<br />

and formate oxidation. D. DuBois,<br />

B. Boro, J. Linehan, J. Roberts, B. Galan,<br />

J. Schoffel, C. Kubiak<br />

2:30 422. Bimetallic cooperativity in catalysis<br />

based on a binuclating tetraphosphine<br />

ligand. G. G. Stanley, D. Polakova,<br />

A. R. Barnum, C. T. Alexander,<br />

Z. S. Wilson, M. A. Peterson<br />

3:00 Intermission<br />

3:10 423. Evolution from TMPA (� TPA) in<br />

copper-dioxygen and heme-copper-dioxygen<br />

coordination chemistry.<br />

K. D. Karlin<br />

3:50 424. Construction and properties of<br />

binuclear Ni-Fe complexes in relation to<br />

the active site of Ni-Fe-S carbon monoxide<br />

dehydrogenase. D. Huang,<br />

R. H. Holm<br />

4:20 425. Coordination chemistry with trisphenolate,<br />

thiolate, and selenolate amine<br />

and phosphine tripod ligands. S. A. Koch<br />

4:50 426. Ligand design elements that promote<br />

generation of high-valent nonheme<br />

iron-oxo species. L. Que, Jr.<br />

Section E<br />

Boston Convention & Exhibition Center<br />

Room 257A<br />

Bioinorganic Chemistry<br />

M. Millar, S. Koch, Organizers<br />

A. Valentine, J. Wilker, Presiding<br />

1:30 427. Active site of particulate methane<br />

monooxygenase. R. Balasubramanian,<br />

S. M. Smith, M. A. Culpepper, S. Rawat,<br />

L. A. Yatsunyk, T. L. Stemmler,<br />

A. Rosenzweig<br />

2:10 428. Bioinorganic approaches to renewable<br />

energy catalysis. C. J. Chang<br />

2:30 429. Synthesis and reactivity of manganese<br />

and iron complexes with methylated<br />

derivatives of bis(2-pyridylmethyl)-<br />

1,2-ethanediamine (bispicen).<br />

C. M. Coates, K. Hagan, C. A. Mitchell,<br />

C. R. Goldsmith<br />

2:50 430. Titanium in the environment: Siderophore<br />

coordination and photoreactivity.<br />

K. L. Batchler, K. E. Cole,<br />

A. M. Valentine<br />

3:10 431. Development of multifunctional<br />

small molecules as chemical tools and<br />

potential therapeutics for Alzheimer’s disease.<br />

M. Lim<br />

3:30 432. Escaping the octopus-like grasp<br />

of iron-oxygen chemistry: Studies on marine<br />

biological materials. J. D. White,<br />

C. R. Matos-Perez, J. R. Burkett,<br />

A. O. Mattes, T. W. McCarthy,<br />

J. J. Wilker<br />

3:50 433. Recognition of Zn 2� by the conjugates<br />

of calixarenes and carbohydrates<br />

and the role of the corresponding complex<br />

in biorelevant systems. C. P. Rao<br />

4:10 434. Development of caged-complexes<br />

for studying signaling and homeostasis of<br />

metal ions. S. C. Burdette<br />

4:30 435. Comparison of the reactivity<br />

chemistry of mononuclear and binuclear<br />

non-heme ferrous complexes with oxygen,<br />

peroxides, and oxygen atom donor<br />

molecules. J. P. Caradonna<br />

Section F<br />

Boston Convention & Exhibition Center<br />

Room 257B<br />

Inorganic Catalysts<br />

B. Donovan-Merkert, Organizer<br />

N. Abrams, Presiding<br />

1:30 436. Studies of the effects of hydrogen<br />

with the hopes of improving the catalytic<br />

reduction of dinitrogen to ammonia at a<br />

single molybdenum center. B. S. Hanna,<br />

R. R. Schrock<br />

1:50 437. Cross-coupling with tricarbonylchromium-coordinated<br />

benzyllithiums: A<br />

new approach to polyarylmethane derivatives.<br />

G. I. McGrew, J. Temaismithi,<br />

P. J. Carroll, P. J. Walsh<br />

2:10 438. One-pot synthesis of catalytically<br />

stable and active nanoreactors: Encapsulation<br />

of size-controlled nanoparticles<br />

within a hierarchically macroporous core<br />

@ordered mesoporous shell system.<br />

B. Su,X.Yang<br />

2:30 439. Investigation of nanostructured<br />

mixed monolayer protected nanoparticles<br />

as catalytic platforms. A. Ghosh,<br />

S. Basak, B. H. Wunsch, R. Kumar,<br />

F. Stellacci<br />

2:50 440. Spinel-type cobalt-manganesebased<br />

mixed oxide as sacrificial catalyst<br />

for the high yield synthesis of homogeneous<br />

carbon nanotubes. J. Tessonnier,<br />

M. Becker, W. Xia, F. Girgsdies,<br />

R. Blume, L. Yao, D. Su, M. Muhler,<br />

R. Schlögl<br />

3:10 441. Structures and reaction mechanisms<br />

of propene oxide isomerization to<br />

propanal on H-FER zeolite: A theoretical<br />

study using the newly developed density<br />

functional theory. B. Boekfa, T. Maihom,<br />

S. Wannakao, K. Bobuatong,<br />

J. Limtrakul<br />

3:30 442. Reaction mechanisms of ethene<br />

formation via ethanol dehydration catalyzed<br />

by Fe-ZSM-5 zeolite: An ONIOM<br />

study with an M06-L functional.<br />

T. Maihom, B. Boekfa, S. Wannakao,<br />

J. Limtrakul<br />

3:50 443. Spinel ferrite nanoparticles as selective<br />

microwave absorbers for heterogeneous<br />

oxidation catalysis.<br />

M. Thompson, P. Chem,<br />

L. J. van de Burgt, A. E. Stiegman<br />

4:10 444. Novel oxynitride compounds from<br />

cellulose biotemplates. A. Levine,<br />

J. M. MCEnaney, N. M. Abrams<br />

4:30 445. Synthesis of different CeO 2 structures<br />

on mesoporous silica and characterization<br />

of the reduction properties and<br />

the catalytic behavior. J. Strunk,<br />

W. C. Vining, A. T. Bell<br />

4:50 446. Investigation on the contradictory<br />

gas sensing behaviors of semiconducting<br />

ZnO and Zn 2SnO 4 single crystalline<br />

nanowires arrays. A. Cai<br />

Section G<br />

Boston Convention & Exhibition Center<br />

Room 256<br />

Nanoscience<br />

Optoelectronic Characterization<br />

S. Wong, Organizer<br />

S. Lee, Presiding<br />

1:30 447. Photo-induced electron transfer in<br />

chromophore-functionalized quantum<br />

sized gold clusters. K. Kwak,<br />

M. Devadas, H. Lee, G. Ramakrishna,<br />

D. Lee<br />

1:50 448. Fluorophore functionalized metal<br />

clusters. M. Devadas, D. Lee, E. Sinn<br />

2:10 449. Upconversion luminescence and<br />

X-ray-excited optical luminescence<br />

(XEOL) of lanthanide doped Yttrium oxide<br />

nanocrystals. I. N. Stanton, J. A. Ayres,<br />

M. J. Therien<br />

2:30 450. Ab initio study of multiple exiton<br />

generation (MEG) in quantum dots.<br />

Z. Zhang, P. Zimmerman, C. Musgrave<br />

2:50 451. Surface-enhanced Raman spectroscopy<br />

with silver nanocube dimers:<br />

Experiment and calculation. S. Lee,<br />

G. S. Lang, L. Hung, J. E. Cornett,<br />

I. D. Mayergoyz, O. Rabin<br />

3:20 Intermission<br />

3:40 452. Solar energy conversion with selforganized<br />

regular arrays of S-doped TiO 2<br />

nanotubes. Y. Shin, S. Lee<br />

4:10 453. Probing dynamics of photoinduced<br />

charge transfer in heterodimers<br />

composed of CdSe/ZnS quantum dots<br />

and fullerene derivatives by single molecule<br />

spectroscopy. M. Cotlet,Z.Xu<br />

4:30 454. Single-molecule optical detection<br />

of nitroaromatic compounds by carbon<br />

nanotubes. D. A. Heller, G. W. Pratt,<br />

J. Zhang, N. Nair, A. J. Hansborough,<br />

A. A. Boghossian, N. F. Reuel,<br />

P. W. Barone, M. S. Strano<br />

4:50 455. Exciton antennae and concentrators<br />

from core-shell and corrugated carbon<br />

nanotube filaments of homogeneous<br />

composition. J. Han, G. L. Paulus,<br />

R. Maruyama, D. A. Heller, W. Kim,<br />

P. W. Barone, C. Lee, J. Choi, M. Ham,<br />

C. Song, C. Fantini, M. S. Strano<br />

5:10 456. Anomalously large reactivity of<br />

single graphene layers and edges toward<br />

electron transfer chemistries. R. Sharma,<br />

J. Baik, C. Perera, M. S. Strano<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Room 258A<br />

Commemoration of the Founding of the<br />

ACS Journal Organometallics<br />

Synthesis and Catalysis<br />

D. Lichtenberger, Organizer, Presiding<br />

2:00 457. Efficient iron catalyst for the chemoselective<br />

hydrogenation of aldehydes<br />

and ketones. C. P. Casey,H.Guan,<br />

A. C. Atesin<br />

2:30 458. Multiheterometallic transition<br />

metal complexes: Going for records.<br />

H. Lang<br />

3:00 459. Custom polyethylene by molecular<br />

design. J. C. Stevens<br />

3:30 460. Some memories and then some<br />

new chemistry of single walled carbon<br />

nanotubes. M. L. Green<br />

4:00 Close of symposium D. Seyferth,<br />

J. Gladysz<br />

Section D<br />

Boston Convention & Exhibition Center<br />

Room 259A/B<br />

Main Group Chemistry<br />

B. Donovan-Merkert, Organizer<br />

J. J. Weigand, Presiding<br />

2:00 461. Lewis acidic properties of a bifunctional<br />

stibonium/borane. C. R. Wade,<br />

F. P. Gabbaï<br />

2:20 462. Use of group 6 carbonyl reagents<br />

to stabilize phosphonium and siliconium<br />

cationic species. J. M. Beres,<br />

A. M. Leigh, M. J. Panzner, V. Scionti,<br />

B. D. Wright, C. Wesdimiotis,<br />

W. J. Youngs, C. A. Tessier<br />

2:40 463. Phosphorus-containing<br />

calix[5]arene metal complexes: Catalysis<br />

and a rare � 6 palladium geometry.<br />

B. Rios, M. Lattman<br />

3:00 Intermission<br />

3:10 464. Heavy atom effects in thienyl<br />

BODIPY systems. K. Kim, T. Jun,<br />

S. Khatua, S. Choi, D. G. Churchill<br />

3:30 465. Capturing In � monomers in a neutral<br />

weakly coordinating environment.<br />

T. Jurca, S. I. Gorelsky, I. Korobkov,<br />

G. P. Yap, D. S. Richeson<br />

3:50 466. Transition metal-like behavior of<br />

mercury in a dinuclear complex featuring<br />

a mercury3antimony interaction. T. Lin,<br />

C. R. Wade, F. P. Gabbaï<br />

4:10 467. Formation of cationic phosphorus<br />

clusters by insertion of phosphenium cations<br />

into P-P bonds of the P 4 tetrahedron.<br />

J. J. Weigand, M. H. Holthausen<br />

TUESDAY EVENING<br />

Section A<br />

Boston Convention & Exhibition Center<br />

Hall C<br />

Inorganic Chemistry<br />

M. Millar, Organizer<br />

7:00–9:00<br />

468. Synthesis of biologically relevant manganese<br />

clusters by reductive aggregation.<br />

W. Lo, S. Vaddypally, P. Müller,<br />

W. H. Armstrong<br />

469. Trinuclear manganese complexes relevant<br />

to Photosystem II. S. Vaddypally,<br />

W. Lo, L. Greb, W. H. Armstrong<br />

470. Influence of platinum-based anticancer<br />

agents on nucleosome mobility. G. Zhu,<br />

S. J. Lippard<br />

471. Elucidation of the reactivity of nitric oxide<br />

with polypyrridyl copper(II) complexes.<br />

J. Rosenthal, J. Kozhukh,<br />

S. J. Lippard<br />

472. Visualization of endogenous nitric oxide<br />

in live cells using cell-trappable fluorescent<br />

probes. M. D. Pluth, L. E. McQuade,<br />

S. J. Lippard<br />

473. Pt(IV) encapsulated PLGA-PEG nanoparticles<br />

for targeting integrins in tumors.<br />

N. J. Graf, N. Kolishetti, D. R. Bielenberg,<br />

O. C. Farokhzad, S. J. Lippard<br />

474. Thermodynamic studies of DNA duplexes<br />

containing the spiroiminodihydantoin<br />

lesion. E. R. Jamieson,<br />

F. Chinyengetere, M. Dwarakanath,<br />

M. Ng, M. Thida, C. Gao, M. Martei<br />

475. Solid state coordination chemistry: Organic-inorganic<br />

hybrid materials constructed<br />

from copper 5-(4�-pyridyl)tetrazole<br />

networks with embedded molybdate<br />

clusters. S. Jones,H.Liu,<br />

C. C. O’Connor, J. Zubieta<br />

The official technical program<br />

for the 240th National Meeting<br />

is available at:<br />

www.acs.org/boston2010<br />

INOR<br />

TECH–67

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