TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
TECHNICAL PROGRAM - American Chemical Society Publications
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TUESDAY AFTERNOON<br />
Section B<br />
Boston Convention & Exhibition Center<br />
Room 258C<br />
ExxonMobil Solid State Chemistry Faculty<br />
Fellow Award<br />
Symposium in Honor of Sarbajit Banerjee<br />
S. Brock, Organizer, Presiding<br />
1:30 Introductory Remarks<br />
1:40 414. Understanding the influence of finite<br />
size on the phase transitions and<br />
phase stabilities of early transition metal<br />
oxides. S. Banerjee, L. Whittaker,<br />
C. J. Patridge, S. W. Depner,<br />
J. M. Velazquez, K. R. Kort<br />
2:10 415. Nanomaterials for energy storage.<br />
M. Whittingham<br />
2:40 416. <strong>Chemical</strong> strategies in nanoscience.<br />
S. S. Wong<br />
3:10 Intermission<br />
3:25 417. Using local structural probes to<br />
understand and optimize the functioning<br />
of lithium ion battery materials. B. Key,<br />
R. Bhattacharyya, N. Trease, C. P. Grey<br />
3:55 418. Nanomaterials composed of<br />
nanocomponents: Nanoparticle supercrystals<br />
and hybrids. I. P. Herman<br />
4:25 419. Discovery and characterization of<br />
novel materials for electrical energy generation<br />
and storage: Fuel cells, batteries<br />
and super-caps. H. D. Abruña<br />
4:55 Concluding Remarks<br />
Section C<br />
Boston Convention & Exhibition Center<br />
Room 258B<br />
Ligand Design and Metal Behavior<br />
M. Millar, S. Koch, Organizers<br />
L. Doerrer, Organizer, Presiding<br />
1:30 420. Monobridged, binuclear metallacycles<br />
supported by third generation<br />
bis(1-pyrazolyl)methane ligands: Unusual<br />
magnetic properties. D. L. Reger,<br />
E. A. Foley, R. P. Watson, A. E. Pascui,<br />
M. D. Smith<br />
2:00 421. Design of phosphine ligands for<br />
electrocatalytic carbon dioxide reduction<br />
and formate oxidation. D. DuBois,<br />
B. Boro, J. Linehan, J. Roberts, B. Galan,<br />
J. Schoffel, C. Kubiak<br />
2:30 422. Bimetallic cooperativity in catalysis<br />
based on a binuclating tetraphosphine<br />
ligand. G. G. Stanley, D. Polakova,<br />
A. R. Barnum, C. T. Alexander,<br />
Z. S. Wilson, M. A. Peterson<br />
3:00 Intermission<br />
3:10 423. Evolution from TMPA (� TPA) in<br />
copper-dioxygen and heme-copper-dioxygen<br />
coordination chemistry.<br />
K. D. Karlin<br />
3:50 424. Construction and properties of<br />
binuclear Ni-Fe complexes in relation to<br />
the active site of Ni-Fe-S carbon monoxide<br />
dehydrogenase. D. Huang,<br />
R. H. Holm<br />
4:20 425. Coordination chemistry with trisphenolate,<br />
thiolate, and selenolate amine<br />
and phosphine tripod ligands. S. A. Koch<br />
4:50 426. Ligand design elements that promote<br />
generation of high-valent nonheme<br />
iron-oxo species. L. Que, Jr.<br />
Section E<br />
Boston Convention & Exhibition Center<br />
Room 257A<br />
Bioinorganic Chemistry<br />
M. Millar, S. Koch, Organizers<br />
A. Valentine, J. Wilker, Presiding<br />
1:30 427. Active site of particulate methane<br />
monooxygenase. R. Balasubramanian,<br />
S. M. Smith, M. A. Culpepper, S. Rawat,<br />
L. A. Yatsunyk, T. L. Stemmler,<br />
A. Rosenzweig<br />
2:10 428. Bioinorganic approaches to renewable<br />
energy catalysis. C. J. Chang<br />
2:30 429. Synthesis and reactivity of manganese<br />
and iron complexes with methylated<br />
derivatives of bis(2-pyridylmethyl)-<br />
1,2-ethanediamine (bispicen).<br />
C. M. Coates, K. Hagan, C. A. Mitchell,<br />
C. R. Goldsmith<br />
2:50 430. Titanium in the environment: Siderophore<br />
coordination and photoreactivity.<br />
K. L. Batchler, K. E. Cole,<br />
A. M. Valentine<br />
3:10 431. Development of multifunctional<br />
small molecules as chemical tools and<br />
potential therapeutics for Alzheimer’s disease.<br />
M. Lim<br />
3:30 432. Escaping the octopus-like grasp<br />
of iron-oxygen chemistry: Studies on marine<br />
biological materials. J. D. White,<br />
C. R. Matos-Perez, J. R. Burkett,<br />
A. O. Mattes, T. W. McCarthy,<br />
J. J. Wilker<br />
3:50 433. Recognition of Zn 2� by the conjugates<br />
of calixarenes and carbohydrates<br />
and the role of the corresponding complex<br />
in biorelevant systems. C. P. Rao<br />
4:10 434. Development of caged-complexes<br />
for studying signaling and homeostasis of<br />
metal ions. S. C. Burdette<br />
4:30 435. Comparison of the reactivity<br />
chemistry of mononuclear and binuclear<br />
non-heme ferrous complexes with oxygen,<br />
peroxides, and oxygen atom donor<br />
molecules. J. P. Caradonna<br />
Section F<br />
Boston Convention & Exhibition Center<br />
Room 257B<br />
Inorganic Catalysts<br />
B. Donovan-Merkert, Organizer<br />
N. Abrams, Presiding<br />
1:30 436. Studies of the effects of hydrogen<br />
with the hopes of improving the catalytic<br />
reduction of dinitrogen to ammonia at a<br />
single molybdenum center. B. S. Hanna,<br />
R. R. Schrock<br />
1:50 437. Cross-coupling with tricarbonylchromium-coordinated<br />
benzyllithiums: A<br />
new approach to polyarylmethane derivatives.<br />
G. I. McGrew, J. Temaismithi,<br />
P. J. Carroll, P. J. Walsh<br />
2:10 438. One-pot synthesis of catalytically<br />
stable and active nanoreactors: Encapsulation<br />
of size-controlled nanoparticles<br />
within a hierarchically macroporous core<br />
@ordered mesoporous shell system.<br />
B. Su,X.Yang<br />
2:30 439. Investigation of nanostructured<br />
mixed monolayer protected nanoparticles<br />
as catalytic platforms. A. Ghosh,<br />
S. Basak, B. H. Wunsch, R. Kumar,<br />
F. Stellacci<br />
2:50 440. Spinel-type cobalt-manganesebased<br />
mixed oxide as sacrificial catalyst<br />
for the high yield synthesis of homogeneous<br />
carbon nanotubes. J. Tessonnier,<br />
M. Becker, W. Xia, F. Girgsdies,<br />
R. Blume, L. Yao, D. Su, M. Muhler,<br />
R. Schlögl<br />
3:10 441. Structures and reaction mechanisms<br />
of propene oxide isomerization to<br />
propanal on H-FER zeolite: A theoretical<br />
study using the newly developed density<br />
functional theory. B. Boekfa, T. Maihom,<br />
S. Wannakao, K. Bobuatong,<br />
J. Limtrakul<br />
3:30 442. Reaction mechanisms of ethene<br />
formation via ethanol dehydration catalyzed<br />
by Fe-ZSM-5 zeolite: An ONIOM<br />
study with an M06-L functional.<br />
T. Maihom, B. Boekfa, S. Wannakao,<br />
J. Limtrakul<br />
3:50 443. Spinel ferrite nanoparticles as selective<br />
microwave absorbers for heterogeneous<br />
oxidation catalysis.<br />
M. Thompson, P. Chem,<br />
L. J. van de Burgt, A. E. Stiegman<br />
4:10 444. Novel oxynitride compounds from<br />
cellulose biotemplates. A. Levine,<br />
J. M. MCEnaney, N. M. Abrams<br />
4:30 445. Synthesis of different CeO 2 structures<br />
on mesoporous silica and characterization<br />
of the reduction properties and<br />
the catalytic behavior. J. Strunk,<br />
W. C. Vining, A. T. Bell<br />
4:50 446. Investigation on the contradictory<br />
gas sensing behaviors of semiconducting<br />
ZnO and Zn 2SnO 4 single crystalline<br />
nanowires arrays. A. Cai<br />
Section G<br />
Boston Convention & Exhibition Center<br />
Room 256<br />
Nanoscience<br />
Optoelectronic Characterization<br />
S. Wong, Organizer<br />
S. Lee, Presiding<br />
1:30 447. Photo-induced electron transfer in<br />
chromophore-functionalized quantum<br />
sized gold clusters. K. Kwak,<br />
M. Devadas, H. Lee, G. Ramakrishna,<br />
D. Lee<br />
1:50 448. Fluorophore functionalized metal<br />
clusters. M. Devadas, D. Lee, E. Sinn<br />
2:10 449. Upconversion luminescence and<br />
X-ray-excited optical luminescence<br />
(XEOL) of lanthanide doped Yttrium oxide<br />
nanocrystals. I. N. Stanton, J. A. Ayres,<br />
M. J. Therien<br />
2:30 450. Ab initio study of multiple exiton<br />
generation (MEG) in quantum dots.<br />
Z. Zhang, P. Zimmerman, C. Musgrave<br />
2:50 451. Surface-enhanced Raman spectroscopy<br />
with silver nanocube dimers:<br />
Experiment and calculation. S. Lee,<br />
G. S. Lang, L. Hung, J. E. Cornett,<br />
I. D. Mayergoyz, O. Rabin<br />
3:20 Intermission<br />
3:40 452. Solar energy conversion with selforganized<br />
regular arrays of S-doped TiO 2<br />
nanotubes. Y. Shin, S. Lee<br />
4:10 453. Probing dynamics of photoinduced<br />
charge transfer in heterodimers<br />
composed of CdSe/ZnS quantum dots<br />
and fullerene derivatives by single molecule<br />
spectroscopy. M. Cotlet,Z.Xu<br />
4:30 454. Single-molecule optical detection<br />
of nitroaromatic compounds by carbon<br />
nanotubes. D. A. Heller, G. W. Pratt,<br />
J. Zhang, N. Nair, A. J. Hansborough,<br />
A. A. Boghossian, N. F. Reuel,<br />
P. W. Barone, M. S. Strano<br />
4:50 455. Exciton antennae and concentrators<br />
from core-shell and corrugated carbon<br />
nanotube filaments of homogeneous<br />
composition. J. Han, G. L. Paulus,<br />
R. Maruyama, D. A. Heller, W. Kim,<br />
P. W. Barone, C. Lee, J. Choi, M. Ham,<br />
C. Song, C. Fantini, M. S. Strano<br />
5:10 456. Anomalously large reactivity of<br />
single graphene layers and edges toward<br />
electron transfer chemistries. R. Sharma,<br />
J. Baik, C. Perera, M. S. Strano<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Room 258A<br />
Commemoration of the Founding of the<br />
ACS Journal Organometallics<br />
Synthesis and Catalysis<br />
D. Lichtenberger, Organizer, Presiding<br />
2:00 457. Efficient iron catalyst for the chemoselective<br />
hydrogenation of aldehydes<br />
and ketones. C. P. Casey,H.Guan,<br />
A. C. Atesin<br />
2:30 458. Multiheterometallic transition<br />
metal complexes: Going for records.<br />
H. Lang<br />
3:00 459. Custom polyethylene by molecular<br />
design. J. C. Stevens<br />
3:30 460. Some memories and then some<br />
new chemistry of single walled carbon<br />
nanotubes. M. L. Green<br />
4:00 Close of symposium D. Seyferth,<br />
J. Gladysz<br />
Section D<br />
Boston Convention & Exhibition Center<br />
Room 259A/B<br />
Main Group Chemistry<br />
B. Donovan-Merkert, Organizer<br />
J. J. Weigand, Presiding<br />
2:00 461. Lewis acidic properties of a bifunctional<br />
stibonium/borane. C. R. Wade,<br />
F. P. Gabbaï<br />
2:20 462. Use of group 6 carbonyl reagents<br />
to stabilize phosphonium and siliconium<br />
cationic species. J. M. Beres,<br />
A. M. Leigh, M. J. Panzner, V. Scionti,<br />
B. D. Wright, C. Wesdimiotis,<br />
W. J. Youngs, C. A. Tessier<br />
2:40 463. Phosphorus-containing<br />
calix[5]arene metal complexes: Catalysis<br />
and a rare � 6 palladium geometry.<br />
B. Rios, M. Lattman<br />
3:00 Intermission<br />
3:10 464. Heavy atom effects in thienyl<br />
BODIPY systems. K. Kim, T. Jun,<br />
S. Khatua, S. Choi, D. G. Churchill<br />
3:30 465. Capturing In � monomers in a neutral<br />
weakly coordinating environment.<br />
T. Jurca, S. I. Gorelsky, I. Korobkov,<br />
G. P. Yap, D. S. Richeson<br />
3:50 466. Transition metal-like behavior of<br />
mercury in a dinuclear complex featuring<br />
a mercury3antimony interaction. T. Lin,<br />
C. R. Wade, F. P. Gabbaï<br />
4:10 467. Formation of cationic phosphorus<br />
clusters by insertion of phosphenium cations<br />
into P-P bonds of the P 4 tetrahedron.<br />
J. J. Weigand, M. H. Holthausen<br />
TUESDAY EVENING<br />
Section A<br />
Boston Convention & Exhibition Center<br />
Hall C<br />
Inorganic Chemistry<br />
M. Millar, Organizer<br />
7:00–9:00<br />
468. Synthesis of biologically relevant manganese<br />
clusters by reductive aggregation.<br />
W. Lo, S. Vaddypally, P. Müller,<br />
W. H. Armstrong<br />
469. Trinuclear manganese complexes relevant<br />
to Photosystem II. S. Vaddypally,<br />
W. Lo, L. Greb, W. H. Armstrong<br />
470. Influence of platinum-based anticancer<br />
agents on nucleosome mobility. G. Zhu,<br />
S. J. Lippard<br />
471. Elucidation of the reactivity of nitric oxide<br />
with polypyrridyl copper(II) complexes.<br />
J. Rosenthal, J. Kozhukh,<br />
S. J. Lippard<br />
472. Visualization of endogenous nitric oxide<br />
in live cells using cell-trappable fluorescent<br />
probes. M. D. Pluth, L. E. McQuade,<br />
S. J. Lippard<br />
473. Pt(IV) encapsulated PLGA-PEG nanoparticles<br />
for targeting integrins in tumors.<br />
N. J. Graf, N. Kolishetti, D. R. Bielenberg,<br />
O. C. Farokhzad, S. J. Lippard<br />
474. Thermodynamic studies of DNA duplexes<br />
containing the spiroiminodihydantoin<br />
lesion. E. R. Jamieson,<br />
F. Chinyengetere, M. Dwarakanath,<br />
M. Ng, M. Thida, C. Gao, M. Martei<br />
475. Solid state coordination chemistry: Organic-inorganic<br />
hybrid materials constructed<br />
from copper 5-(4�-pyridyl)tetrazole<br />
networks with embedded molybdate<br />
clusters. S. Jones,H.Liu,<br />
C. C. O’Connor, J. Zubieta<br />
The official technical program<br />
for the 240th National Meeting<br />
is available at:<br />
www.acs.org/boston2010<br />
INOR<br />
TECH–67