Hindi - Himachal Pradesh

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(b) Polymerization: Mechanisms: Addition, Step Growth and Coordinationpolymerization, Methods: Bulk, suspension, interfacial condensation and emulsionpolymerization.(c) Properties of polymers: Glass transition temperature, crystallinity, molecular weight,Polymer solutions and their thermodynamic properties, Determination of molecularweights by sedimentation, light scattering, osmotic pressure, viscosity, end groupanalysis methods.(d) Commercial polymers: Poly (methyl methacrylate), Polycarbonate, Teflon, silicones,fire retardant polymers.(e) New concepts in polymers: Biomaterials, Polymer catalysts, reagents and substrates,and Conducting polymers.6. Synthetic uses of reagents:OsO 4 , HIO 4 , Pb(OAc) 4 , Hg(OAc) 2 , SeO 2 , B 2 H 6 , Na-Liquid NH 3 , LiAlH 4 , NaBH 4 , n-BuLiand NBS.7. Photochemistry:General concepts of photochemistry: Jablonski diagram; Norrish-Type I and Type IIreactions; Paterno-Buchi Reaction, Barton reactions, Photo Fries rearrangement.8. Principles of spectroscopy and applications in structure elucidation:(a) UV-visible spectra: electronic excitation; simple chromophoric groups, application toconjugated and extended conjugated systems, solvent effects, stereochemistry,Woodward-Fisher rules, application of UV-visible spectroscopy.(b) Infra red spectroscopy: Molecular vibration, Absorption of common functionalgroups, Applications of IR.(c) Nuclear magnetic resonance: Theory of nuclear magnetic resonance, Relaxationphenomenon, Chemical shift; Shielding mechanism, Spin-spin splitting, Chemicalexchange, Double resonance, Applications of 1 H NMR.(d) Mass spectrometry: Principle of mass spectrometry, Different modes of ionization,Metastable peak, Factors affecting fragmentation of simple organic molecules,McLafferty rearrangement, Nitrogen rule.9 Modern Concept in Chemistry:Basic concepts of Green chemistry, Supramolecular chemistry, Combinatorial chemistry.CIVIL ENGINEERINGPAPER-ITheory and design of structures:Strength of Materials - Simple Stress and Strain, Elastic constants, Principle stresses &strains in two dimensions, Theories of failures, Mohr circle, axially loaded compressionmembers, Shear force and bending moment, theory of simple bending, Shear Stressdistribution across cross sections, Beams of uniform strength.Structural Analysis- Principle of superposition, reciprocal theorem, unsymmetricalbending, columns and struts, Analysis of determinate and indeterminate structures, simpleand space frames, degrees of freedom, virtual work, energy theorems, deflection oftrusses, redundant frames, three moments equation, slope & deflection method, momentdistribution method, column analogy & energy methods, Matrix method of analysis,stiffness and flexibility matrix & Elements of plastic analysis. Analysis of determinate and
indeterminate arches, spandrel braced arches. Moving loads - influence lines for simpleand continuous beams and frames.Steel Design - Factors of safety and load factor, Welding, riveting & bolting, design oftension, compression and flexural members, built up beams and plate girders, semi-rigidand rigid connections, Design of stanchions, slab and gusted bases, crane and gantrygirders, roof trusses, water tanks. Plastic design of continuous frames and portals.R.C.C. Design – Working stress method – Design of beams, slabs, columns & staircases.Limit state method - Design of one way and two way rectangular slabs, simple andcontinuous beams, columns, stairs. footings- single and combined raft foundations,elevated water tanks, encased beams and columns, Design of retaining, counter fort &breast walls.Methods and system of prestressing, anchorages losses in prestress, design of prestressedgirders and beams.Building Construction:Building materials and construction- timber, stone, brick, sand, surkhi, mortar, concrete,paints and varnishes, plastics. Detailing of walls, floors, roofs and ceilings, staircases,doors and windows, plastering, jointing, painting, use of building codes, ventilation, airconditioning, lighting and acoustics. Building estimates and specification, constructionscheduling- PERT and CPMSoil Mechanics and Foundation Engineering:Soil Mechanics- classification of soil, atterberg’s limits, void ratio, moisture contents,permeability, laboratory and field tests, seepage and flownets, flow under hydraulicstructures, uplift and quick sand condition, unconfined and direct shear tests, triaxial test,earth pressure theories, stability of slopes, theories of consolidation, rate of settlement,total and effective stress analysis, pressure distribution in soils, Boussinasque andWestergaard’s theories, soil stabilization.Foundation Engineering- Bearing capacity of footings, piles and wells, design of retainingwalls, sheet pile and caissons.PAPER-IISurvey and Transportation Engineering:Survey: Common methods of distance and angle measurements, plane table survey,levelling, traverse survey, triangulation survey, corrections and adjustments, contouring,topographical map, surveying instruments, Tachometry, Circular & transition curves,Principles of Photogrammetry, Principles of Remote sensing and GIS.Highways- classification of roads, planning, geometric design of highways, highwaymaterials, flexible and rigid pavements, Traffic engineering and traffic surveys,intersection and road signs, signals and markings, Road drainage- culverts & smallbridges, transportation system design.Railways- permanent way, ballast, sleeper, chairs and fastening, points and crossing,different types of turnouts, cross-overs, setting out of points, maintenance of track, superelevation, creep of rail, ruling gradients, track resistance, tractive effort, curve resistance,station yards, signals and interlocking, Railway crossing.Fluid Mechanics and Hydraulic Engineering:
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Hindi - Himachal Pradesh

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