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Since chemical products have high pu‐<br />

rity and corrosiveness, corrosion protection and<br />

prevention is very important. The popular types<br />

of chemical tanker plate material is made from<br />

special types of stainless steel with a high resis‐<br />

tant <strong>to</strong> corrosion from acid. Stainless steel used<br />

for bulkheads can be solid stainless steel or mild<br />

steel clad with stainless steel. Rubber is some‐<br />

times used <strong>to</strong> line tanks carrying products<br />

mainly acids, which are unsuitable for use with<br />

stainless steel or coating. Zinc silicate is fre‐<br />

quently used in tanks designed <strong>to</strong> carry alcohol<br />

as well as some types of solvents and other<br />

chemicals. It is necessary <strong>to</strong> inspect zinc coated<br />

bulkhead after they have been dried <strong>to</strong> ensure<br />

the coating has not been softened or otherwise<br />

damaged.<br />

The requirement for coating application<br />

is under MARPOL Annex II (Regulations for the<br />

Control of Pollution by Noxious Liquid Sub‐<br />

stances). Before coating application, the steel<br />

temperature and relative air humidity in the tank<br />

are two basic fac<strong>to</strong>rs <strong>to</strong> observe in ensuring the<br />

correct coating application. The application of<br />

coating starts from the bot<strong>to</strong>m of the tank <strong>to</strong> the<br />

ceiling, because during application the evapo‐<br />

rated solvents may flow <strong>to</strong> the bot<strong>to</strong>m of the<br />

tank. Hence, the air in the tank is both renewed<br />

and dehumidified <strong>to</strong> keep clean atmosp<strong>here</strong> and<br />

steady temperature and humidity conditions.<br />

Figure 2: Application of coating<br />

<strong>MIMET</strong> Technical Bulletin Volume 1 (2) 2010<br />

The sequence of coating application also plays an<br />

important rule. If we consider a coating system of<br />

two parts (2 coatings), then we should apply the<br />

first coating <strong>to</strong> all tank surfaces for a specific dry<br />

film thickness. At this stage, as we approach the<br />

ceiling we must cover the tank bot<strong>to</strong>m <strong>to</strong> avoid any<br />

overspray.<br />

Figure 3: Coating application sequence<br />

Some cargoes are required <strong>to</strong> be carried at<br />

certain temperatures. For that reason, heating coils<br />

are installed in the cargo tanks <strong>to</strong> keep the cargo at<br />

the required temperature. The heating substance is<br />

oil or water coming from a heat exchanger, so en‐<br />

able the cargo <strong>to</strong> be carried at a desired range of<br />

temperatures (ExxonMobil, 2002). Chemical tankers<br />

must have a system for tank heating in order <strong>to</strong><br />

maintain the viscosity of certain cargoes. Typically<br />

this system consists of a boiler which pumps pres‐<br />

surized steam through so‐called “heating coils”<br />

made from stainless steel pipes in the cargo tanks,<br />

thus transferring heat in<strong>to</strong> the cargo, which circu‐<br />

lates in the tank by convection.<br />

In SOLAS Chapter II‐2, Regulation 4 Para‐<br />

graph 5.5, tankers are also required <strong>to</strong> be fitted with<br />

an inert gas system. With the inert gas system, the<br />

protection against a tank explosion is achieved by<br />

keeping the oxygen content low. It will reduce the<br />

hydrocarbon gas concentration of tank atmosp<strong>here</strong><br />

<strong>to</strong> a safe proportion. The problem is that impurities<br />

such as carbon and moisture are normally present<br />

in flue gases and it is difficult <strong>to</strong> use a conventional<br />

inert gas system with some chemical.<br />

| MARINE FRONTIER @ <strong>UniKL</strong><br />

115

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