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25th International Meeting on Organic Geochemistry IMOG 2011

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O-50<br />

Bey<strong>on</strong>d Orgas- BP’s new predictive model for biogenic and<br />

thermogenic gas expulsi<strong>on</strong> from source rocks<br />

Mark Osborne, T<strong>on</strong>y Barwise<br />

BP Explorati<strong>on</strong> Operating Co Ltd, Sunbury-<strong>on</strong>-Thames, United Kingdom (corresp<strong>on</strong>ding<br />

author:Mark.Osborne@uk.bp.com)<br />

BP‘s ‗Orgas‘ kinetic scheme, was created in the<br />

1980‘s-early 1990‘s to predict the oil and gas volume<br />

expelled from different source rock<br />

organofacies[1,2,3]. The global kinetic model<br />

assigned kinetic parameters based <strong>on</strong> gross<br />

depositi<strong>on</strong>al envir<strong>on</strong>ment and stratigraphic age-<br />

useful in areas of low geochemical knowledge<br />

including fr<strong>on</strong>tier explorati<strong>on</strong>. The published scheme<br />

has been implemented in most commercially available<br />

basin modelling tools, becoming widely used<br />

throughout the petroleum industry to the present day.<br />

While Orgas is still c<strong>on</strong>sidered to be technically<br />

robust and pragmatic, BP has recently made<br />

improvements to the scheme to provide enhanced<br />

pre-drill predicti<strong>on</strong>s of the volume, compositi<strong>on</strong> and<br />

physical properties of expelled petroleum fluids. This<br />

informati<strong>on</strong> is important for understanding the likely<br />

quality, value and volume of petroleum fluid that may<br />

be present in a basin or prospect, for both<br />

c<strong>on</strong>venti<strong>on</strong>al or unc<strong>on</strong>venti<strong>on</strong>al play types (e.g. shale<br />

gas, coal bed methane, biogenic).<br />

With regards to modelling of gas expulsi<strong>on</strong>, the<br />

modificati<strong>on</strong>s to our proprietary scheme fall into three<br />

main categories:<br />

1) Modelling of both biogenic (bacterial) and<br />

thermogenic gas generati<strong>on</strong> and expulsi<strong>on</strong>. Our work<br />

suggests biogenic gas is generated from typical<br />

source rocks, as well as leaner sediments. Biogenic<br />

and thermogenic gas should not be modelled<br />

separately- they are part of the c<strong>on</strong>tinuum of fluid<br />

types that are generated during burial of most source<br />

rocks (Fig 1).<br />

2) A revised model for gas adsorpti<strong>on</strong> and retenti<strong>on</strong>.<br />

Both adsorpti<strong>on</strong> of gas <strong>on</strong> kerogen and retenti<strong>on</strong> in<br />

porosity are important factors c<strong>on</strong>trolling whether gas<br />

remains trapped in a source rock or is expelled from<br />

it. The old Orgas scheme c<strong>on</strong>sidered <strong>on</strong>ly adsorpti<strong>on</strong>.<br />

The new model is critical for the correct evaluati<strong>on</strong> of<br />

shale gas plays.<br />

3) Predicti<strong>on</strong> of the isotopic compositi<strong>on</strong> of the<br />

expelled gases. As biogenic and then thermogenic<br />

gas is generated and becomes mixed in the source,<br />

the expelled gas isotopic compositi<strong>on</strong> systematically<br />

evolves in a predictable manner. This model is<br />

c<strong>on</strong>sistent with global observati<strong>on</strong>s from isotube data<br />

collected from explorati<strong>on</strong> wells.<br />

Collectively these three modificati<strong>on</strong>s produce more<br />

realistic assessments of gas expelled from (and<br />

retained within) source rocks<br />

Fig. 1. An example of biogenic and thermogenic<br />

expulsi<strong>on</strong> rates and their variance with source rock<br />

thermal stress<br />

References<br />

[1] Pepper AS and Corvi PJ. Simple Kinetic Models of<br />

Petroleum Formati<strong>on</strong>: Oil and Gas Generati<strong>on</strong> from<br />

Kerogen. Marine and Petroleum Geology 12 (1995):<br />

291-319.<br />

[2] Pepper AS and Corvi PJ. Simple Kinetic Models of<br />

Petroleum Formati<strong>on</strong>: Modelling an Open System.<br />

Marine and Petroleum Geology 12 (1995): 417-452.<br />

[3] Pepper AS and Dodd TA. Simple Kinetic Models of<br />

Petroleum Formati<strong>on</strong> Part II: oil-gas cracking. Marine<br />

and Petroleum Geology 12 (1995): 321-340.<br />

110

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