24.02.2013 Views

25th International Meeting on Organic Geochemistry IMOG 2011

25th International Meeting on Organic Geochemistry IMOG 2011

25th International Meeting on Organic Geochemistry IMOG 2011

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

P-123<br />

<strong>Organic</strong> matter characteristics of Bazhenov Formati<strong>on</strong> in the<br />

central part of the West-Siberian basin based <strong>on</strong> biomarker<br />

parameters and pyrolysis<br />

Enver Ablya, Elena K<strong>on</strong><strong>on</strong>chenko<br />

Moscow State University, Moscow, Russian Federati<strong>on</strong> (corresp<strong>on</strong>ding author:lena.k<strong>on</strong><strong>on</strong>@mail.ru)<br />

Bazhenov Formati<strong>on</strong> (BF) (J3) is just 20m thickness<br />

but it is believed a main source rock in the West-<br />

Siberian basin. It is heterogeneous <strong>on</strong> the area. There<br />

is a central part in its structure which is characterized<br />

by high c<strong>on</strong>tent of organic matter. It is c<strong>on</strong>sidered that<br />

in the central part of the basin BF is presented mainly<br />

by bazhenovites which have TOC reaching to 25%<br />

(<strong>on</strong> the average more than 7-10 %).<br />

In this work it is shown that the structure of BF<br />

organic matter (OM) is more difficult than it was<br />

represented earlier. As an object of research there<br />

were samples from BF at close area of the central<br />

part. Studying of c<strong>on</strong>diti<strong>on</strong>s of accumulati<strong>on</strong> and<br />

transformati<strong>on</strong> of OM was a research objective.<br />

Macroscopic descripti<strong>on</strong> of core, pyrolysis by Rock-<br />

Eval and GC-MS have been carry out. It has been<br />

established (fig.) presence of two extremely different<br />

types of organic matter (including degree of maturity).<br />

The first type (1) is characterized by low Pr/Ph,<br />

abnormal high c<strong>on</strong>tent of C27 steranes in comparis<strong>on</strong><br />

with С29, also high ratio t23/t24 (tricyclic terpanes)<br />

that indicates enough deep-water c<strong>on</strong>diti<strong>on</strong>s of<br />

sedimentati<strong>on</strong>. It is possible to interpret high<br />

Dibenzotiofene/Phenantrene index as a sign of low<br />

Eh. Together with the pyrolysis data (high HI) this<br />

type of organic matter can be carried to the typically<br />

marine. The sec<strong>on</strong>d type (2) of organic matter has<br />

opposite characteristics and also higher c<strong>on</strong>centrati<strong>on</strong><br />

of gammacerane that speaks about c<strong>on</strong>diti<strong>on</strong>s of the<br />

high salinity. This type can be named terrigenous.<br />

Different degree of maturity of two types is very<br />

interesting. For the first type maturity is relatively high<br />

according to the Ts/Tm and �� sterane ratios, for the<br />

sec<strong>on</strong>d type (terrigenous) it is much lower (very low<br />

Ts/Tm and �� sterane ratios, the presence of<br />

moretanes). However, according to Rock-Eval data<br />

(Tmax), which always gives the average rate, maturity<br />

is near. Thus, we have two types of organic matter<br />

with different degrees of transformati<strong>on</strong>, and possibly<br />

generated different hydrocarb<strong>on</strong>s, but, nevertheless,<br />

passed virtually the same thermal history.<br />

Terrigenous type formed apparently under intensive<br />

influence of adjacent c<strong>on</strong>tinent that early thought is<br />

not typical for the central part of the basin. In the<br />

neighbouring areas z<strong>on</strong>es of distributi<strong>on</strong> of abnormal<br />

BF have been identified (thickness up to 100 m, with<br />

Mass chromatogram m/z 191<br />

seams of sandst<strong>on</strong>es).<br />

Them<br />

genesis is<br />

associated with<br />

descent of<br />

turbidites flows<br />

from the c<strong>on</strong>tinent.<br />

In the<br />

study area<br />

normal BF is<br />

distributed. However,<br />

descent of<br />

turbidites in<br />

adjacent areas<br />

can affect the<br />

formati<strong>on</strong> of it.<br />

265

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!