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25th International Meeting on Organic Geochemistry IMOG 2011

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P-192<br />

Climate variability in the Lake Victoria regi<strong>on</strong> (East Africa) since<br />

the Late Pleistocene as shown by molecular biomarkers<br />

Melissa Berke 1 , Josef Werne 2 , Thomas Johns<strong>on</strong> 1 , Kliti Grice 3 , Stefan Schouten 4 , Jaap<br />

Sinninghe Damsté 4<br />

1 Large Lakes Observatory & Department of Geological Sciences, University of Minnesota Duluth, Duluth,<br />

United States of America, 2 Large Lakes Observatory & Department of Chemistry and Biochemistry,<br />

University of Minnesota Duluth, Duluth, United States of America, 3 Department of Chemistry, Curtin<br />

University, Perth, Australia, 4 Royal NIOZ, Department of Marine <strong>Organic</strong> Biogeochemistry, Den Burg,<br />

Netherlands (corresp<strong>on</strong>ding author:berk0135@umn.edu)<br />

Recent organic geochemical advances have<br />

facilitated the comparis<strong>on</strong> between c<strong>on</strong>tinental<br />

temperature change, hydrologic variability, and<br />

terrestrial vegetati<strong>on</strong> resp<strong>on</strong>se. TEX86, a proxy based<br />

<strong>on</strong> the lipids of aquatic Crenarchaeota that show a<br />

positive correlati<strong>on</strong> with growth temperature, was<br />

used to rec<strong>on</strong>struct surface water temperatures from<br />

Lake Victoria, East Africa during the latest<br />

Pleistocene-Holocene. Hydrologic c<strong>on</strong>diti<strong>on</strong>s were<br />

then interpreted using compound specific δD of fatty<br />

acids from sediments and compared to hydrologic<br />

implicati<strong>on</strong>s from paleoecological data, specifically<br />

pollen and diatom assemblages found in the lake<br />

(Kendall, 1969; Stager et al., 2003). Compound<br />

specific δ 13 C data from terrestrial leaf wax biomarkers<br />

(n-alkanes) was then evaluated in order to determine<br />

how the patterns of rainfall and aridity in this regi<strong>on</strong><br />

have affected the terrestrial vegetati<strong>on</strong> in the<br />

watershed. Initial comparis<strong>on</strong>s of climatic changes<br />

seen in temperature, vegetati<strong>on</strong>, and hydrologic<br />

records appear to show some periods of c<strong>on</strong>sistency<br />

between warm/wet intervals and cool/dry intervals,<br />

which is expected for this regi<strong>on</strong>, but far less often<br />

shown. This is <strong>on</strong>e of the first studies from a tropical<br />

East African lake to compare all three of these<br />

biomarkers (TEX86, δD, and δ 13 C) in order to<br />

rec<strong>on</strong>struct a complete regi<strong>on</strong>al-scale picture of<br />

climate variability since the Late Pleistocene.<br />

Lake Victoria temperatures show a steady<br />

warming beginning 16 cal ka, with a pause around the<br />

Younger Dryas, dominated by arid c<strong>on</strong>diti<strong>on</strong>s and<br />

str<strong>on</strong>g savannah grassland development during this<br />

interval. There is c<strong>on</strong>tinued warming to a sustained<br />

thermal maximum for this porti<strong>on</strong> of the record at<br />

~10.5-8.5 ka, which generally coincides with the<br />

Northern Hemisphere summer insolati<strong>on</strong> maximum.<br />

This thermal maximum occurs during the most humid<br />

interval of this record (~9.5-8.3 ka), shown by an<br />

increase of humid forest pollen and high diatom<br />

abundance (due to increased water column mixing<br />

and nutrient runoff). Temperatures abruptly cool<br />

~1.5ºC in

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