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25th International Meeting on Organic Geochemistry IMOG 2011

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P-484<br />

Coupling of Miocene-Pliocene (7-5 Ma) African climate, surface<br />

ocean temperature and marine organic carb<strong>on</strong> burial: highresoluti<strong>on</strong>,<br />

multi-proxy records from the eastern equatorial<br />

Atlantic (ODP 959)<br />

Thomas Wagner, Olubunmi Eniola, Erin McClym<strong>on</strong>t<br />

Newcastle University, Newcastle up<strong>on</strong> Tyne, United Kingdom (corresp<strong>on</strong>ding<br />

author:thomas.wagner@ncl.ac.uk)<br />

The late Miocene to early Pliocene was a period of<br />

major climate transiti<strong>on</strong> with events that impacted <strong>on</strong><br />

large-scale ocean and atmospheric circulati<strong>on</strong> and<br />

c<strong>on</strong>sequently global climate. Tect<strong>on</strong>ic events such as<br />

the Tibetan and Himalaya uplift and the closing of<br />

ocean gateways are proposed to have caused a l<strong>on</strong>g<br />

term cooling trend and a principal change in<br />

vegetati<strong>on</strong> in the low latitudes, including a general<br />

shift from C3 vegetati<strong>on</strong> to C4 vegetati<strong>on</strong> in Africa<br />

around 8-6 Ma 1 . Large-scale hydrological changes<br />

are also recorded by carb<strong>on</strong> isotopic ratios in<br />

carb<strong>on</strong>ates and soil organic matter 2 .<br />

With regard to the tropical Atlantic corridor the<br />

establishment of modern type atmospheric and ocean<br />

circulati<strong>on</strong> at about 4.4-4.3 Ma 3 has been proposed.<br />

Further studies <strong>on</strong> ODP 959 off tropical West Africa 4<br />

showed that the late Miocene to early Pliocene<br />

climate records were modulated by cyclic high<br />

amplitude swings in TOC which were linked to the<br />

evoluti<strong>on</strong> of African trade winds, c<strong>on</strong>tinental upwelling<br />

and eustatic sea level fluctuati<strong>on</strong>s. For these<br />

sediments Norris 3 inferred cooling of surface waters<br />

by 2-3°C (6.7-5.9 Ma) and proposed the <strong>on</strong>set of<br />

modern type climate ocean dynamics ~4.4 Ma.<br />

Here, we take these previous studies further and<br />

present new complementary high-resoluti<strong>on</strong> (2.5 cm,<br />

~2.5-5 kyr) records of sea-surface temperatures<br />

(SSTs, alken<strong>on</strong>e derived U K 37‘), supply of terrestrial<br />

organic matter (leaf wax lipids) and organic carb<strong>on</strong><br />

burial (TOC) for ODP Site 959. The complementary<br />

new data provide, in combinati<strong>on</strong> with detailed<br />

frequency analyses, new insights into the causal<br />

relati<strong>on</strong>ships and trends between African climate,<br />

marine resp<strong>on</strong>se, and links with high latitude climate<br />

forcing during the critical time interval 7-5 Ma. All<br />

geochemical records show distinct high frequency<br />

(millennial time scale) fluctuati<strong>on</strong>s that argue for a<br />

highly dynamic and sensitive resp<strong>on</strong>se of the tropical<br />

Atlantic to African climate and orbital forcing. TOC is<br />

low (in general

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