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25th International Meeting on Organic Geochemistry IMOG 2011

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P-340<br />

Atypical fluids in offshore shallow buried reservoirs<br />

Denis Levaché, Christine Lafaurie, Yannick Poirier, Gérard Ségalini<br />

TOTAL Explorati<strong>on</strong> & Producti<strong>on</strong>, Pau, France (corresp<strong>on</strong>ding author:denis.levache@total.com)<br />

In (deep)offshore explorati<strong>on</strong>, shallow buried<br />

reservoirs are usually avoided due to the str<strong>on</strong>g risk<br />

of biodegradati<strong>on</strong> and c<strong>on</strong>sequently highly viscous<br />

fluids. Indeed the maximum risk of biodegradati<strong>on</strong><br />

being situated towards 40-50°C, reservoirs around<br />

900-1000m of depth are the riskiest.<br />

However recent discoveries of light fluids in reservoir<br />

at shallow depths have triggered questi<strong>on</strong>s regarding<br />

the charge and preservati<strong>on</strong> of the HC in these<br />

reservoirs.<br />

Typically these fluids have an apparent low<br />

biodegradati<strong>on</strong> level and good physical properties (i.e.<br />

low in-situ viscosities and API above 30°). Strikingly<br />

the molecular distributi<strong>on</strong> of the oil is very unusual as<br />

seen in Figure 1. Almost no n-alkane is present after<br />

n-C17/C18 where Pristane and Phytane dominate.<br />

The geochemical study <strong>on</strong> liquids by GC and GC-MS,<br />

detailed analysis of associated gases (compositi<strong>on</strong><br />

and isotope ratio measurement � 13 C and � 2 H) and<br />

mud gas analyses allow to propose a complex filling<br />

history of these reservoirs involving multiple steps:<br />

� A first phase of filling by an early charge that<br />

is quickly biodegraded in reservoirs<br />

subjected to temperatures lower than 60°C.<br />

Such fluids are usually encountered in the<br />

shallow reservoirs of these formati<strong>on</strong>s.<br />

� The sec<strong>on</strong>d phase of filling by retrograde<br />

c<strong>on</strong>densati<strong>on</strong> of a light fluid and also<br />

possibly a stripping by methane. The<br />

reservoirs cannot hold the gas phase thus<br />

generated as shown by the isotopic analysis<br />

of mud gases that indicates c<strong>on</strong>tinuous gas<br />

fluxes from deeper origin.<br />

The remaining fluid c<strong>on</strong>sists of the retrograde<br />

c<strong>on</strong>densate overprinting the initial biodegraded<br />

charge.<br />

The use of the geochemical interpretati<strong>on</strong> helps to<br />

build the proper thermodynamic model that match the<br />

behavior of these fluids in these reservoirs. The<br />

model used here involves two source rocks that have<br />

expelled at various stages of maturities. The predicted<br />

expelled fluids placed at the reservoir c<strong>on</strong>diti<strong>on</strong>s have<br />

a behavior in good agreement with the observed fluid<br />

compositi<strong>on</strong>.<br />

Norm.<br />

Finally 1400 the understanding of the presence of these<br />

gas fluxes is the main driver to predict the HC fluid<br />

quality and thus the success of a prospect in these<br />

1200<br />

shallow reservoirs.<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

0<br />

*FID1 A, (L:\POLE MOLECULAIRE\GC-ID\ANALYSES\CAMEROUN 2008\NJOM001B\165171ID.D - NOVEMBRE\BL081118.D)<br />

nC6<br />

nC5<br />

nC7<br />

nC8<br />

nC9<br />

nC10<br />

nC11<br />

nC12<br />

nC13<br />

nC14<br />

nC15<br />

0 25 50 75 100 125 150 175 200 225<br />

nC16<br />

Pr<br />

nC17<br />

nC18<br />

Ph<br />

N-alkanes depleted from nC18<br />

Fig.1 C6+ fracti<strong>on</strong> Gas Chromatography of a selected<br />

atypical oil.<br />

471<br />

min

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