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25th International Meeting on Organic Geochemistry IMOG 2011

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P-190<br />

Large scale cooling in Tertiary Central Europe as inferred by the<br />

MBT/CBT paleothermometer<br />

Thorsten Bauersachs 1 , Stefan Schouten 2 , Lorenz Schwark 1<br />

1 Christian-Albrechts-University, Kiel, Germany, 2 Royal Netherlands Institute for Sea Research, Texel,<br />

Netherlands (corresp<strong>on</strong>ding author:thb@gpi.uni-kiel.de)<br />

Earth‘s climate experienced dramatic changes<br />

throughout the last 65 Ma. Starting at the<br />

Paleocene/Eocene thermal maximum, the global<br />

climate underwent a gradual cooling that eventually<br />

resulted in the glaciati<strong>on</strong>s in the Neogene [1]. Most<br />

rec<strong>on</strong>structi<strong>on</strong>s of climate variability are derived from<br />

the marine realm using global deep sea oxygen<br />

isotope curves or molecular paleotemperature proxies<br />

[1]. In c<strong>on</strong>trast, <strong>on</strong>ly little informati<strong>on</strong> <strong>on</strong> the changes<br />

of the c<strong>on</strong>tinental climate is available, which is mainly<br />

due to a lack of c<strong>on</strong>tinuous high resoluti<strong>on</strong> records<br />

and suitable quantitative temperature proxies.<br />

The methylati<strong>on</strong> index of branched tetraethers<br />

(MBT) is a novel temperature proxy based <strong>on</strong><br />

temperature-driven changes in the membrane-lipid<br />

compositi<strong>on</strong> of presumably anaerobic soil bacteria [2].<br />

These changes correlate well with mean annual air<br />

temperature (MAAT) and the MBT proxy has thus<br />

been used to rec<strong>on</strong>struct paleotemperature records in<br />

terrestrial as well as coastal marine sediments [3].<br />

In this study, we employed the MBT Index <strong>on</strong> a<br />

number of lacustrine deposits ranging in age from the<br />

Early Eocene to the Late Oligocene in order to<br />

rec<strong>on</strong>struct climate evoluti<strong>on</strong> of the Central European<br />

c<strong>on</strong>tinent. The Messel oil shale (Germany)<br />

accumulated in a small crater lake during the Eocene<br />

climate optimum and thus allows rec<strong>on</strong>structing<br />

temperature development in a so-called green house<br />

world. Methylati<strong>on</strong> of the branched glycerol dialkyl<br />

glycerol tetraethers (GDGTs) suggests that the MAAT<br />

at time of oil shale formati<strong>on</strong> ranged from 20-32 °C<br />

over an estimated time period of ca. 1 Ma. This is in<br />

good agreement with temperature estimates based <strong>on</strong><br />

pale<strong>on</strong>tological observati<strong>on</strong>s suggesting a<br />

paratropical climate in Eocene Central Europe with an<br />

average air temperature of ca. 25-30 °C [4].<br />

In c<strong>on</strong>trast, to the green house period of the Early<br />

Eocene, the climate of the Oligocene was significantly<br />

cooler reflected by low MAAT of 8-15 °C in the<br />

lacustrine deposit of Lake Enspel (Westerwald,<br />

Germany). These MBT-derived air temperatures are<br />

similar to those previously rec<strong>on</strong>structed using floral<br />

elements of the Enspel deposit [5].<br />

Our results indicate that the paleotemperature<br />

trends of the Central European c<strong>on</strong>tinent, based <strong>on</strong><br />

the distributi<strong>on</strong> of branched GDGTs in Tertiary<br />

lacustrine deposits, resemble those previously<br />

obtained from marine records and that the MBT proxy<br />

might be a valuable tool for rec<strong>on</strong>structing terrestrial<br />

paleoclimate records.<br />

Fig. 1. Mean annual air temperature (MAAT) rec<strong>on</strong>structed<br />

from the distributi<strong>on</strong> of branched GDGTs in (a) the Eocene<br />

Messel oil shale and (b) the Oligocene Lake Enspel deposit.<br />

References<br />

[1] Zachos et al. (2001) Science 292, 686-693<br />

[2] Weijers et al. (2007) Geoch Cosmoch Ac 71, 701-703<br />

[3] D<strong>on</strong>ders et al. (2007) EPSL 281, 215-225<br />

[4] Wilde (1989) Cour. Forsch. Senk 115, 1-213<br />

[5] Herrmann (2007) PhD Thesis, Tübingen University<br />

329

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