25th International Meeting on Organic Geochemistry IMOG 2011

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P-350 Geochemical comparison of oil samples and core extracts from Yanchang Formation in Ordos Basin, China Weiwei Yang, Guangdi Liu State Key Laboratory of Petroleum Resource and Prospecting in China University of Petroleum, Beijing, China (corresponding author:yangweiwei_850101@yahoo.com.cn) Geochemical analysis of core extracts is often in place of oil samples for oil-source correlation and exploration when no tested or produced oil samples are available. The geochemical characteristics of solvent extraction from cores and tested or produced oil are similar, but some differences have been observed between them (Horstad et al., 1990; Larter and Aplin, 1995; Stoddart et al., 1995; Baylis, 1998; Jianhui Feng et al. 2003). In order to identify the differences, a geochemical study was carried out to compare the geochemical parameters obtained from the analysis of tested oil samples and reservoir cores extracts in the laboratory using GC and GCMS. In Yanchang Formation of Ordos Basin, eight tested oil samples and eleven cored reservoir samples from the same horizons were collected and analyzed from six wells. The results show that the oil samples are more enriched in lighter molecular weight components than that of the core extracts, with the C21-/C22+ ratios ranging from 2.1 to 3.7 much higher than those of the core extracts ranging from 0.9 to 1.3. This phenomenon is due to evaporation during cores preserved in the core storage for many years. Besides, remarkable differences are observed between the distribution patterns of terpanes for some of the oil samples and their respective core extracts samples, from the same intervals in the same wells, which demonstrates the heterogeneity of tested intervals. Some source indicators, e.g. relative contents of 17α (H)-C30 diahopanes (C30*) and tricyclic terpanes, suggest that oils from extracted reservoir cores and produced oil samples derive from different types of sources. Take the Well Bai284 (Chang8 Member) for example, the tested oil sample (1857-1862m) is lower C30* and tricyclic terpanes contents relating to the oil shale, whereas the solvent extraction from the core (1857.9m) is higher C30* and tricyclic terpanes contents relating to the black mudstone. So examination of core extracts instead of tested or produced oils may be misleading in oil-source correlation, we should take these differences into account in exploration. References [1] Baylis, S.A. (1998) Geochemical comparison of core extracts and oil samples in reservoir. Organic Geochemistry 29, 463-484 [2] Horstad, I., Larter, S. R., Dypvik, H., et al. (1990) Degradation and maturity controls on oil field petroleum column heterogeneity in the Gullfaks field, Norwegian North Sea. Organic Geochemistry 16, 497-510. [3] Jianhui, F., Yuming, T. Xiaoping, L. et al. (2003) Geochemical comparison and implications of oils, core extracts and oil-bearing fluid inclusions in reservoirs of Dongpu Depression. Geochemica 32, 591-600 [4] Larter, S.R., Aplin, A.C. (1995) Reservoir geochemistry: methods, applications and opportunities. In the Geochemistry of Reservoir, eds. Cubitt J.M., England, W.A., Geological Society Special Publication 86, 5-32 [5] Stoddart, D.P., Hall, P.B., Larter, S.R., et al. (1995) The reservoir geochemistry of the Eldfisk field, Norwegian North Sea. In the Geochemistry of Reservoir, eds. Cubitt J.M., England, W.A., Geological Society Special Publication 86, 257-279 481
P-351 The releasing of covalently-bound biomarkers via hydropyrolysis for the bitumen-source correlation of Majiang paleo-reservoir Fang Yunxin, Geng Ansong, Liao Yuhong, Wu Liangliang Guangzhou Institute of Geochemistry,Chinese Academy of Sciences, Guangzhou, China (corresponding author:asgeng@gzb.ac.cn) There are different viewpoints on the bitumensource correlation of Majiang paleo-reservoir in the Southern Guizhou Depression of China. Three potential source rocks in this depression could be inferred: the Lower-Cambrian marine mudstone, Lower-Silurian shale and Lower-Permian mudstone. Most of the potential source rocks and solid bitumens are of high maturity. The low yields of extracts from bitumens and source rocks in Majiang area can not satisfy the detection limit of analytical instruments, such as GC-MS and GC-IRMS. And the severe thermal alterations obscure oil-source correlations by routine biomarkers of extracts. Routine biomarkers in EOM of source rocks and solid bitumen, such as C27~C29-regular steranes and C31~C35 homohopanes, may be altered during maturation. Due to all these factors, it is difficult to use routine biomarkers of extracts for the bitumen-souce correlation. Catalytic hydropyrolsis refers to pyrolysis assisted by high hydrogen pressure (15 MPa) and a dispersed sulfided molybdenum catalyst, which permits covalent bond cleavage at relatively low temperature (
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25th Inter
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Dear Conference Delegates, Preface
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Monday 19 th September 2011 - Morni
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Monday 19 th September 2011 - After
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Tuesday 20 th September 2011 - Afte
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Wednesday 21 st September 2011 - Mo
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Wednesday 21 st September 2011 - Af
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13.40 - 15.05 Poster Session 4 (In
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Friday 23 rd September 2011 - Morni
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Poster Sessions (in Kongress-Saal)
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P-026 Comparison of comprehensive t
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P-052 Incorporation of Archaeal and
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P-081 Geochemical evidence for two
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P-108 Organic geochemistry and Meso
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P-133 Can we estimate catchment-sca
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P-157 Can laterally advected interm
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P-182 The influence of hydrogen on
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P-207 Biomarkers along a holocene s
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P-232 Some experimental results on
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P-261 Natural gas generation, migra
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P-288 Re/Os fractionation during ge
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P-314 Chemometric analysis of oil-o
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P-340 Atypical fluids in offshore s
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P-366 Organic geochemical character
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P-392 Environmental forensic study
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P-416 Developing analytical protoco
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P-442 Deep-sea benthic archaea recy
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P-464 Effects of within-catchment p
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Poster Session 4 - Thursday 22 nd S
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Monday Oral Presentations 58
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O-02 Melting history of West Antarc
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O-04 Insights about the marine nitr
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O-06 Eocene out-of-India dispersal
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O-08 An integrated lipid biomarker
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O-10 Sulfur species as facilitators
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O-12 Sulfur isotope systematic of i
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O-14 Exploring the diversity of arc
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O-16 Improved genetic characterizat
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O-18 Petroleum system analysis Sout
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O-19 The borolithochromes: boron-co
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O-21 Study of the stable isotopic c
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O-23 Novel applications of trace me
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O-25 The chemical structure of inso
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O-27 Coenzyme factor 430: abundance
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O-29 Influence of temperature on me
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O-31 The fate of collembola derived
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O-33 Empirical relationship between
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O-35 Biomarker evidence for the Lat
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O-37 The seco-oleananes: identifica
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O-38 Microbial communities associat
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O-40 The importance of geochemical
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O-42 Charge history and petroleum g
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O-44 Bacterial formation of (di)eth
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O-46 Development of a novel tool fo
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O-48 Evolution of petroleum composi
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O-50 Beyond Orgas- BP’s new predi
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O-52 Nitrogen isotopes of amino aci
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O-54 Biomarker and petrographic evi
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O-55 The organic geochemistry of ca
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O-57 Exploring mass extinction even
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O-59 Black shale formation by micro
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O-61 The significant impact of weat
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O-63 Simultaneous shifts in tempera
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O-65 Fluxes and isotope composition
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O-67 Biogeochemical impact of CO2 e
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Bacteria number ml-1 Bacteria numbe
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O-71 Aquathermolysis: pressure effe
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O-73 Designing tight-shale producti
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O-74 Tracing 13C-labeled inorganic
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O-76 Carbon fluxes in phylogenetica
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O-78 Fluid property prediction from
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O-80 Denitrifying bacteria as poten
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O-82 Tetraether lipid profiles in c
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O-84 Prediction of gas volume and d
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Monday Poster Presentations 148
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P-002 Structure and function of asp
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P-004 Preliminary study of acid deg
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P-006 Chemical and geochemical char
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P-008 High resolution measurement o
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P-010 Acidic fraction analyses of B
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P-012 Heteroatom-containing compoun
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P-014 Evaluation of hydropyrolysis
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P-016 Iron isotopic compositions of
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P-018 Evaluation of accelerated sol
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P-020 Improvement of HPLC-protocols
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P-022 Open-system hydrous pyrolysis
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P-024 The phenolic characterisation
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P-026 Comparison of comprehensive t
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P-028 Characterisation of lignin de
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P-030 Trace analysis of methylated
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P-033 An evaluation of petroleum so
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P-035 Contrasting macromolecular or
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P-037 Evolution of depositional env
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P-039 Organic carbon content and ch
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P-041 Organic geochemistry of entra
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P-043 Petrological and organic geoc
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P-045 Occurrence and geochemical ch
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P-047 Characterization of lignites
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P-049 Organic matter of Lower Permi
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P-051 Kerogen sulphur, hydrogen and
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P-053 Sulfur-bound compounds in fre
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P-055 Organic matter preservation i
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P-058 Characterization of aromatic
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P-060 Biomarkers parameters used to
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P-063 Origin of crude oil with high
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P-065 Molecular maturation of Bitum
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P-067 C21-C23 steroidal tricyclic t
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P-069 The age and palaeoenvironment
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P-071 Structural characterization o
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P-074 Discussion on appliance of 25
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P-076 Lanostanes as the new biomark
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P-079 Geochemistry of ―just gener
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P-081 Geochemical evidence for two
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P-083 Thermal maturity assessment o
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P-085 Flash pyrolysis-gas chromatog
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P-087 Petroleum geochemistry of the
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P-089 Addressing thermogenic and bi
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P-091 Investigation of oil stabilit
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P-093 Organic geochemistry, petrole
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P-095 Natural petroleum fractionati
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P-097 Geochemistry of low-boiling
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P-099 Oxygen-containing compounds i
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P-101 Formation of giant deep-burie
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P-103 Geochemical characteristics o
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P-105 Challenges on the origin of o
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P-107 Caldera of the Uzon volcano a
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P-109 A saga on organic geochemistr
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P-111 An integrated inorganic and o
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P-114 Hydrocarbon generation potent
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P-116 Marine transgressional event
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P-118 The cracking kinetics of two
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P-120 The generation potential of t
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P-122 Organic geochemical character
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P-124 Compositional features of org
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P-126 The value of generation hydro
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P-128 Investigation of fish pond ma
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P-130 Bituminous mixtures of Hakemi
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P-132 Combined � 13 C - �D anal
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P-134 Biomarkers preserved in cave
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P-136 Analysis of insoluble organic
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P-139 Role and nature of organic ma
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P-141 Biosurfactants - a green alte
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P-143 Phenolic compounds in water l
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P-145 Current level of the organic
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P-147 The d13C composition of indiv
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P-149 Targeted chemical and physica
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P-151 Cu(II) complexation with humi
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P-153 Differentiation of indoor and
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P-156 A detailed study of the intac
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P-158 Unusual distribution of long-
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P-160 Biomarker signatures of metha
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P-162 Lipid biomarkers and bulk bio
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P-164 Chemotaxonomic composition an
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P-166 The role of two submarine can
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P-168 Correlation of crenarchaea an
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P-170 Microbial activity and abunda
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P-172 Microbially mediated carbonat
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P-174 Distinct microbial inventorie
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P-176 Microbial consortium mediatin
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P-178 Diversity of microbial commun
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P-180 Inhibition of anaerobic oil d
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P-182 The influence of hydrogen on
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P-184 Have they lost their heads? D
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P-187 Paleohydrological changes on
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P-189 Paleoenvironmental variations
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P-191 Highly branched isoprenoid al
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P-193 A new global calibration for
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P-195 Molecular fossils and the lat
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P-197 Sediment trap and core top st
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P-199 Detection of environmental ch
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P-201 Carbon and hydrogen isotope b
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P-203 Biogeochemical processes in H
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P-205 Lipid biomarker analysis of f
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P-207 Biomarkers along a holocene s
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P-209 A comparison of methane emiss
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P-211 Paleocene-Eocene Thermal Maxi
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P-213 Biomarker proxies indicate si
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P-215 Distributions of long-chain d
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P-217 The Vinylguaiacol/Indole or V
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P-219 The age and palaeoenvironment
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P-221 Differences in distribution o
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P-225 The change of land plant deri
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P-227 Terrestrial organic matter in
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P-229 Geochemical peculiarities of
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P-231 Bacteriohopanepolyol content
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P-233 Branched GDGTs in the Yenisei
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P-235 Simulation of organic matter
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P-237 Nature of C29 sterols in the
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P-239 Differentiation of organic ma
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P-242 Changes of Rock-Eval HI, OI,
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P-244 Identification and distributi
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P-246 Carbon isotopes and lipid bio
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P-248 Comparison of soil organic ma
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P-250 Biomarker distribution along
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Wednesday Poster Presentations 388
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P-255 Gas source classification in
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P-257 The components and carbon iso
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P-259 Stable carbon isotopes of coa
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P-261 Natural gas generation, migra
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P-264 Natural gas geochemistry of t
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P-266 Geochemical and isotopic char
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P-269 Distribution of alkylbenzenes
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P-271 Terrestrial-derived biomarker
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P-273 Preservation of β-carotane i
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P-275 Aromatic hydrocarbons in oils
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P-277 Statistical analysis of diamo
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P-279 Characterization of biomarker
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P-281 The significance of novel A-n
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P-283 Correlation between compositi
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P-285 Understanding Fluid Inclusion
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P-287 The hydrocarbon occurrence an
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P-289 Correlation of crude oils res
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P-291 Geochemical parameters for un
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P-293 Hydrocarbon biomarkers in the
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P-295 Using diamondoids to unravel
Page 431 and 432: P-297 Significance of aromatic biom
Page 433 and 434: P-299 Drilling conditions making we
Page 435 and 436: P-301 Biomarker distributions and
Page 437 and 438: P-303 Evaluation of petroleum syste
Page 439 and 440: P-305 Geochemical indices of hydroc
Page 441 and 442: P-307 Basin modelling of the Hammer
Page 443 and 444: P-309 Comparative characteristics o
Page 445 and 446: P-311 High water pressure induced c
Page 447 and 448: P-313 Calibration of absolute matur
Page 449 and 450: P-315 Organic Geochemistry of Lower
Page 451 and 452: P-317 Laboratory simulation of vert
Page 453 and 454: P-319 The study of C1-C3 gas genera
Page 455 and 456: P-321 Hydrocarbon potential of Maik
Page 457 and 458: P-323 Paleoenvironment significance
Page 459 and 460: P-325 Origin of abnormal sonic resp
Page 461 and 462: P-327 Organic geochemistry and orga
Page 463 and 464: P-329 Characterising the deposition
Page 465 and 466: P-331 Organic-geochemical character
Page 467 and 468: P-335 Geochemistry of aqua-bitumoid
Page 469 and 470: P-337 Application of electrospray i
Page 471 and 472: P-339 Geochemical characterization
Page 473 and 474: P-341 Simulation studies on the ads
Page 475 and 476: P-343 Effective diffusivities of CO
Page 477 and 478: P-345 Oil Fingerprinting associated
Page 479 and 480: P-347 Strategies for the assessment
Page 481: P-349 Fluid pressure evolution and
Page 485 and 486: P-354 Sulfur isotope fractionation
Page 487 and 488: P-356 Controls on the kinetics of t
Page 489 and 490: P-358 Sulfur compounds in liquid pr
Page 491 and 492: P-360 High pressure pyrolysis of hy
Page 493 and 494: P-362 The reaction of elemental sul
Page 495 and 496: P-365 Geochemical evaluation of the
Page 497 and 498: P-367 Geochemical controls on shale
Page 499 and 500: P-369 Evolution of pores in organic
Page 501 and 502: P-371 Preliminary investigations in
Page 503 and 504: P-373 Geochemistry of coalbed metha
Page 505 and 506: P-375 Integration of basin modeling
Page 507 and 508: P-377 Oil shales occurring in Mongo
Page 509 and 510: Thursday Poster Presentations 508
Page 511 and 512: P-381 Permissible concentration of
Page 513 and 514: P-383 Accumulation and degradation
Page 515 and 516: P-385 Source determination and dept
Page 517 and 518: P-387 The use of phospholipid fatty
Page 519 and 520: P-389 Biogeochemical process studie
Page 521 and 522: P-391 Environmental forensics-recen
Page 523 and 524: P-393 Geochemical characterization
Page 525 and 526: P-395 Source characterization using
Page 527 and 528: P-397 Impact of different operating
Page 529 and 530: P-399 Resolving sources and preserv
Page 531 and 532: P-402 New insights into soil organi
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P-404 Amino sugars as biomarkers fo
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P-406 Biogeochemistry of lake Soppe
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P-408 Sea surface salinity reconstr
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P-410 Carbon cycling in lacustrine
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P-412 Radiocarbon distributions in
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P-414 European lake sediment calibr
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P-416 Developing analytical protoco
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P-418 Extreme intra- and intermolec
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P-420 � 2 H differences among lip
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P-424 Intact polar lipid and associ
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P-426 Bacterial versus archaeal act
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P-428 Study of microbial activity a
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P-430 New bacteriochlorophyll degra
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P-432 Thermally stable anammox biom
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P-434 Impact of a high CO2 partial
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P-436 Methane oxidation in the wate
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P-438 Lipid biomarkers of archaeal
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P-440 Estimation of endospore numbe
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P-442 Deep-sea benthic archaea recy
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P-444 Isolating and cultivating env
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P-446 Distribution of ammonia-oxidi
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P-448 Genetic and metabolic charact
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P-450 Proxies based on archaeal and
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P-453 Experimental palaeochemotaxon
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P-455 Long term cooling and punctua
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P-457 Molecular and isotopic eviden
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P-459 Long-term variations of palae
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P-461 Miocene to Pliocene environme
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P-463 Holocene paleoclimatic variat
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P-465 Hydrological and biogeochemic
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P-467 Molecular hydrogen isotope sy
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P-469 Impact of anaerobic methane o
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P-471 Integrating biomarker and mic
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P-473 Application of TEX86-paleothe
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P-475 Stable isotopes (C, S) and hy
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P-478 The first findings of 12- and
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P-480 The 3 P’s* and the Albian o
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P-482 Meter-scale oxygen gradients
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P-484 Coupling of Miocene-Pliocene
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P-486 New molecular marker and spec
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P-488 Paleoenvironmental changes fr
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P-491 Methoxy-serratenes as discrim
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P-493 Vegetation and soil organic m
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P-497 Decomposition of wheat straw
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P-499 The relationship between peat
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P-501 Land use and climatic effects
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P-503 Geochemical characterization
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P-505 Organic carbon composition an
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P-507 Dynamics of soil organic matt
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P-509 Exploiting isotopic, organic,
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P-511 The effect of soil moisture o
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P-513 Anaerobic oxidation of plant-
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P-515 Variability of terrestrially-
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Author Index 638
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Anselmetti Flavio S. O-63 Ansong Ge
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Brinkhuis Henk P-200, P-468 Britton
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de Souza Carvalho Ismar P-017 Dedys
Page 647 and 648:
Francu Juraj P-037, P-266 Frank Ric
Page 649 and 650:
Hart Malcolm O-09 Hartkopf-Fröder
Page 651 and 652:
Jin Zhijun P-094 Jingjing Li P-179
Page 653 and 654:
Lausmaa Jukka O-58 Lavrieux Marlèn
Page 655 and 656:
Marsh Steven P-509 Marshall Chris O
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Nemchenko- Rovenskaya Alla P-112 Ne
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Radovic Miljana P-152 Ramanathan AL
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Schröder Jan P-020, P-029 Schubert
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Strelnikova Eugenia P-099 Stuart-Wi
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Wakeham Stuart G. O-69 Walters Clif
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Zhang Jing P-515 Zhang Jingru P-398
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25th International Meeting on Organic Geochemistry IMOG 2011

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