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25th International Meeting on Organic Geochemistry IMOG 2011

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P-456<br />

Post-glacial paleoclimatic changes in northeastern Brazil<br />

inferred from depth-sensitive depositi<strong>on</strong>al records of organic<br />

matter in sediments of Lagoa do Caçó<br />

Abdelfettah Sifeddine 1,2 , Philip Meyers 3 , Renato Campello Cordeiro 2 , Ana Luiza<br />

Spadano Albuquerque 2 , Marcello Bernardes 2 , Marie-Pierre Ledru 1 , Bruno Turcq 1 , Jorge<br />

Joao Abrao 2<br />

1 Institut de Recherche pour le Développement, France (IRD), LOCEAN, UMR 7159 CNRS-IRD-Univ. P. & M.<br />

Curie-MNHN), B<strong>on</strong>dy, France, 2 Departamento de Geoquímica, Universidade Federal Fluminense, Niteroi,<br />

Brazil, 3 Department of Geological Sciences, The University of Michigan, Ann Arbor, United States of<br />

America (corresp<strong>on</strong>ding author:pameyers@umich.edu)<br />

Elemental and isotopic compositi<strong>on</strong>s of organic matter<br />

in surficial sediments from five transects across<br />

Lagoa do Caçó (Brazil) have been analyzed to<br />

identify the depth-related processes that affect the<br />

producti<strong>on</strong>, preservati<strong>on</strong>, and depositi<strong>on</strong> of<br />

sedimentary organic matter in this shallow tropical<br />

lake. Each of four transverse transects begins at a<br />

margin dominated by aquatic macrophytes<br />

(Eleocharis), crosses the central deep part of the lake,<br />

and finishes in the opposite macrophyte-dominated<br />

margin. In each transect, TOC c<strong>on</strong>centrati<strong>on</strong>s, C/N<br />

ratios, and � 13 C values decrease between 0 to 4 m,<br />

whereas � 15 N values increase. The parameters<br />

remain stable in sediment from water depths from 4 m<br />

to the center of the lake at 10 m. The depth-related<br />

patterns reflect differences in both the delivery and<br />

the depositi<strong>on</strong> of organic matter in the lake. <strong>Organic</strong><br />

matter is abundantly produced in the marginal area by<br />

emersed and submerged macrophyte vegetati<strong>on</strong> that<br />

diminishes with depth and disappears at 4 meters.<br />

After the disappearance of macrophytes, organic<br />

matter is principally produced at low rates by openlake<br />

phytoplankt<strong>on</strong>. Drawdown of dissolved oxygen is<br />

high in the lake margins, but it is low in the<br />

oligotrophic open waters of the lake. Preservati<strong>on</strong> of<br />

organic matter is c<strong>on</strong>sequently better in sediments of<br />

the lake margins than in deep waters. The depthrelated<br />

pattern of organic matter delivery and<br />

depositi<strong>on</strong> in the sediments of Lagoa do Caçó, in<br />

which water levels are sensitive to groundwater<br />

fluctuati<strong>on</strong>s, was combined with pollen data to<br />

rec<strong>on</strong>struct changes in the post-glacial<br />

paleohydrology of this lake system. A sediment core<br />

from the lake margin and another from the center of<br />

the lake record different histories of organic matter<br />

accumulati<strong>on</strong> that reflect changes in lake level over<br />

the last 21 kyrs. At the end of the last glacial<br />

maximum, a predominantly dry regi<strong>on</strong>al climate was<br />

interrupted by short humid phases as reflected by a<br />

successi<strong>on</strong> of very thin layers of sand and organic<br />

matter. The subsequent late glacial climate was<br />

relatively wet and included two rapid lake-level<br />

increases accompanied by forest expansi<strong>on</strong>. The two<br />

moist phases were separated by a phase where the<br />

lake level remained stable and a cool climate<br />

―Podocarpus‖ forest developed. These humid climate<br />

periods differed significantly from the presently warm<br />

tropical c<strong>on</strong>diti<strong>on</strong>s. We c<strong>on</strong>clude that post-glacial to<br />

Holocene climate moisture has been c<strong>on</strong>trolled by<br />

intensificati<strong>on</strong>s or positi<strong>on</strong>al shifts of the Intertropical<br />

C<strong>on</strong>vergence Z<strong>on</strong>e that affected lake levels, which in<br />

turn have left an imprint <strong>on</strong> the elemental and isotopic<br />

compositi<strong>on</strong>s of sediment organic matter.<br />

581

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