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25th International Meeting on Organic Geochemistry IMOG 2011

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P-220<br />

A multiproxy high-resoluti<strong>on</strong> approach for the rec<strong>on</strong>structi<strong>on</strong> of<br />

sea surface temperatures of the last 500 years at the southern<br />

Italian shelf<br />

Arne Leider 1 , Anna-Lena Grauel 2 , Kai-Uwe Hinrichs 1 , Stefano M. Bernasc<strong>on</strong>i 2 , Gerard<br />

J.M. Versteegh 1<br />

1 Org. <strong>Geochemistry</strong> Group, MARUM Center for Marine Envir<strong>on</strong>mental Sci. & Department of Geosciences,<br />

University of Bremen, Bremen, Germany, 2 Geological Institute, ETH Zürich, Zürich, Switzerland<br />

(corresp<strong>on</strong>ding author:arneleider@uni-bremen.de)<br />

The southern Italian shelf harbors excellent sites for<br />

high-resoluti<strong>on</strong> paleoenvir<strong>on</strong>mental rec<strong>on</strong>structi<strong>on</strong>s [1<br />

and references therein]. Furthermore, Italy provides a<br />

unique archive of instrumental and historical records<br />

of climate and envir<strong>on</strong>ment in the Mediterranean.<br />

Previous core-top calibrati<strong>on</strong>s al<strong>on</strong>g the southern<br />

Italian shelf showed clear discrepancies between sea<br />

surface temperature (SST) proxies based <strong>on</strong> the U K‘ 37<br />

and TEX86 indices as well as � 18 O of the planktic<br />

foraminifer G. ruber (white) (Fig. 1A-D). The<br />

alken<strong>on</strong>e-based SSTs reflect maxima in haptophyte<br />

producti<strong>on</strong> during colder seas<strong>on</strong>s. The TEX86-derived<br />

temperatures increase with distance from shore, so<br />

that at least offshore TEX86-derived SSTs reflect<br />

summer temperatures in the stratified and oligotrophic<br />

water column of the I<strong>on</strong>ian Sea [2]. � 18 O based<br />

temperatures of G. ruber (white) also reflect a<br />

summer signal but variati<strong>on</strong>s seem to be influenced<br />

offshore by changes in water depth habitat and<br />

salinity of I<strong>on</strong>ian Sea waters [3].<br />

In this study we have extended the previous<br />

temperature proxy comparis<strong>on</strong> [2] to a time series<br />

using a core from the southern Italian shelf covering<br />

the last 500 years with a 3-year sample resoluti<strong>on</strong><br />

(39.76°N, 17.89°E, 173 m water depth).<br />

The SST proxy signals show a high variability during<br />

the last 500 years with amplitudes of up to 3°C that<br />

could not be explained by variati<strong>on</strong>s in regi<strong>on</strong>al<br />

instrumental temperature records al<strong>on</strong>e. The<br />

alken<strong>on</strong>e-based temperatures (14.6-19.4°C; Fig. 1E)<br />

are up to 5°C lower compared to TEX86 temperatures<br />

(18.0-22.0°C). However, both proxies show covariati<strong>on</strong>s<br />

with maxima at 1500 AD, 1800 AD and a<br />

decrease in SST during the last century which<br />

c<strong>on</strong>trasts with the global temperature trend [e.g., 4]. In<br />

general, � 18 O based temperatures (15.9-21.9°C)<br />

agree with TEX86 SST estimates, but show periods<br />

with opposing trends. We speculate that these reflect<br />

variati<strong>on</strong>s in the balance between near-coastal and<br />

more saline I<strong>on</strong>ian Sea waters from the Eastern<br />

Mediterranean partly affecting the � 18 O compositi<strong>on</strong><br />

and carrying a high TEX86 temperature signal.<br />

References<br />

[1] Versteegh, G.J.M., de Leeuw, J.W., Tarricco, C.,<br />

Romero, A. (2007) Geochem. Geophys. Geosyst. 8,<br />

doi:10.1029/2006GC001543.<br />

[2] Leider, A., Hinrichs, K.-U., Mollenhauer, G., Versteegh,<br />

G.J.M., (2010) Earth Planet. Sci. Lett. 300, 112-124.<br />

[3] Grauel, A.L., Bernasc<strong>on</strong>i, S.M., (2010) Mar.<br />

Micropale<strong>on</strong>tology 77, 175-186.<br />

[4] IPCC (2007) WG1, Cambridge Univ. Press, New York.<br />

Fig. 1. Distributi<strong>on</strong> of sea surface temperatures (A-D) based <strong>on</strong> annual mean satellite data and the temperature proxies<br />

U K‘ 37, TEX86 and � 18 O of G. ruber (white) in surface sediments at the southern Italian shelf [adapted from 2, 3]. E) Depth<br />

profile of alken<strong>on</strong>e-based SSTs in core GeoB 10709-4, black curve indicates 3-point running mean.<br />

359

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