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25th International Meeting on Organic Geochemistry IMOG 2011

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P-366<br />

<strong>Organic</strong> geochemical characterizati<strong>on</strong> and distributi<strong>on</strong> of<br />

unc<strong>on</strong>venti<strong>on</strong>al hydrocarb<strong>on</strong> plays of the Lower Cretaceous of<br />

NW Germany<br />

Ulrich Berner, Matthias Heldt<br />

Federal Institute for Geosciences and Natural Resources, Hannover, Germany (corresp<strong>on</strong>ding<br />

author:ulrich.berner@bgr.de)<br />

Within the Lower Sax<strong>on</strong>y Basin (LSB) of NW<br />

Germany sediments of the Lower Cretaceous are<br />

known to c<strong>on</strong>tain abundant organic material at<br />

different stratigraphic levels. We present a<br />

geochemical high-resoluti<strong>on</strong> study of sediments of the<br />

German Wealden (Berriasian) and compare the data<br />

to Barremian and Aptian organic-rich sediments.<br />

A complete successi<strong>on</strong> comprising 360 m of the<br />

German Wealden (Berriasian) has been investigated<br />

at a drill site located in the western part of the LSB,<br />

representing typical basin sediments of the larger<br />

area. Thermally immature Barremian and Aptian<br />

sediments where obtained from three wells of the<br />

eastern part of the LSB. Samples have been collected<br />

at all drill sites at a minimum spacing of 1 m in order<br />

to better describe facies changes. <strong>Organic</strong><br />

geochemical investigati<strong>on</strong>s including pyrolysis<br />

methods as well as molecular and carb<strong>on</strong> isotope<br />

analyzes have been performed <strong>on</strong> the collected<br />

sediments.<br />

Our data combined with additi<strong>on</strong>al geochemical<br />

informati<strong>on</strong> show that the Berriasian sediments have<br />

been deposited in a predominantly lacustrine<br />

envir<strong>on</strong>ment that however experienced marine<br />

ingressi<strong>on</strong>s. The numerous facies changes within the<br />

Wealden are likely related to climatically driven<br />

precipitati<strong>on</strong> changes, which have lead to lake level<br />

variati<strong>on</strong>s. The observed depositi<strong>on</strong>al changes are<br />

associated with variati<strong>on</strong>s of the organic facies.<br />

During periods of high lake levels, the organic matter<br />

of the clay st<strong>on</strong>es and marls is hydrogen-rich and<br />

likely derived from aquatic precursors. The associated<br />

anoxic to dysoxic water c<strong>on</strong>diti<strong>on</strong>s are obvious from<br />

the stable carb<strong>on</strong> isotopic compositi<strong>on</strong> of the organic<br />

carb<strong>on</strong> which is highly enriched in 12 C suggesting that<br />

a microbial methane cycle had established during the<br />

depositi<strong>on</strong> of the sediments and the organic matter<br />

experienced a significant c<strong>on</strong>tributi<strong>on</strong> from the<br />

microbial pool. Low lake levels were associated with<br />

the depositi<strong>on</strong> of hydrogen-depleted organic matter,<br />

which either relate to land plant and/or highly oxidized<br />

material.<br />

Our data of the Barremian to Lower Aptian organicrich<br />

Dark Shale Sequence shows that the sediments<br />

c<strong>on</strong>tain variable amounts of terrestrial and aquatic<br />

organic matter deposited in a marine envir<strong>on</strong>ment.<br />

The Lower Aptian Fish Shale is dominated by aquatic<br />

organic matter, and both Barremian and Lower Aptian<br />

sediments c<strong>on</strong>tain rather high c<strong>on</strong>centrati<strong>on</strong>s of C28steranes<br />

(Fig. 1), which could be related to observed<br />

higher abundances of coccolithophores.<br />

Figure 1: Relative abundances of C27 to C29 ��steranes<br />

of Lower Cretaceous sediments of the Lower<br />

Sax<strong>on</strong>y Basin.<br />

Although, basin sediments of the Wealden are highly<br />

variable the anoxic to dysoxic facies types c<strong>on</strong>taining<br />

type I kerogens are excellent sources for in-situ oil<br />

and gas (at higher maturities). Favorable targets for<br />

the extracti<strong>on</strong> of unc<strong>on</strong>venti<strong>on</strong>al hydrocarb<strong>on</strong>s in the<br />

NW German Basin would likely be secti<strong>on</strong>s of<br />

Wealden 3 and 4.<br />

The Barremian and Aptian organic-rich shales<br />

exceeding partly 100 m of thickness c<strong>on</strong>tain type II<br />

kerogens, and would generate oil and gas, if the<br />

maturities were sufficiently high in the basin.<br />

The Lower Sax<strong>on</strong>y Basin is tect<strong>on</strong>ically segmented<br />

with highly variable heat flow regimes, which set the<br />

boundary c<strong>on</strong>diti<strong>on</strong>s for the mapped distributi<strong>on</strong> of<br />

unc<strong>on</strong>venti<strong>on</strong>al Lower Cretaceous plays.<br />

495

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