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25th International Meeting on Organic Geochemistry IMOG 2011

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P-081<br />

Geochemical evidence for two sources of oils in the Papuan<br />

Basin, Papua New Guinea<br />

Manzur Ahmed 1 , Herbert Volk 1 , David Holland 2 , T<strong>on</strong>y Allan 1<br />

1 CSIRO Earth Science and Resource Engineering, North Ryde, Australia, 2 InterOil, Cairns, Australia<br />

(corresp<strong>on</strong>ding author:manzur.ahmed@csiro.au)<br />

Two major groups of hydrocarb<strong>on</strong>s, Family A and<br />

Family B, can be distinguished by detailed organic<br />

geochemical assessment of 34 oils/c<strong>on</strong>densates,<br />

inclusi<strong>on</strong> oils and solid bitumens from the Eastern<br />

Papuan Basin (EPB) and the Western Papuan Basin<br />

(WPB) (Fig. 1). Both groups of oils/c<strong>on</strong>densates could<br />

be further divided into two subgroups based <strong>on</strong> minor<br />

variati<strong>on</strong>s in source facies. Family A2 samples in the<br />

EPB were generated at peak to late oil-window<br />

maturities from a clay-rich marine source rock<br />

c<strong>on</strong>taining predominantly terrestrial higher plant<br />

derived organic matter deposited in suboxic to anoxic<br />

envir<strong>on</strong>ments. Biomarker signatures are related to the<br />

crude oils from the WPB Fold Belt regi<strong>on</strong>, and similar<br />

to those oils (Family A1), this family was probably<br />

generated from the Late Jurassic Imburu Formati<strong>on</strong>.<br />

Family B samples were also generated at peak to late<br />

oil-window maturities, but from a clay-poor, possibly<br />

calcareous marine source rock, richer in prokaryotic<br />

organic matter, and deposited in suboxic to anoxic<br />

envir<strong>on</strong>ments. This is indicated by higher abundances<br />

of C29 �� hopane,�C35 homohopanes and<br />

2��methylhopanes. Oleanane±lupane and the<br />

distributi<strong>on</strong>s of nordiacholestanes and norcholestanes<br />

suggest that the Family B oils/c<strong>on</strong>densates were<br />

derived from Cretaceous or younger source rock(s).<br />

Hydrocarb<strong>on</strong>s in the Elk-Antelope gas-c<strong>on</strong>densate<br />

field, a significant recent discovery in the EPB, cluster<br />

in Family B. The molecular and isotopic signatures of<br />

thermogenic gases in this field show very little<br />

variati<strong>on</strong> and are also c<strong>on</strong>sistent with marine source<br />

rocks. The presence of two major groups of<br />

oils/c<strong>on</strong>densates in the EPB is c<strong>on</strong>sistent with the two<br />

families of solid bitumens and an inclusi<strong>on</strong> oil from the<br />

Aure Scarp area (George et al., 2007), and different<br />

types of oils and inclusi<strong>on</strong> oils in the WPB regi<strong>on</strong><br />

(George et al., 1997).<br />

Although the exact origin of Family B hydrocarb<strong>on</strong>s is<br />

unclear, source rock intervals may be hosted in<br />

Cretaceous or Palaeogene strata, e.g. in the<br />

Cretaceous Ieru or Chim Formati<strong>on</strong>s. New total<br />

organic carb<strong>on</strong> and Rock Eval pyrolysis data indicate<br />

that the Late Jurassic / Early Cretaceous Tubu and<br />

Maril Shales in the Papuan Gulf regi<strong>on</strong> are also<br />

potential source rocks.<br />

Figure 1. Dendrogram of hierarchical cluster analysis of 13<br />

source-specific biomarker parameters showing genetic<br />

groups of oil/c<strong>on</strong>densates in the Papuan Basin. Data for<br />

solid bitumens; Puri-1 and Bwata-1 oils/c<strong>on</strong>densates are<br />

1.0<br />

P'nyang-2X 1922 m FI oil<br />

Iagifu-7X 2615 m FI oil<br />

Iagifu-7X 2564 m FI oil<br />

Triceratops-1-1805 m oil show<br />

Triceratops-1-1844 m oil show<br />

CN405 Family B solid bitumen<br />

ELK-2 oil show<br />

CN360 Family B solid bitumen<br />

Moose-2 513 m oil show<br />

0.8 0.6 0.4 0.2 0.0<br />

Elk-1 oil/c<strong>on</strong>densate<br />

CN540 Family B solid bitumen<br />

CN409 Family B solid bitumen<br />

Yawiyo seep sample-1<br />

Family B1<br />

CN457 Family B solid bitumen<br />

Bwata-1 oil/c<strong>on</strong>densate<br />

North Ox seep<br />

Moose-2 753 m oil show<br />

Moose-2 634 m oil show<br />

Family B<br />

Antelope-1 DST-11 oil/c<strong>on</strong>densate<br />

Antelope-1 DST-12 oil/c<strong>on</strong>densate<br />

Antelope-1 DST-14 oil/c<strong>on</strong>densate<br />

Antelope-1 DST-13 oil/c<strong>on</strong>densate<br />

from George et al. (2007), and Western Fold Belt<br />

oils/inclusi<strong>on</strong> oils are from George et al. (1997). Sample<br />

names in black for the Eastern and in red for the Western<br />

Papuan Basin.<br />

References<br />

Elk-4 oil-c<strong>on</strong>densate<br />

Antelope-1 1747 oil/c<strong>on</strong>densate<br />

Antelope-1 D-8 oil/c<strong>on</strong>densate<br />

Iagifu-7X DST-1 crude oil<br />

Iagifu-7X DST-3 crude oil<br />

Iagifu-7x DST-5 crude oil<br />

Iagifu-7X DST-2 crude oil<br />

Pangia seep<br />

CN415 Family A solid bitumen<br />

CN383 Family A solid bitumen<br />

Puri-1 oil/c<strong>on</strong>densate<br />

CN381 Family A solid bitumen<br />

Similarity value<br />

Family A1<br />

Family B2<br />

Family A<br />

Family A2<br />

[1] George, S.C., Krieger, F.W.,Eadingt<strong>on</strong>, P.J., Quezada,<br />

R.A., Greenwood, P.F., Eisenberg, L.I., Hamilt<strong>on</strong>, P.J. and<br />

Wils<strong>on</strong>, M.A., 1997. Geochemical comparis<strong>on</strong> of oil–bearing<br />

fluid inclusi<strong>on</strong>s trapped in quartz grains and live oil from the<br />

Toro Sandst<strong>on</strong>e, Papua New Guinea. <strong>Organic</strong> <strong>Geochemistry</strong><br />

26, 155-173.<br />

[2] George, S.C., Volk, H., Ahmed, M., Pickel, W., and Allan,<br />

T., 2007. Biomarker evidence for two sources for solid<br />

bitumens in the Subu wells: implicati<strong>on</strong>s for the petroleum<br />

prospectivity of the East Papuan Basin. <strong>Organic</strong><br />

<strong>Geochemistry</strong>, 38, 609-642.<br />

224

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