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25th International Meeting on Organic Geochemistry IMOG 2011

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P-107<br />

Caldera of the Uz<strong>on</strong> volcano as a natural laboratory of the<br />

modern oil formati<strong>on</strong><br />

Alexey K<strong>on</strong>torovich 1 , Svetlana Bortnikova 1 , Gennadii Karpov 2 , Vladimir Kashirtsev 1 ,<br />

Elena Kostyreva 1 , Alexander Fomin 1<br />

1 Institute of Petroleum Geology and Geophysics SB RAS, Novosibirsk, Russian Federati<strong>on</strong>, 2 Institute of<br />

Volcanology and Seismology FEB RAS, Petropavlovsk-Kamchatsky, Russian Federati<strong>on</strong><br />

The advocates of abiogenic origin of oil<br />

frequently give examples of naphthide occurrence in<br />

the craters of modern volcanoes. Authors selected<br />

and examined oil shows from the caldera of the Uz<strong>on</strong><br />

volcano (Kamchatka). The hydrocarb<strong>on</strong> type c<strong>on</strong>tent<br />

of oil shows is dominated by hydrocarb<strong>on</strong>s (HC) (90-<br />

93%). The c<strong>on</strong>centrati<strong>on</strong> of saturated hydrocarb<strong>on</strong>s<br />

by weight in them is two times as much as that of<br />

aromatic <strong>on</strong>es. The c<strong>on</strong>centrati<strong>on</strong> of heterocyclic<br />

compounds is 7-10%. Few asphaltenes are present in<br />

the examined samples (< 0,3%). The compositi<strong>on</strong> of<br />

saturated and aromatic hydrocarb<strong>on</strong>s of oil shows in<br />

the Uz<strong>on</strong> volcano caldera shows that they have been<br />

derived from lipids of land plant remains brought into<br />

sediments (the ratio of sterane c<strong>on</strong>centrati<strong>on</strong>s<br />

С29/С27>2,5, tricyclane index 2(С19+С20)/ΣСi (i = 23,<br />

24, 25, 26)>1,5, relatively high c<strong>on</strong>centrati<strong>on</strong> of<br />

triaromatic steroids), aquabi<strong>on</strong>ts, inhabitants of<br />

caldera sediments and bottom waters (the ratio n-<br />

С27/n-С17

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