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Em4885 irrigation management practices to protect ground water

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5<br />

CHAPTER 3<br />

The nitrogen cycle, shown schematically in Figure 3-1, is the name given <strong>to</strong> the movement of<br />

nitrogen in its different forms from the atmospheric gas N 2 in<strong>to</strong> the soil in some form or another and<br />

then back <strong>to</strong> the atmosphere. Some of the more important processes that occur are:<br />

1. Fixation - addition of nitrogen <strong>to</strong> the soil through the symbiotic action of rhizobia<br />

bacteria on the root systems of legumes or by other microorganisms (non-symbiotic)<br />

in the soil and <strong>water</strong>.<br />

2. Mineralization - the breakdown of soil organic matter by the activity of microbes.<br />

+ Mineralization converts organic nitrogen <strong>to</strong> the ammonium (NH ) form, which<br />

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is available <strong>to</strong> the plant.<br />

+ - 3. Nitrification - the conversion of the ammonium (NH ) form <strong>to</strong> the nitrate (NO3 ) form.<br />

4<br />

- Nitrification is the result of activity by soil bacteria. Nitrate (NO ) nitrogen is readily<br />

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- available <strong>to</strong> plants. However, nitrate (NO ) nitrogen is also readily leached since it stays<br />

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in solution and does not adhere <strong>to</strong> soil particles. Nitrification is a relatively quick<br />

process. Nitrogen added <strong>to</strong> the soil via commercial fertilizer in the ammonium form can<br />

be transformed <strong>to</strong> the nitrate form within one <strong>to</strong> two weeks if conditions are favorable.<br />

4. Immobilization - the conversion of inorganic nitrogen in organic matter which occurs<br />

when carbon is added <strong>to</strong> the soil. Plant residues are the chief source of this carbon.<br />

However, as the decomposition of plant residues continues, nitrogen is again released<br />

through mineralization as explained previously.<br />

- 5. Denitrification - conversion of nitrate (NO ) nitrogen in<strong>to</strong> the atmospheric gas N2 by soil<br />

3<br />

bacteria in wet, poorly aerated conditions, such as would be found in <strong>water</strong>-logged, heavy<br />

soils. This process can also occur relatively rapidly but requires decomposing organic<br />

matter as a carbon source.<br />

6. Volatilization - the movement of nitrogen in the form of ammonia gas <strong>to</strong> the atmosphere.<br />

+ Volatilization occurs when ammonium (NH ) forms of nitrogen are applied <strong>to</strong> the soil<br />

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surface and not properly worked in<strong>to</strong> the soil. Volatilization increases with high<br />

temperatures and calcareous soils. Lack of rain following the application and high<br />

amounts of crop residue also increase the process.<br />

- 7. Leaching - the movement of the nitrate (NO ) form below the crop’s root zone. Both<br />

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+ - - the ammonium (NH ) and nitrate (NO3 ) forms will leach. However, the nitrate (NO3 )<br />

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form is highly soluble and thus, is more readily leachable. Leaching occurs with deep<br />

percolation, the movement of soil <strong>water</strong> below the root zone. Unfortunately, many times,<br />

leachate moves <strong>to</strong> an aquifer and contaminates <strong>ground</strong> <strong>water</strong>.<br />

An example of a path in the nitrogen cycle that includes the use of commercial fertilizer is:<br />

+ 1. Conversion of atmospheric N in<strong>to</strong> the ammonium (NH ) form by a commercial<br />

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fertilizer manufacturer.<br />

+ 2. Addition of the ammonium (NH ) fertilizer <strong>to</strong> the soil by a grower.<br />

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