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Proceedings e report - Firenze University Press

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SORPTION OF MOISTURE AND DIMENSIONAL CHANGE OF WOOD SPECIES USED IN HISTORIC OBJECTS<br />

Table 1: GAB constants for water vapour adsorption and desorption isotherms for 21 species of wood as well as<br />

their coefficients of tangential and radial dimensional change<br />

Species Adsorption/desorption Dimensional change<br />

coefficients<br />

vm*10 -2<br />

c k tangential radial<br />

Softwoods<br />

pine (Pinus spp.) 7.25/10.07 13.5/8.21 0.49/0.44 0.38 0.13<br />

Japanese cypress (Chamaecyparis<br />

obtusa)<br />

7.58/10.19 4.38/7.41 0.63/0.53 0.23 0.12<br />

spruce (Picea spp.) 6.82/7.96 10.04/12.4<br />

9<br />

0.74/0.70 0.34 0.14<br />

larch (Larix decidua) 7.07/7.33 9.89/9.05 0.74/0.72 0.45 0.13<br />

fir (Abies spp.)<br />

Hardwoods<br />

7.40/11.35 8.90/7.55 0.66/0.50 0.32 0.12<br />

sycamore (Acer pseudoplatanus) 6.67/12.49 9.01/7.01 0.58/0.30 0.38 0.19<br />

oak (Quercus spp.) 6.19/11.1 7.36/7.26 0.72/0.51 0.33 0.19<br />

dark fossil oak wood 7.57/11.13 7.36/12.50 0.45/0.24 0.62 0.39<br />

rosewood (Dalbergia spp.) 6.11/9.84 9.31/7.38 0.66/0.53 0.33<br />

walnut (Juglans spp.) 5.88/10.41 7.35/4.36 0.69/0.56 0.21 0.14<br />

cherry (Prunus avium) 5.91/8.64 9.89/7.01 0.72/0.66 0.25 0.14<br />

lime (Tilia spp.) 4.51/7.69 7.42/4.70 0.79/0.66 0.30 0.19<br />

sour cherry (Prunus cerasus) 6.80/8.15 8.74/9.83 0.69/0.71 0.29 0.16<br />

elm (Ulmus procera) 5.65/9.07 14.16/7.03 0.74/0.66 0.31 0.17<br />

poplar (Populus spp.) 5.95/8.13 9.58/7.88 0.73/0.68 0.27 0.12<br />

mahogany (Swietenia mohagoni) 7.80/11.18 10.00/7.86 0.65/0.59 0.28 0.11<br />

beech (Fagus sylvatica) 6.98/11.92 7.11/4.88 0.70/0.53 0.36 0.17<br />

birch (Betula pendula) 6.67/10.60 7.85/5.64 0.71/0.57 0.30 0.21<br />

willow (Salix spp.) 6.59/9.07 8.03/7.03 0.73/0.66 0.20 0.07<br />

apple (Malus domestica) 6.83/14.95 7.70/5.15 0.73/0.64 0.35 0.20<br />

ash (Fraxinus excelsior L) 6.63/6.54 8.92/8.32 0.68/0.20 0.29 0.21<br />

Average 6.83/9.36 8.61/7.59 0.66/0.57<br />

4. Dimensional change isotherms<br />

The amount wood specimens swell or shrink was measured as relative dimensional change versus RH.<br />

The relationships were described by fitting the polynomial of degree 3 to the adsorption (swelling) and<br />

desorption (shrinkage) data. As for the sorption isotherms, the ‘average’ swelling and shrinking<br />

isotherms were calculated by fitting the data for all 21 wood species and they are shown for the<br />

tangential and radial directions in Fig. 3. The constant coefficients of the polynomial a0 to a3, for the<br />

swelling and shrinkage, are listed in Table 2.<br />

Table 2: The constant coefficients of the polynomial predicting the average swelling and shrinkage isotherms.<br />

a0 a1 a2 a3<br />

swelling tangential -0.0088 4.8412 -5.1062 6.0800<br />

swelling radial -0.0031 3.0628 -3.1238 3.2034<br />

shrinkage tangential 0.0131 5.2690 0.6517 -0.4018<br />

shrinkage radial 0.0051 3.5639 -0.6023 -0.0461<br />

14

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