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Proceedings e report - Firenze University Press

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WOOD SCIENCE FOR CONSERVATION OF CULTURAL HERITAGE<br />

treatment about half intensity per mass unit of the untreated sample. Five months after treatment the<br />

intensity per mass unit for treated samples was higher than that after three months but lied between<br />

half and one third of the untreated samples. This shows that in addition to consolidation effect, the<br />

impregnation with the styrene resin has also a protective effect against natural cellulose free radicals.<br />

Table 3. Semnal RES<br />

Sample<br />

Three months after treatment Five months after treatment<br />

Intensity (a.u.) Mass normated Intensity (a.u.) Mass normated<br />

intesity<br />

intesity<br />

A untreated 54738 1766 104859 3383<br />

A treated 78894 974 133497 1648<br />

B untreated 85968 1719 198648 3973<br />

B treated 58059 907 92979 1453<br />

C untreated 39149 1223 112194 3506<br />

C treated 97551 938 126054 1212<br />

4. Conclusions<br />

The delivered dose of 24 kGy was more than enough to disinfect the studied samples from insects and<br />

moulds. In addition, this dose is very close to the usual dose used for sterilization. So, after treatment<br />

the samples were almost sterile. Using this irradiation dose for disinfection, proper packaging of<br />

samples and post-irradiation handling procedures of them, after the disinfection treatment the<br />

conservator can seal first a totally clean object of biodeterioration factors, and after that proceed to its<br />

restoration. Irradiation doses up to 10 kGy can be used for prevention from the action of different<br />

biodeterioration factors or for first step of remediation treatment.<br />

In case of consolidation by impregnation with styrene resin, the wooden object becomes heavier and<br />

more resistant at penetration and bending. The treated object contains less free radicals than the<br />

untreated one. Also, the object changes its colour, generally getting darker, and does not get better<br />

impact resistance. When a conservator considers that disadvantages such application of a nonreversible<br />

consolidation treatment, darker colour and less impact resistance are not of crucial<br />

importance for a certain cultural heritage object then this treatment method can be a very good choice.<br />

As a general conclusion, the irradiation treatment is considered proper to be applied to different<br />

wooden cultural heritage objects only for their disinfection (as prevention treatment or as first step of<br />

remediation treatment aiming at conservation) or both for their disinfection and consolidation (as<br />

remediation treatment aiming at conservation).<br />

ACKNOWLEDGEMENTS<br />

The authors would like to thank COST Action IE0601 for the opportunity for collaboration given to<br />

them through the STSM of Dr. Mihalis Cutrubinis at ARC-Nucléart Grenoble, France and Romanian<br />

National Authority for Scientific Research for the economic support of scientific work.<br />

REFERENCES<br />

1. IAEA, 2003. Report from a technical meeting; emerging applications of radiation processing for<br />

21 st<br />

century. Vienna, Austria.<br />

2. Tiano P., 2002. Biodegradation of Cultural Heritage: Decay Mechanisms and Control Methods.<br />

<strong>Proceedings</strong> of ARIADNE Workshop 9 – Historic materials and their diagnostics, February 4-10.<br />

3. Diehl J. F., 1996. Biological efects of ionizing radiation in Safety of irradiated food. Ed. Marcel<br />

Dekker Inc., New York, USA.<br />

4. Ramiere R. and Tran K. Q., 1989. Nucleart: Nuclear Techniques Applied to Art. Nuclear Europe,<br />

7:50.<br />

87

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