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Proceedings e report - Firenze University Press

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ultramarine<br />

[bad]<br />

titanium white<br />

[medium]<br />

napples yellow<br />

[medium]<br />

cadmium<br />

yellow (citron)<br />

WOOD SCIENCE FOR CONSERVATION OF CULTURAL HERITAGE<br />

HL 0.90<br />

(0.79)<br />

CM 0.39<br />

(0.29)<br />

HL -1.60<br />

(0.62)<br />

CM -1.31<br />

(0.46)<br />

HL 0.82<br />

(0.33)<br />

CM -0.66<br />

(0.08)<br />

HL -1.39<br />

(0.25)<br />

[bad] CM -0.20<br />

(0.18)<br />

cadmium<br />

yellow<br />

HL 0.54<br />

(0.59)<br />

[bad] CM 2.01<br />

(0.48)<br />

ochre yellow<br />

[bad]<br />

HL 4.29<br />

(0.75)<br />

CM 3.71<br />

(0.65)<br />

ochre yellow<br />

Cd yellow<br />

Cd yellow (citron)<br />

ultramarine<br />

cobalt blue<br />

Solferino lake<br />

cadmium red<br />

napples yellow<br />

titanium white<br />

Brunswick blue<br />

Prussian blue<br />

silver white<br />

ivory black<br />

raw umber<br />

poppy seed oil<br />

linseed oil<br />

rabbit-skin glue<br />

2.00<br />

(0.94)<br />

5.45<br />

(0.41)<br />

0.26<br />

(0.07)<br />

-0.12<br />

(0.02)<br />

-0.18<br />

(0.06)<br />

-0.51<br />

(0.06)<br />

1.03<br />

(0.15)<br />

0.23<br />

(0.17)<br />

0.31<br />

(0.37)<br />

0.75<br />

(0.45)<br />

-0.86<br />

(0.33)<br />

0.50<br />

(0.21)<br />

233<br />

-3.00<br />

(1.17)<br />

-6.05<br />

(0.35)<br />

0.76<br />

(0.20)<br />

1.45<br />

(0.10)<br />

-1.57<br />

(0.55)<br />

-3.70<br />

(0.53)<br />

-1.92<br />

(0.47)<br />

-0.20<br />

(0.30)<br />

2.85<br />

(1.29)<br />

5.09<br />

(1.69)<br />

4.30<br />

(0.66)<br />

5.34<br />

(0.38)<br />

3.32<br />

(1.32)<br />

7.05<br />

(0.43)<br />

0.76<br />

(0.21)<br />

1.45<br />

(0.10)<br />

-1.58<br />

(0.55)<br />

-3.72<br />

(0.53)<br />

-1.96<br />

(0.47)<br />

-0.21<br />

(0.30)<br />

2.70<br />

(1.30)<br />

4.91<br />

(1.70)<br />

3.55<br />

(0.66)<br />

5.06<br />

(0.28)<br />

1.37<br />

(0.72)<br />

3.83<br />

(0.28)<br />

-2.26<br />

(0.55)<br />

0.77<br />

(0.43)<br />

0.18<br />

(0.08)<br />

0.59<br />

(0.08)<br />

-0.61<br />

(0.10)<br />

-0.14<br />

(0.11)<br />

0.67<br />

(0.24)<br />

1.05<br />

(0.28)<br />

2.61<br />

(0.33)<br />

1.81<br />

(0.34)<br />

CM<br />

HL<br />

0 2 4 6 8 10<br />

dE* [CIELAB units]<br />

3.72<br />

(1.09)<br />

8.15<br />

(0.36)<br />

1.80<br />

(0.56)<br />

1.96<br />

(0.17)<br />

1.79<br />

(0.51)<br />

3.79<br />

(0.34)<br />

2.58<br />

(0.38)<br />

0.36<br />

(0.29)<br />

2.92<br />

(1.27)<br />

5.52<br />

(1.53)<br />

6.14<br />

(0.70)<br />

6.52<br />

(0.51)<br />

Fig. 1. Total colour differences between unirradiated and irradiated samples (A)<br />

For samples prepared with binders (rabbit skin glue, linseed oil and poppy seed oil), without pigments,<br />

the agreement was good. In this paper are presented only the samples with 12 layers of binders; for<br />

samples with a lower number of layers the agreement is much better. The highest disagreement, only<br />

quantitative, is for lightness (L*): CM indicates a higher difference in L*.<br />

Regarding the effect of gamma irradiation, there are small colour differences; even in the case of<br />

rabbit skin glue, the main component of colour difference is from chroma- considering 12 layers of<br />

binder and 200 kGy, this difference is still acceptable, although this dose is 20 times the reference<br />

dose for disinfections.<br />

In the case of samples prepared with different pigments in mixture with poppy seed oil, the agreement<br />

between the two spectrophotometers is depending on the uniformity of the sample. One can observe<br />

1.60<br />

3.69<br />

1.00<br />

1.51<br />

0.82<br />

1.79<br />

0.91<br />

0.15<br />

1.14<br />

2.10<br />

3.19<br />

2.91

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